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Volumn 46, Issue 28, 2007, Pages 5310-5313

[Au3Ge45]9- - A binary anion containing a {Ge45} cluster

Author keywords

Cluster compounds; Germanium; Gold; Structure elucidation; Zintl anions

Indexed keywords

CLUSTER COMPOUNDS; STRUCTURE ELUCIDATION; ZINTL ANIONS;

EID: 34447569412     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200603389     Document Type: Article
Times cited : (96)

References (57)
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    • [2.2.2]crypt = 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo-[8.8.8] hexacosane.
    • [2.2.2]crypt = 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo-[8.8.8] hexacosane.
  • 34
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    • The units I to III have two identical prism heights and one prism height elongated by 7 to 10%. This longest prism height is adjacent to the Ge-Ge exo bond. The homoatomic exo cluster contacts (Ge11-Ge51, Ge21-Ge52, Ge31-Ge53) range from 2.583 Å to 2.617 Å and can be considered as slightly elongated covalent bonds between Ge atoms.
    • The units I to III have two identical prism heights and one prism height elongated by 7 to 10%. This longest prism height is adjacent to the Ge-Ge exo bond. The homoatomic exo cluster contacts (Ge11-Ge51, Ge21-Ge52, Ge31-Ge53) range from 2.583 Å to 2.617 Å and can be considered as slightly elongated covalent bonds between Ge atoms.
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    • [4] with two exo bonds.
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    • 2ν-distorted tetrahedral coordination of the Au atoms and d(Au-Ge) = 2.59-2.62 Å; U. Zachwieja, J. Wlodarski, Z. Anorg. Allg. Chem. 2004, 630, 993.
    • 2ν-distorted tetrahedral coordination of the Au atoms and d(Au-Ge) = 2.59-2.62 Å; U. Zachwieja, J. Wlodarski, Z. Anorg. Allg. Chem. 2004, 630, 993.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.