A perfect couple: PLP/SEC/ESI-MS for the accurate determination of propagation rate coefficients in free radical polymerization

Macromolecular Chemistry and Physics

Volumn 211, Issue 1, 2010, Pages 80-90

  Gruendling, Till ^a,b   Voll, Dominik ^a   Guilhaus, Michael ^b   Barner Kowollik, Christopher ^a  

^a KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^b UNIVERSITY OF NEW SOUTH WALES   (Australia)

Author keywords

Accurate propagation rate coefficients (kp); Arrhenius equation; Electrospray ionization mass spectrometry (ESI MS); Pulsed laser polymerization (PLP); Size exclusion chromatography (SEC)

Indexed keywords

ARRHENIUS EQUATION; BAND-BROADENING; BENCHMARK DATA; BUTYL METHACRYLATES; ELECTROSPRAY IONIZATION MASS SPECTROMETRY; EMPIRICAL MODEL; FIRST-PRINCIPLES; HOMOLOGOUS SERIES; INTERNAL CALIBRATION; KINETIC SIMULATION; MOLECULAR WEIGHT MEASUREMENTS; MULTI-DETECTORS; PROPAGATION RATE COEFFICIENT; PULSED LASER POLYMERIZATION; SHORT CHAIN LENGTHS; SIZE EXCLUSION; UNIVERSAL CALIBRATION;

ATOM TRANSFER RADICAL POLYMERIZATION; CALIBRATION; CHROMATOGRAPHIC ANALYSIS; ELECTROSPRAY IONIZATION; FREE RADICALS; GEL PERMEATION CHROMATOGRAPHY; IONIZATION; MASS SPECTROMETERS; MASS SPECTROMETRY; MOLECULAR WEIGHT DISTRIBUTION; MONOMERS; PARTICLE DETECTORS; PULSED LASER APPLICATIONS; PULSED LASERS; SIZE EXCLUSION CHROMATOGRAPHY;

FREE RADICAL POLYMERIZATION;

EID: 73649121674     PISSN: 10221352     EISSN: 15213935     Source Type: Journal    
DOI: 10.1002/macp.200900394     Document Type: Article

References (68)

