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Crystals of 1 have been structurally characterized with the formula Ho4Mn6C91H112N 8O54. Analytical data for 1 (fw, 3171.25, Found C, 34.25; H, 3.39; N, 3.96; Requires C 34.46; H 3.56; N 3.53. Crystal data for 1: M⌈, 3171.25, monoclinic, space group P2(1)/c, a, 14.0149(19) Å, b= 14.421(2) Å, c, 28.304(4) Å, α, 90°, β, 92.402(6)°, γ, 90°, V, 5715.5(13) Å3, Z, 2; dcalcd, 1.843 mg/ m3; 2.91° < θ < 28.38°; crystal dimensions (mm3, 0.68 x 0.06 x 0.06; μ, 3.492 mm-1; T, 113(2) K; 14 251 used of 58 744 reflections collected. 14 251 reflections and 792 parameters were used for the full-matrix, least-squares refinement of F2, R1, 0.0390 [I > 2σI, R1, 0.0
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2, R1 = 0.0390 [I > 2σ(I)], R1 = 0.0609 (all data); wR2 = 0.0795 [I > 2σ(I)], wR2 = 0.0862 (all data). All non-hydrogen atoms were refined anisotropically with the hydrogen atoms placed in idealized positions. Further details are given in the Supporting Information for 1 and 3.
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Karlin, K. D, Ed, John Wiley and Sons, Inc, New York
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