Copper complexes with non-innocent ligands: Probing CuII/catecholato-CuI/o-semiquinonato redox isomer equilibria with EPR spectroscopy

Inorganica Chimica Acta

Volumn 337, Issue , 2002, Pages 163-172

  Kaim, Wolfgang ^a   Wanner, Matthias ^a   Knödler, Axel ^a   Záliš, Stanislav ^b  

^a UNIVERSITY OF STUTTGART   (Germany)

^b J HEYROVSKÝ INSTITUTE OF PHYSICAL CHEMISTRY   (Czech Republic)

Author keywords

Copper compounds; EPR spectroscopy; Quinone ligands; Redox isomerism; Structure

Indexed keywords

CHLORINE COMPOUNDS; ELECTRON SPIN RESONANCE SPECTROSCOPY; ISOMERS; LIGANDS; NITROGEN COMPOUNDS; PARAMAGNETIC RESONANCE; QUINONE; STEREOCHEMISTRY; STRUCTURE (COMPOSITION);

COORDINATION PATTERNS; COPPER (I) COMPLEXES; DISPROPORTIONATIONS; ELECTRON TRANSFER; EPR SPECTROSCOPY; NON-INNOCENT LIGANDS; REDOX ISOMERISM; TEMPERATURE DEPENDENT;

COPPER COMPOUNDS;

1 DIPHENYLPHOSPHINO 2 DIMETHYLAMINOETHANE; 1 METHYL(2 METHYLTHIOMETHYL) 1H BENZIMIDAZOLE; BENZIMIDAZOLE DERIVATIVE; COPPER COMPLEX; ETHYLAMINE; LIGAND; NITROGEN; OXIDOREDUCTASE; PHOSPHORUS; QUINONE DERIVATIVE; SEMIQUINONE; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CHEMICAL ANALYSIS; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; ISOMER; OXIDATION; OXIDATION REDUCTION REACTION; STRUCTURE ANALYSIS; TEMPERATURE DEPENDENCE;

EID: 0037179984     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(02)01081-2     Document Type: Article

References (54)

