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Volumn 15, Issue 44, 2009, Pages 11808-11814

First heterotrimetallic {3 d-4 d-4 f} single chain magnet, constructed from anisotropic high-spin heterometallic nodes and paramagnetic spacers

Author keywords

Copper; Lanthanides; Magnetic properties; Molybdenum; Single chain magnets

Indexed keywords

1D COORDINATION POLYMER; BRIDGING MODE; CATIONIC SPECIES; CYANO-BRIDGED; HETEROMETALLICS; HETERONUCLEAR; LANTHANIDES; MONONUCLEAR COPPER; ORGANIC LIGANDS; PARAMAGNETIC SPACERS; PHENOLIC RINGS; RING CONTACTS; SINGLE-CHAIN MAGNET; SINGLE-CHAIN MAGNETS; TRIMETALLIC;

EID: 73249125085     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200902408     Document Type: Article
Times cited : (217)

References (80)
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    • note
    • According to the original proposal,[21a,b] the exchange coupling between two spins S=1/2 can be estimated from the energies of the high spin (EHS) and the broken-symmetry (EBS) configurations as J=2ACHTUNGTRENUNG(EBSEHS), while in practice the expression J=EBSEHS is recommended when the B3LYP functional is used.[21c]
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    • In the present compounds the decreasing of the CN-Cu angle enhances the hybridization of p,p*(CN) orbitals with the dx2y2(Cu) orbital (this hybridization vanishes for the maximal angle of 1808)
    • In the present compounds the decreasing of the CN-Cu angle enhances the hybridization of p,p*(CN) orbitals with the dx2y2(Cu) orbital (this hybridization vanishes for the maximal angle of 1808).
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.