1. O. F. Olaj, I. Bitai, F. Hinkelmann, Makromol. Chem. 1987, 188, 1689.
2. C. Barner-Kowollik, T. P. Davis, M. H. Stenzel, Polymer 2004, 45, 7791.
3. S. Beuermann, M. Buback, Prog. Polym. Sci 2002, 27, 191.
4. S. Beuermann, M. Buback, T. P. Davis, R. G. Gilbert, R. A. Hutchinson, O. F. Olaj, G. T. Russell, J. Schweer, A. M. vanHerk, Macromol. Chem. Phys. 1997, 198, 1545.
5. M. Buback, R. G. Gilbert, R. A. Hutchinson, B. Klumperman, F.-D. Kuchta, B. G. Manders, K. F. O'Driscoll, G. T. Russell, J. Schweer, Macromol. Chem. Phys. 1995, 196, 3267.
6. S. Beuermann, M. Buback, T. P. Davis, R. G. Gilbert, R. A. Hutchinson, A. Kajiwara, B. Klumperman, G. T. Russell, Macromol. Chem. Phys. 2000, 201, 1355.
7. S. Beuermann, M. Buback, T. P. Davis, N. Garcia, R. G. Gilbert, R. A. Hutchinson, A. Kajiwara, M. Kamachi, I. Lacik, G. T. Russell, Macromol. Chem. Phys. 2003, 204, 1338.
8. M. Coote, M. D. Zammit, T. P. Davis, Trends Polym. Sci 1996, 4, 189.
9. M. D. Zammit, M. L Coote, T. P. Davis, G. D. Willett, Macromolecules 1998, 31, 955.
10. L. K. Kostanski, D. M. Keller, A. E. Hamielec, J. Biochem. Biophys. Methods 2004, 58, 159.
11. S. Beuermann, M. Buback, Pure Appl. Chem. 1998, 70, 1415.
12. Z. Grubisic, P. Rempp, H. Benoit, J. Polym. Sci B Polym. Lett. 1967, 5, 753.
13. Z. Szablan, M. Huaming, M. Adler, M. H. Stenzel, T. P. Davis, C. Barner-Kowollik, J. Polym. Sci A Polym. Chem. 2007, 45, 1931.
14. T. P. Davis, K. F. O'Driscoll, M. C. Piton, M. A. Winnik, Macromolecules 1990, 23, 2113.
15. R. A. Hutchinson, S. Beuermann, D. A. Paquet, J. H. McMinn, Macromolecules 1997, 30, 3490.
16. R. A. Hutchinson, D. A. Paquet, J. H. McMinn, R. E. Fuller, Macromolecules 1995, 28, 4023.
17. P. Pascal, M. A. Winnik, D. H. Napper, R. G. Gilbert, Macromol. Rapid Commun. 1993, 14, 213.
18. M. Buback, U. Geers, C. H. Kurz, Macromol. Chem. Phys. 1997, 198, 3451.
19. J. P. A. Heuts, R. G. Gilbert, L. Radom, Macromolecules 1995, 28, 8771.
20. D. M. Huang, M. J. Monteiro, R. G. Gilbert, Macromolecules 1998, 31, 5175.
21. I. Degirmenci, D. Avci, V. Aviyente, K. Van Cauter, V. Van Speybroeck, M. Waroquier, Macromolecules 2007, 40, 9590.
22. I. Degirmenci, V. Aviyente, V. Van Speybroeck, M. Waroquier, Macromolecules 2009, 42, 3033.
23. E. I. Izgorodina, M. L. Coote, Chem. Phys. 2006, 324, 96.
24. K. Van Cauter, V. Van Speybroeck, P. Vansteenkiste, M.-F. Reyniers, M. Waroquier, Chem. Phys. Chem. 2006, 7, 131.
25. M. D. Zammit, M. L Coote, T. P. Davis, G. D. Willett, Macromolecules 1998, 31, 955.
26. M. D. Zammit, T. P. Davis, Polymer 1997, 38, 4455.
27. I. Schnoll-Bitai, C. Mader, J. Chromatogr., A 2006, 1137, 198.
28. M. Buback, M. Busch, R. A. Lämmel, Macromol. Theory Simul. 1996, 5, 845.
29. I. Schnöll-Bitai, C. Mader, Macromol. Symp. 2007, 248, 33.
30. O. F. Olaj, P. Vana, M. Zoder, A. Kornherr, G. Zifferer, Macromol. Rapid Commun. 2000, 21, 913.
31. R. X. E. Willemse, B. B. P. Staal, A. M. van Herk, S. C. J. Pierik, B. Klumperman, Macromolecules 2003, 36, 9797.
32. J. P. A. Heuts, G. T. Russell, G. B. Smith, A. M. v. Herk, Macromol. Symp. 2007, 248, 12.
