Pentadienyls vs cyclopentadienyls and reversal of metal-ligand bonding affinity with metal oxidation state: Synthesis, molecular structures, and electronic structures of high-valent zirconium pentadienyl complexes

Journal of the American Chemical Society

Volumn 126, Issue 43, 2004, Pages 14105-14116

  Rajapakshe, Asha ^a   Gruhn, Nadine E ^a   Lichtenberger, Dennis L ^a   Basta, Rehan ^b   Arif, Atta M ^b   Ernst, Richard D ^b  

^a University of Arizona   (United States)

^b UNIVERSITY OF UTAH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE TRANSFER; ELECTRONIC STRUCTURE; MOLECULAR STRUCTURE; ORGANIC COMPOUNDS; OXIDATION; SYNTHESIS (CHEMICAL); ZIRCONIUM;

CHARGE-TRANSFER BANDS; CYCLOPENTADIENYL; LIGANDS; PENTADIENYLS;

CHEMICAL BONDS;

CYCLOPENTADIENE DERIVATIVE; METAL COMPLEX; ZIRCONIUM;

ARTICLE; BINDING AFFINITY; CHEMICAL ANALYSIS; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; ELECTRONICS; OXIDATION; REACTION ANALYSIS; SYNTHESIS;

EID: 7444271531     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja040123+     Document Type: Article

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