Synthesis, structure, and magnetic properties of a large lanthanide-transition-metal single-molecule magnet

Angewandte Chemie - International Edition

Volumn 43, Issue 30, 2004, Pages 3912-3914

  Zaleski, Curtis M ^b   Depperman, Ezra C ^a   Kampf, Jeff W ^b   Kirk, Martin L ^a   Pecoraro, Vincent L ^b  

^a UNIVERSITY OF NEW MEXICO   (United States)

^b UNIVERSITY OF MICHIGAN   (United States)

Author keywords

Cluster compounds; Dysprosium; Lanthanides; Magnetic properties; Manganese

Indexed keywords

DYSPROSIUM COMPOUNDS; MAGNETIC PROPERTIES; MANGANESE; MOLECULAR STRUCTURE; SYNTHESIS (CHEMICAL);

MIXED-METAL TOPOLOGY; STEREOPICTURES; TRIMERS;

MAGNETS;

DYSPROSIUM; ION; LANTHANIDE; MANGANESE; MANGANESE DERIVATIVE; METAL COMPLEX; SALICYLHYDROXAMIC ACID; TRANSITION ELEMENT;

ARTICLE; CHEMICAL STRUCTURE; MAGNET; MAGNETISM; MOLECULE; SYNTHESIS;

EID: 4544335196     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200454013     Document Type: Article

References (31)

1. a) D. Freedman, T. J. Emge, J. G. Brennan, J. Am. Chem. Soc. 1997, 119, 11112-11113;
2. b) R. Wang, Z. Zheng, T. Jin, R. J. Staples, Angew. Chem. 1999, 111, 1929-1932; Angew. Chem. Int. Ed. 1999, 38, 1813-1815;
3. b) R. Wang, Z. Zheng, T. Jin, R. J. Staples, Angew. Chem. 1999, 111, 1929-1932; Angew. Chem. Int. Ed. 1999, 38, 1813-1815;
4. c) M. R. Bürgstein, P. W. Roesky, Angew. Chem. 2000, 112, 559-562; Angew. Chem. Int. Ed. 2000, 39, 549-551;
5. c) M. R. Bürgstein, P. W. Roesky, Angew. Chem. 2000, 112, 559-562; Angew. Chem. Int. Ed. 2000, 39, 549-551;
6. d) J. Xu, K. N. Raymond, Angew. Chem. 2000, 112, 2857-2859; Angew. Chem. Int. Ed. 2000, 39, 2745-2747;
7. d) J. Xu, K. N. Raymond, Angew. Chem. 2000, 112, 2857-2859; Angew. Chem. Int. Ed. 2000, 39, 2745-2747;
8. e) Y. Bretonnière, M. Mazzanti, J. Pécaut, M. M. Olmstead, J. Am. Chem. Soc. 2002, 124, 9012-9013;
9. f) N. Fatin-Rouge, É. Tóth, D. Perret, R. H. Backer, A. Merbach, J.-C. G. BUnzli, J. Am. Chem. Soc. 2000, 122, 10810-10820;
10. g) L. G. Westin, M. Kritikos, A. Caneschi, Chem. Commun. 2002, 1012-1013.
11. a) M. Andruh, I. Ramade, E. Codjovi, O. Guillou, O. Kahn, J. C. Trombe, J. Am. Chem. Soc. 1993,115,1822-1829;
12. b) X.-M. Chen, S. M. J. Aubin, Y.-L. Wu, Y.-S. Yang, T. C. W. Mak, D. N. Hendrickson, J. Am. Chem. Soc. 1995, 117, 9600-9601;
13. c) R.E.P. Winpenny, Chem. Soc. Rev. 1998, 27, 447-452;
14. d) A. J. Stemmler, J. W. Kampf, M. L. Kirk, B. H. Atasi, V. L. Pecoraro, Inorg. Chem. 1999, 38, 2807-2817;
15. e) C. Benelli, D. Gatteschi, Chem. Rev. 2002, 102, 2369-2387.
16. a) R. A. Reyonlds III, D. Coucouvanis, J. Am. Chem. Soc. 1998, 120, 209-210;
17. b) C. Benelli, M. Murrie, S. Parsons, R.E.P. Winpenny, J. Chem. Soc. Dalton Trans. 1999, 4125-4126;
18. c) B.-Q. Ma, S. Gao, O. Bai, H.-L. Sun, G.-X. Xu, J. Chem. Soc. Dalton Trans. 2000, 1003-1004;
19. d) B. Yan, Z. Chen, S. Wang, S. Gao, Chem. Lett. 2001, 350-351;
20. e) A. J. Tasiopoulos, T. A. O'Brien, K. A. Abboud, G. Christou, Angew. Chem. 2004, 116, 349-353; Angew. Chem. Int. Ed. 2004, 43, 345-349.
21. e) A. J. Tasiopoulos, T. A. O'Brien, K. A. Abboud, G. Christou, Angew. Chem. 2004, 116, 349-353; Angew. Chem. Int. Ed. 2004, 43, 345-349.
22. S. Osa, T. Kido, N. Matsumoto, N. Re, A. Pochaba, J. Mrozinski, J. Am. Chem. Soc. 2004, 126, 420-421.
23. M. S. Lah, V. L. Pecoraro, J. Am. Chem. Soc. 1989, 111, 7258-7259.
24. C. Dendrinou-Samara, M. Alexiou, C. M. Zaleski, J. W. Kampf, M. L. Kirk, D. P. Kessissoglou, V. L. Pecoraro, Angew. Chem. 2003, 115, 3893-3896; Angew. Chem. Int. Ed. 2003, 42, 3763-3766.
25. C. Dendrinou-Samara, M. Alexiou, C. M. Zaleski, J. W. Kampf, M. L. Kirk, D. P. Kessissoglou, V. L. Pecoraro, Angew. Chem. 2003, 115, 3893-3896; Angew. Chem. Int. Ed. 2003, 42, 3763-3766.
26. 2, R1 = 0.0564 [I > 2σ(I)], R1 = 0.0958 (all data); wR2 = 0.1576 [I > 2σ(I)], wR2 = 0.1771 (all data). Further details are given in the Supporting Information. CCDC-231260 (1) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/ retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44) 1223-336-033; or deposit@ccdc.cam.ac.uk).
27. a) R. Sessoli, H.-L. Tsai, A. R. Schake, S. Wang, J. B. Vincent, K. Folting, D. Gatteschi, G. Christou, D. N. Hendrickson, J. Am. Chem. Soc. 1993, 115, 1804-1816;
28. b) G. Christou, D. Gatteschi, D. N. Hendrickson, R. Sessoli, MRS Bull. 2000, 25, 66-71;
29. c) D. Gatteschi, R. Sessoli, Angew. Chem. 2003, 115, 278-309; Angew. Chem. Int. Ed. 2003, 42, 268-297.
30. c) D. Gatteschi, R. Sessoli, Angew. Chem. 2003, 115, 278-309; Angew. Chem. Int. Ed. 2003, 42, 268-297.
31. N. Ishikawa, M. Sugita, T. Ishikawa, S.-Y. Koshihara, Y. Kaizu, J. Am. Chem. Soc. 2003, 125, 8694-8695.