33. A. A. Gridnev, S. D. Ittel, Macromolecules 1996, 29, 5864.
34. G. Moad, E. Rizzardo, D. H. Solomon, A. L. J. Beckwith, Polym. Bull. 1992, 29, 647.
35. O. F. Olaj, M. Zoder, P. Vana, A. Kornherr,I. Schnöll-Bitai, G. Zifferer, Macromolecules 2005, 38, 1944.
36. G. Montaudo, S. Carroccio, A. S. Montaudo, C. Puglisi, F. Samperi, Macromol. Symp. 2004, 218, 101.
37. G. Montaudo, F. Samperi, M. S. Montaudo, Prog. Polym. Sci. 2006, 31, 277.
38. P. M. Peacock, C. N. McEwen, Anal. Chem. 2004, 76, 3417.
39. P. M. Peacock, C. N. McEwen, Anal. Chem. 2006, 78, 3957.
40. D. C. Schriemer, L. Li, Anal. Chem. 1997, 69, 4176.
41. H. C. M. Byrd, C. N. McEwen, Anal. Chem. 2000, 72, 4568.
42. D. C. Schriemer, L. Li, Anal. Chem. 1997, 69, 4169.
43. B. Guo, H. Chen, H. Rashidzadeh, X. Liu, Rapid Commun. Mass Spectrosc. 1997, 11, 781.
44. P. Malvagna, G. Impallomeni, R. Cozzolino, E. Spina, D. Garozzo, Rapid Commun. Mass Spectrosc. 2002, 16, 1599.
45. I. Schnöll-Bitai, T. Hrebicek, A. Rizzi, Macromol. Chem. Phys. 2007, 208, 485.
46. C. M. Guttman, K. M. Flynn, W. E. Wallace, A. J. Kearsley, Macromolecules 2009, 42, 1695.
47. C. Bamer-Kowollik, P. Vana, P. D. Thomas, J. Polym. Sci. A Polym. Chem. 2002, 40, 675.
48. P. O. Danis, D. E. Karr, D. G. Westmoreland, M. C. Piton, D. I. Christie, P. A. Clay, S. H. Kable, R. G. Gilbert, Macromolecules 1993, 26, 6684.
49. J. Schweer, J. Sarnecki, F. Mayer-Posner, K. Müllen, H. J. Rader, J. Spickermann, Macromolecules 1996, 29, 4536.
50. M. D. Zammit, T. P. Davis, D. M. Haddleton, Macromolecules 1996, 29, 492.
51. C. M. Guttman, K. M. Flynn, W. E. Wallace, A. J. Kearsley, Macromolecules 2009, 42, 1695.
52. H. Sato, N. Ichieda, H. Tao, H. Ohtani, Anal Sci. 2004, 20, 1289.
53. M. S. Montaudo, C. Puglisi, F. Samperi, G. Montaudo, Rapid Commun. Mass Spectrosc. 1998, 12, 519.
54. T. Gruendling, M. Guilhaus, C. Barner-Kowollik, Anal. Chem. 2008, 80, 6915.
55. D. J. Aaserud, L. Prokai, W. J. Simonsick, Anal. Chem. 1999, 71, 4793.
56. L. Prokai, W. J. Simonsick, Rapid Commun. Mass Spectrosc. 1993, 7, 853.
57. T. Gruendling, T. Junkers, M. Guilhaus, C. Barner-Kowollik, Macromol. Chem. Phys. 2009, DOI: 10.1002/macp.200900323.
58. T. Gruendling, R. Pickford, M. Guilhaus, C. Barner-Kowollik, J. Polym. Sci A Polym. Chem. 2008, 46, 7447.
59. T. Gruendling, Guilhaus, C. Barner-Kowollik, Macromolecules 2009, 42, 6366.
60. T. Gruendling, M. Guilhaus, C. Barner-Kowollik, Anal. Chem. 2008, 80, 6915.
61. T. Gruendling, M. Guilhaus, C. Barner-Kowollik, Macromol. Rapid Commun. 2009, 30, 589.
62. A. Rudin, H. L. W. Hoegy, J. Polym. Sci A-1 1972, 10, 217.
63. A. L. Spatorico, B. Coulter, J. Polym. Sei Polym. Phys. Ed. 1973, 11, 1139.
64. A. M. Van Herk, T. Droge, Macromol. Theory Simul. 1997, 6, 1263.
65. nd edition, Oxford University Press, Oxford 2007.
66. F. Günzler, E. H. H. Wong, S. P. S. Koo, T. Junkers, C. BarnerKowollik, Macromolecules 2009, 42, 1488.
67. Z. Szablan, T. Junkers, S. P. S. Koo, T. Lovestead, T. P. Davis, M. H. Stenzel, C. Barner-Kowollik, Macromolecules 2007, 40, 6820.
68. S. Beuermann, Macromolecules 2002, 35, 9300.