Heterometallic [Mn5-Ln4] single-molecule magnets with high anisotropy barriers

Chemistry - A European Journal

Volumn 14, Issue 12, 2008, Pages 3577-3584

  Mereacre, Valeriu ^a   Ako, Ayuk M ^a   Clérac, Rodolphe ^b   Wernsdorfer, Wolfgang ^c   Hewitt, Ian J ^a   Anson, Christopher E ^a   Powell, Annie K ^a  

^a UNIVERSITY OF KARLSRUHE   (Germany)

^b UNIVERSITÉ DE BORDEAUX   (France)

^c LABORATOIRE DE CRISTALLOGRAPHIE   (France)

Author keywords

Cluster compounds; Lanthanides; Magnetic properties; Manganese; Single molecule magnets

Indexed keywords

MAGNETIC MATERIALS; MAGNETIC PROPERTIES; MAGNETS; MANGANESE; METALLIC COMPOUNDS; MOLECULES; RARE EARTH ELEMENTS; X RAY DIFFRACTION;

CLUSTER COMPOUNDS; HETEROMETALLICS; HIGH ANISOTROPY; N-METHYLDIETHANOLAMINE; SINGLE CRYSTAL X-RAY DIFFRACTION; SINGLE-MOLECULE MAGNET; SLOW RELAXATIONS; SQUID MEASUREMENTS;

SINGLE CRYSTALS;

EID: 47049090965     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200800125     Document Type: Article

References (54)

