Influence of the basicity of internal bases in diiron model complexes on hydrides formation and their transformation into protonated diiron hexacarbonyl form

Journal of Organometallic Chemistry

Volumn 695, Issue 5, 2010, Pages 721-729

  Xiao, Zhiyin ^a   Xu, Fenfen ^a   Long, Li ^a   Liu, Yinqiu ^c   Zampella, Giuseppe ^b   Gioia, Luca De ^b   Zeng, Xirui ^c   Luo, Qiuyan ^c   Liu, Xiaoming ^a  

^a NANCHANG UNIVERSITY   (China)

^b UNIVERSITY OF MILANO BICOCCA   (Italy)

^c JINGGANGSHAN UNIVERSITY   (China)

Author keywords

FeFe hydrogenase; Bridging hydride; DFT calculation; Internal base; Model complex

Indexed keywords

BASE MODELS; BRIDGING HYDRIDE; DFT CALCULATION; DIIRON CENTRES; DITHIOLS; FORMATION REACTION; HEXACARBONYL COMPLEX; HYDROGENASES; MODEL COMPLEXES; PENTACARBONYL; PENTACARBONYL COMPLEXES; POSITIVE CORRELATIONS; PROTONATED; SPECTROSCOPIC TECHNIQUE;

HYDRIDES; IRON COMPOUNDS; PROBABILITY DENSITY FUNCTION; PROPANE;

COORDINATION REACTIONS;

EID: 75749143458     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2009.12.007     Document Type: Article

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