Oxidative coupling of deltahedral [Ge9]4- Zintl ions [14]

Journal of the American Chemical Society

Volumn 121, Issue 39, 1999, Pages 9245-9246

  Xu, Li ^a   Sevov, Slavi C ^a  

^a UNIVERSITY OF NOTRE DAME   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ETHYLENEDIAMINE; GERMANIUM; ION; METAL COMPLEX;

CHEMICAL BINDING; CHEMICAL MODIFICATION; CHEMICAL REACTION; CRYSTAL STRUCTURE; LETTER; OXIDATION; PRECIPITATION;

EID: 0032857974     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja992269s     Document Type: Letter

References (22)

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13. (a) von Schnering, H.-G.; Baitinger, M.; Bolle, U.; Cabrera, W. C.; Curda, J.; Grin, Y.; Heinemann, F.; Llanos, L.; Peters, K.; Schmeding, A.; Somer, M. Z. Anorg. Allg. Chem. 1997, 623, 1037.
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15. 17, a three-electron-richer compound.
16. Redistilled ethylenediamine (99.5+%), packaged under nitrogen (Aldrich), and Kryptofix 222 (98%, Acros) were used as received. All operations of the dissolution and crystallization were performed in a helium-filled glovebox.
17. 2) were done using the SHELXTL V5.1 package. The data were corrected for absorption with the aid of three ψ scans at different θ angles.
18. Belin, C. H. E.; Corbett, J. D.; Cisar, A. J. Am. Chem. Soc. 1977, 99, 7163.
19. Bobev, S.; Sevov, S. C. J. Am. Chem. Soc. 1999, 121, 3795.
20. Bobev, S.; Sevov, S. C., unpublished results.
21. -1), and therefore no magnetic moment due to localized spins.
22. Chains of nine-atom clusters and alkali metal cations have been reported: Burns, R.; Corbett, J. D. Inorg. Chem. 1985, 24, 1489. See also ref 6.