1. a) P. D. W. Boyd, Q. Li, J. B. Vincent, K. Folting, H.-R. Chang, W. E. Streib, J. C. Huffman, G. Christou, D. N. Hendrickson, J. Am. Chem. Soc. 1988, 110, 8537 - 8539;
2. b) A. Caneschi, D. Gatteschi, R. Sessoli, J. Am. Chem. Soc. 1991, 113, 5873 -5874;
3. c) R. Sessoli, H.-L. Tsai, A. R. Schake, S. Wang, J. B. Vincent, K. Folting, D. Gatteschi, G. Christou, D. N. Hendrickson J. Am. Chem. Soc. 1993, 115, 1804 -1816;
4. d) R. Sessoli, D. Gatteschi, A. Caneschi, M. A. Novak, Nature 1993, 365, 141 -143.
5. T . Lis, Acta Crystallogr. Sect. B 1980, 36, 2042 -2046.
6. [3]a) D. Gatteschi, R. Sessoli, Angew. Chem. 2003, 115, 278 - 309;
7. Angew. Chem. Int. Ed. 2003, 42, 268 - 297;
8. b) R. Bircher, G. Chaboussant, C. Dobe, H. U. GDdel, S. T. Ochsenbein, A. Sieber, O. Waldmann, Adv. Funct. Mater. 2006, 16, 209 -220;
9. c) O. Waldmann, Inorg. Chem. 2007, 46, 10035 - 10037.
10. a) G. Christou, D. Gatteschi, D. N. Hendrickson, R. Sessoli, MRS Bull. 2000, 25, 66 -71;
11. b) J. P. Price, S. R. Batten, B. Moubaraki, K. S. Murray, Chem. Commun. 2002, 762 -763;
12. c) E. C. Sanudo, W. Wernsdorfer, K. A. Abboud, G. Christou, Inorg. Chem. 2004, 43, 4137 - 4144.
13. D . N. Hendrickson, G. Christou, H. Ishimoto, J. Yoo, E. K. Brechin, A. Yamaguchi, E. M. Rumberger, S. M. J. Aubin, Z. Sun, G. Aromi, Polyhedron 2001, 20, 1479 -1488.
14. a) E. K. Brechin, M. Soler, G. Christou, J. Davidson, D. N. Hendrickson, S. Parsons, W. Wernsdorfer, Polyhedron 2003, 22, 1771 -1775;
15. b) E. K. Brechin, M. Soler, G. Christou, M. Helliwell, S. J. Teat, W. Wernsdorfer, Chem. Commun. 2003, 11, 1276 - 1277.
16. a) H. Miyasaka, R. Clérac, W. Wernsdorfer, L. Lecren, C. Bonhomme, K. Sugiura, M. Yamashita, Angew. Chem. 2004, 116, 2861 -2865;
17. Angew. Chem. Int. Ed. 2004, 43, 2801 -2805;
18. b) H. Miyasaka, T. Nezu, K. Sugimoto, K. Sugiura, M. Yamashita, R. Clérac, Chem. Eur. J. 2005, 11, 717 - 724;
19. c) L. Lecren, W. Wernsdorfer, Y.-G. Li, O. Roubeau, H. Miyasaka, R. Clérac, J. Am. Chem. Soc. 2005, 127, 11311 - 11317;
20. d) C. Kachi-Terajima, H. Miyasaka, K.-i Sugiura, R. Cléac, H. Nojiri, Inorg. Chem. 2006, 45, 4381 - 4390;
21. e) C. Kachi-Terajima, H. Miyasaka, A. Saitoh, N. Shirakawa, M. Yamashita, R. Clérac, Inorg. Chem. 2007, 46, 5861 - 5872.
22. a) C. J. Milios, A. Vinslava, W. Wernsdorfer, S. Moggach, S. Parsons, S. P. Perlepes, G. Christou, E. K. Brechin, J. Am. Chem. Soc. 2007, 129, 2754 -2755;
23. b) C. J. Milios, A. Vinslava, W. Wernsdorfer, A. Prescimone, P. A. Wood, S. Parsons, S. P. Perlepes, G. Christou, E. K. Brechin, J. Am. Chem. Soc. 2007, 129, 6547 - 6561.
24. a) F. Mori, T. Ishida, T. Nogani, Polyhedron 2005, 24, 2588 -2592;
25. b) M. Murugesu, A. Mishra, W. Wernsdorfer, K. A. Abboud G. Christou, Polyhedron 2006, 25, 613 -625;
26. c) M. Ferbinteanu, T. Kajiwara, K.-Y. Choi, H. Nojiri, A. Nakamoto, N. Kojima, F. Cimpoesu, Y. Fujimura, S. Takaishi, M. Yamashita, J. Am. Chem. Soc. 2006, 128, 9008 - 9009;
27. d) J.-P. Costes, J.-M. Clemente-Juan, F. Dahan, J. Milon, Inorg. Chem. 2004, 43, 8200 -8202;
28. e) J.-P. Costes, F. Dahan, W. Wernsdorfer, Inorg. Chem. 2006, 45, 5-7.
29. a) F. Mori, T. Nyui, T. Ishida, T. Nogami, K-Y. Choi, H. Nojiri, J. Am. Chem. Soc. 2006, 128, 1440 -1441;
30. b) S. Osa, T. Kido, N. Matsumoto, N. Re, A. Pochaba, J. Mrozinski, J. Am. Chem. Soc. 2004, 126, 420 - 421.
31. a) C. Aronica, G. Pilet, G. Chastanet, W. Wernsdorfer, J.-F. Jacquot, D. Luneau, Angew. Chem. 2006, 118, 4775 - 4778;
32. Angew. Chem. Int.Ed. 2006, 45, 4659 - 4662;
33. b) V. Chandrasekhar, B. M. Pandian, R. Azhakar, J. J. Vittal, R. Clérac, Inorg. Chem. 2007, 46, 5140 -5142.
34. M. Mereacre, A. M. Ako, R. Clérac, W. Wernsdorfer, G. Filoti, J. BartolomJ, C. E. Anson, A. K. Powell, J. Am. Chem. Soc. 2007, 129, 9248 - 9249.
35. A. M. Ako, V. Mereacre, I. J. Hewitt, R. Clérac, L. Lecren, C. E. Anson, A. K. Powell, J. Mater. Chem. 2006, 16, 2579 -2586.
36. a) A. Mishra, W. Wernsdorfer, K. A. Abboud, G. Christou, J. Am. Chem. Soc. 2004, 126, 15648 -15649;
37. b) C. Zaleski, E. Depperman, J. Kampf, M. Kirk, V. Pecoraro, Angew. Chem. 2004, 116, 4002 - 4004;
38. Angew. Chem. Int. Ed. 2004, 43, 3912 - 3914;
39. c) A. Mishra, W. Wernsdorfer, S. Parson, G. Christou, E. Brechin, Chem. Commun. 2005, 2086 - 2088.
40. W . Liu, H. H. Thorp, Inorg. Chem. 1993, 32, 4102 - 4105.
41. a) J. J. Borrás-Almenar, J. M. Clemente-Juan, E. Coronado, B. S. Tsukerblat, Inorg. Chem. 1999, 38 , 6081 - 6088;
42. b) J. J. BorrWs-Almenar, J. M. Clemente-Juan, E. Coronado, B. S. Tsukerblat, J. Comput. Chem. 2001, 22, 985 - 991.
43. W . Wernsdorfer, Adv. Chem. Phys. 2001, 118, 99-190.
44. W . Wernsdorfer, N. E. Chakov, G. Christou, Phys. Rev. B 2004, 70, 132413/1- 132413/4.
45. D . Foguet-Albiol, T. A. O'Brien, W. Wernsdorfer, B. Moulton, M. Zaworotko, K. A. Abboud, G. Christou, Angew. Chem. 2005, 117, 919 - 923;
46. Angew. Chem. Int. Ed. 2005, 44, 897 -901.
47. a) A. M. Ako, I. J. Hewitt, V. Mereacre, R. Clérac, W. Wernsdorfer, C. E. Anson, A. K. Powell, Angew. Chem. 2006, 118, 5048 -5051;
48. Angew. Chem. Int. Ed. 2006, 45, 4926 - 4929;
49. b) A. J. Tasiopoulos, A. Vinslava, W. Wernsdorfer, K. A. Abboud, G. Christou Angew. Chem. 2004, 116, 2169-2173;
50. Angew. Chem. Int. Ed. 2004, 43, 2117 -2121;
51. Angew. Chem. Int. Ed. 2004, 43, 2117 - 2121;
52. c) H. Miyasaka, K. Nakata, L. Lecren, C. Coulon, Y. Nakazawa, T. Fujisaki, K. Sugiura, M. Yamashita, R. Clérac, J. Am. Chem. Soc. 2006, 128, 3770 -3783.
53. a) G. M.Sheldrick, SADABS (the Siemens Area Detector Absorption Correction), University of Gçttingen, 1996;
54. b) G. M. Sheldrick, SHELXTL 6.14, Bruker AXS Inc., 6300 Enterprise Lane, Madison, WI 53719 - 1173, USA, 2003.