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Volumn 15, Issue 13, 1996, Pages 2923-2931

The carbon-lithium electron pair bond in (CH3Li)n (n = 1, 2, 4)

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EID: 0001118681     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om950966x     Document Type: Article
Times cited : (302)

References (71)
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    • (a) Streitwieser, A., Jr.; Bachrach, S. M.; Dorigo, A. E.; Schleyer, P. v. R. In Lithium Chemistry; Sapse, A. M., Schleyer, P. v. R., Eds.; J. Wiley and Sons: New York, 1995; Chapter 1 and references cited therein.
    • (1995) Lithium Chemistry
    • Streitwieser Jr., A.1    Bachrach, S.M.2    Dorigo, A.E.3    Schleyer, P.V.R.4
  • 2
    • 5344236344 scopus 로고
    • Methoden der Organischen Chemie (Houben-Weyl), Hanack, M., Ed.; Thieme: Stuttgart, Germany
    • (b) Lambert, C.; Schleyer, P. v. R. In Carbanionen. Methoden der Organischen Chemie (Houben-Weyl), Band E19d; Hanack, M., Ed.; Thieme: Stuttgart, Germany, 1993.
    • (1993) Carbanionen , vol.E19D
    • Lambert, C.1    Schleyer, P.V.R.2
  • 4
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    • (c) Lambert, C.; Schleyer, P. v. R. Angew. Chem. 1994, 106, 1187; Angew. Chem., Int. Ed. Engl. 1994, 33, 1129.
    • (1994) Angew. Chem., Int. Ed. Engl. , vol.33 , pp. 1129
  • 20
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    • Sapse, A. M.; Raghavachari, K.; Schleyer, P. v. R.; Kaufmann, E. J. Am. Chem. Soc. 1985, 107, 6483. See also: Rupp, M.; Ahlrichs, R. Theor. Chim. Acta. 1977, 46, 117.
    • (1977) Theor. Chim. Acta , vol.46 , pp. 117
    • Rupp, M.1    Ahlrichs, R.2
  • 24
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    • (a) Günther, H.; Moskau, D.; Bast, P.; Schmalz, D. Angew. Chem. 1987, 99, 1242; Angew. Chem., Int. Ed. Engl. 1987, 26, 1212.
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    • Sapse, A. M., Schleyer, P. v. R., Eds.; Wiley-Interscience: New York, Chapter 5
    • (c) Bauer, W. In Lithium Chemistry; Sapse, A. M., Schleyer, P. v. R., Eds.; Wiley-Interscience: New York, 1995; Chapter 5.
    • (1995) Lithium Chemistry
    • Bauer, W.1
  • 44
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    • Erratum: Ibid. 1986, 34, 7406
    • (l) Perdew, J. P. Phys. Rev. B 1986, 33, 8822. Erratum: Ibid. 1986, 34, 7406.
    • (1986) Phys. Rev. B , vol.33 , pp. 8822
    • Perdew, J.P.1
  • 66
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    • note
    • n systems (counterpoise method) is very small, namely -0.4, -1.1, and -2.8 kcal/mol, and the corresponding charge transfer to lithium of 0.002, 0.003, and 0.006 e is in fact negligible.


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