Effect of the ester side-chain on the propagation kinetics of alkyl methacrylates - An entropic or enthalpic effect?

Macromolecules

Volumn 31, Issue 4, 1998, Pages 955-963

  Zammit, Michael D ^a,b   Coote, Michelle L ^a   Davis, Thomas P ^a   Willett, Gary D ^a  

^a UNIVERSITY OF NEW SOUTH WALES   (Australia)

^b DuluxGroup (Australia)   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

ENTHALPY; ENTROPY; LIGHT SCATTERING; MOLECULAR WEIGHT DISTRIBUTION; POLYMETHYL METHACRYLATES; POLYSTYRENES; PULSED LASER APPLICATIONS; REACTION KINETICS; REFRACTIVE INDEX; SIZE EXCLUSION CHROMATOGRAPHY; VISCOSITY MEASUREMENT;

DIFFERENTIAL REFRACTIVE INDEX; DIFFERENTIAL VISCOMETRY; LOW ANGLE LASER LIGHT SCATTERING; POLYBENZYL METHACRYLATE; POLYBUTYL METHACRYLATE; POLYETHYL METHACRYLATE; PULSED LASER POLYMERIZATION;

POLYMERIZATION;

EID: 0031998203     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9707291     Document Type: Article

References (29)

1. Davis, T. P.; O'Driscoll, K. F.; Piton, M. C.; Winnik, M. A. Macromolecules 1990, 23, 2113.
2. (a) Pascal, P.; Winnik, M. A.; Napper, D. H.; Gilbert, R. G. Makromol. Chem. Rapid Commun. 1993, 14, 213.
3. (b) Questions relating to the accuracy of the Arrhenius parameters reported in this paper have been raised by the original authors, who point out that this work preceded the IUPAC recommendations for PLP consistency checks.
4. Hutchinson, R. A.; Paquet, D. A., Jr.; McMinn, J. H.; Fuller, R. E. Macromolecules 1995, 28, 4023.
5. Hutchinson, R. A.; Paquet, D. A., Jr.; McMinn, J. H.; Beuermann, S.; Fuller, R. E.; Jackson, C. DECHEMA Monogr. 1995, 131, 467.
6. Hutchinson, R. A.; Beuermann, S.; Paquet, D. A., Jr.; McMinn, J. H. Macromolecules 1997, 30, 3490.
7. See, for example: Plate, N. A.; Ponomarenko, A. G. Polym. Sci. USSR 1974, 16, 3067 and references cited therein.
8. See, for example: Coote, M. L.; Zammit, M. D.; Davis, T. P. Trends Polym. Sci. 1996, 4, 189 and references cited therein.
9. Buback, M.; Gilbert, R. G.; Hutchinson, R. A.; klumperman, B.; Kuchta, F.-D.; Manders, B. G.; O'Driscoll, K. F.; Russell, G. T.; Schweer, J. Macromol. Chem. Phys. 1995, 196, 3267.
10. Beuermann, S.; Buback, M.; Davis, T. P.; Gilbert, R. G.; Hutchinson, R. A.; Olaj, O. F.; Russell, G. T.; Schweer, J.; van Herk, A. M. Macromol. Chem. Phys. 1997, 198, 1545.
11. Coote, M. L.; Zammit, M. D.; Davis, T. P.; Willett, G. D. Macromolecules 1997, 30, 8182.
12. Davis, T. P.; Zammit, M. D. Macromol. Symp. 1996, 111, 243.
13. Davis, T. P.; O'Driscoll, K. F.; Piton, M. C.; Winnik, M. A. Macromolecules 1989, 22, 2785.
14. Polymer Laboratories. PL Caliber GPC/SEC Viscometry and LALLS Software version 6.0. Polymer Laboratories Ltd., Essex Road, Church Stretton, Shropshire, SY6 6AX UK, 1995.
15. Rudin, A.; Hoegy, H. L. W. J. Polym. Sci. - Part A1 1972, 10, 217.
16. Benoit, H.; Grubisic, Z.; Rempp, P.; Decker, D.; Zilliox, J. J. Chim. Phys. 1966, 63, 1507.
17. Zammit, M. D.; Davis, T. P. Polymer 1997, 38, 4455.
18. Suddaby, K. G.; Sanayei, R.; O'Driscoll, K. F.; Rudin, A. Makromol. Chem. 1993, 194, 1965.
19. Mourey, T. H.; Balke, S. T. In Chromatography of Polymers, Characterization by SEC and FFF; Provder, T., Ed.; ACS Symposium Series 521; American Chemical Society: Washington DC, 1993; p 180.
20. Samay, G.; Kubin, M.; Podesva, J. J. Angew. Makromol. Chem. 1978, 72, 185.
21. (a) Lyons,R. A.; Heuts, J. P. A. Presented at the 21st Australian Polymer Symposium, Wollongong, NSW, Australia, 1996, p 30 RACI.
22. 4
23. Hutchinson, R. A.; Aronson, M. T.; Richards, J. R. Macromlecules 1993, 26, 6410.
24. Stickler, M.; Meyerhoff, G. Makromol. Chem. 1978, 179, 2729.
25. Coulter, K. E.; Kehde, H.; Hiscock, B. F. Styrene and Related Monomers; Coulter, K. E.; Kehde, H.; Hiscock, B. F., Ed.; Wiley-Interscience: New York, 1971; Vol. 2.
26. Van Herk, A. M. Contour, available from the author: Laboratory of Polymer Chemistry, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven, The Netherlands, 1996.
27. Heuts, J. P. A.; Coote, M. L.; Davis, T. P.; Johnston, L. P. M. ACS Symp. Ser., in press.
28. Mahabadi, H. K.; O'Driscoll, K. F. J. Appl. Polym. Sci. 1977, 21, 1283.
29. Heuts, J. P. A. Dynamics of Propagation and Transfer Reactions in Free-Radical Polymerisation. A Theoretical Study; PhD Thesis; University of Sydney, 1996.