1. Jørgensen C.K. Oxidation Numbers and Oxidation States. 1969;291 Springer, Berlin.
2. McWhinnie W.R., Miller J.D. Adv. Inorg. Chem. Radiochem. 12:1969;135.
3. Burns R.P., McAuliffe C.A. Adv. Inorg. Chem. Radiochem. 22:1979;303.
4. Pierpont C.G., Lange C.W. Prog. Inorg. Chem. 41:1994;331.
5. Herebian D., Bothe E., Bill E., Weyhermüller T., Wieghardt K. J. Am. Chem. Soc. 123:2001;10012.
6. Pierpont C.G. Coord. Chem. Rev. 216-217:2001;99.
7. Caneschi A., Dei A., Fabrizi de Biani F., Gütlich P., Ksenofontov V., Levchenko G., Hoefer A., Renz F. Chem. Eur. J. 7:2001;3926.
8. Lynch M.W., Hendrickson D.N., Fitzgerald B.J., Pierpont C.G. J. Am. Chem. Soc. 106:1984;2041.
9. Dooley D.M., McGuirl M.A., Brown D.E., Turowski P.N., McIntire W.S., Knowles P.F. Nature (Lond.). 349:1991;262.
10. Wilmot C.M., Hajdu J., McPherson M.J., Knowles P.F., Phillips S.E.V. Science. 286:1999;1724.
11. Rall J., Waldhör E., Schwederski B., Schwach M., Kohlmann S., Kaim W. Trautwein A.X., Bioinorganic Chemistry: Transition Metals in Biology and their Coordination Chemistry. 1997;476 VCH, Weinheim.
12. Rall J., Wanner M., Albrecht M., Hornung F.M., Kaim W. Chem. Eur. J. 5:1999;2802.
13. Speier G., Tyeklár Z., Töth P., Speier E., Tisza S., Rockenbauer A., Whalen A.M., Alkire N., Pierpont C.G. Inorg. Chem. 40:2001;5653;
14. See also G.A. Abakumov, V.A. Garnov, V.I. Nevodchikov, V.K. Cherkasov, Dokl. Akad. Nauk SSSR 304 (1989) 109.
15. Albrecht M., Hübler K., Zalis S., Kaim W. Inorg. Chem. 39:2000;4731.
16. Albrecht M., Hübler K., Scheiring T., Kaim W. Inorg. Chim. Acta. 287:1999;204.
17. Schwederski B., Kasack V., Kaim W., Roth E., Jordanov J. Angew. Chem. 102:1990;74.
18. Schwederski B., Kasack V., Kaim W., Roth E., Jordanov J. Angew. Chem., Int. Ed. Engl. 29:1990;78.
19. Wanner M., Sixt T., Klinkhammer K.-W., Kaim W. Inorg. Chem. 38:1999;2753.
20. Itoh S., Kawakami H., Fukuzumi S. J. Am. Chem. Soc. 120:1998;7271. and references therein.
21. Itoh S., Kawakami H., Fukuzumi S. J. Am. Chem. Soc. 119:1997;439.
22. Malet R., Moreno-Manas M., Parella T., Pleixats R. J. Org. Chem. 61:1996;758.
23. Rall J., Kaim W. J. Chem. Soc., Faraday Trans. 90:1994;2905. and literature cited.
24. Goodman B.A., Raynor J.B. Adv. Inorg. Chem. Radiochem. 13:1970;135.
25. Mabbs F.E., Collison D. Electron Paramagnetic Resonance of d-Transition Metal Compounds. 1992;Elsevier, Amsterdam.
26. Müller E., Günter F., Scheffler K., Ziemek P., Rieker A. Liebigs. Ann. Chem. 688:1965;134.
27. Lybchenko L.S., Lakaev S.G., Lyuĺkin Y.A., Prokof'ev A.I. Zh. Fiz. Khim. 55:1981;1216.
28. Vlcek A. Jr. J. Organomet. Chem. 306:1986;63.
29. Vincow G., Fraenkel G.F. J. Chem. Phys. 34:1961;1333.
30. Vogler C., Kaim W., Hausen H.-D. Z. Naturforsch. 48b:1993;1470;
31. A.F. Stange, T. Sixt, W. Kaim, J. Chem. Soc., Chem. Commun. (1998) 469.
32. Schwach M., Hausen H.-D., Kaim W. Inorg. Chem. 38:1999;2242.
33. Alberti A., Camaggi C.M. J. Organomet. Chem. 181:1979;355.
34. Kaim W. Coord. Chem. Rev. 76:1987;187.
35. Abakumov G.A., Lobanov A.V., Cherkasov V.K., Razuvaev G.A. Inorg. Chim. Acta. 49:1981;135.
36. M. Wanner, M. Seiler, W. Kaim, H. Bertagnolli, work in progress.
37. Doslik N., Sixt T., Kaim W. Angew. Chem. 110:1998;2521.
38. Doslik N., Sixt T., Kaim W. Angew. Chem., Int. Ed. 37:1998;2403.
39. Ainscough E.W., Brodie A.M., Ingham S.L., Waters J.M. Inorg. Chim. Acta. 217:1994;191.
40. F. Tisato, F. Refosco, G. Bandoli, G. Pilloni, B. Corain, J. Chem. Soc., Dalton Trans. (1994) 2471.
41. G. Pilloni, G. Bandoli, F. Tisato, B. Corain, Chem. Commun. (1996) 433.
42. Haga M., Dodsworth E.S., Lever A.B.P. Inorg. Chem. 25:1986;447.
43. Lever A.B.P., Auburn P.R., Dodsworth E.S., Haga M., Liu W., Melnik M., Nevin W.A. J. Am. Chem. Soc. 110:1988;8076.
44. Masui H., Lever A.B.P., Auburn P.R. Inorg. Chem. 30:1991;2402.
45. Lever A.B.P., Masui H., Metcalfe R.A., Stufkens D.J., Dodsworth E.S., Auburn P.R. Coord. Chem. Rev. 125:1993;317.
46. Ernst S., Hänel P., Jordanov J., Kaim W., Kasack V., Roth E. J. Am. Chem. Soc. 111:1989;1733.
47. Kasack V., Kaim W., Binder H., Jordanov J., Roth E. Inorg. Chem. 34:1995;1924.
48. (a) W. Kaim, M. Moscherosch, J. Chem. Soc., Faraday Trans. 87:1991;3185;
49. (b) M. Moscherosch, J.S. Field, W. Kaim, S. Kohlmann, M. Krejcik, J. Chem. Soc., Dalton Trans. (1993) 211.;
50. A.-L. Barra, L.-C. Brunel, F. Baumann, M. Schwach, M. Moscherosch, W. Kaim, J. Chem. Soc., Dalton Trans. (1999) 3855.
51. Sheldrick G.M. SHELXTL-PLUS, Relat. 5.03. 1989;Siemens Analytical X-ray Insturments Inc, Madison, Wl.
52. Fonseca Guerra C., Snijders J.G., te Velde G., Baerends E.J. Theor. Chem. Acc. 99:1998;391.
53. Becke A.D. Phys. Rev. A. 38:1988;3098.
54. Perdew J.P. Phys. Rev. A. 33:1986;8822.