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Volumn 48, Issue 23, 2009, Pages 11474-11482

Synthesis, structure, and stability of adducts between phosphide and amide anions and the lewis acids borane, tris(pentafluorophenyl)borane, and tris(pentafluorophenyl)alane

Author keywords

[No Author keywords available]

Indexed keywords

AMIDE; ANION; BORANE DERIVATIVE; FLUORINATED HYDROCARBON; ORGANOMETALLIC COMPOUND; PHOSPHINE DERIVATIVE; TRIS(PENTAFLUOROPHENYL)ALANE; TRIS(PENTAFLUOROPHENYL)BORANE;

EID: 72949111701     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic901799q     Document Type: Article
Times cited : (22)

References (54)
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    • For reviews of the chemistry of tris(pentafluorophenyl)borane see: a
    • For reviews of the chemistry of tris(pentafluorophenyl)borane see: (a) Piers, W. E.; Chivers, T. Chem. Soc. Rev. 1997, 26, 345.
    • (1997) Chem. Soc. Rev , vol.26 , pp. 345
    • Piers, W.E.1    Chivers, T.2
  • 12
    • 29144451950 scopus 로고    scopus 로고
    • For a review of nitrogen adducts of tris(pentafluorophenyl)borane see
    • For a review of nitrogen adducts of tris(pentafluorophenyl)borane see: Focante, F.; Mercandelli, P.; Sironi, A.; Resconi, L. Coord. Chem. Rev. 2006, 250, 170.
    • (2006) Coord. Chem. Rev , vol.250 , pp. 170
    • Focante, F.1    Mercandelli, P.2    Sironi, A.3    Resconi, L.4
  • 21
    • 72949114740 scopus 로고    scopus 로고
    • Walker D. A.; Bochmann, M.; Fuller, A.; Mountford A. J.; Lancaster, S. J. unpublished results.
    • Walker D. A.; Bochmann, M.; Fuller, A.; Mountford A. J.; Lancaster, S. J. unpublished results.
  • 24
    • 0038975012 scopus 로고    scopus 로고
    • 3): Mayer, E. Inorg. Chem. 1971, 10, 2259.
    • 3): Mayer, E. Inorg. Chem. 1971, 10, 2259.
  • 33
    • 72949099112 scopus 로고    scopus 로고
    • In 4, the B(2)-H(2A) 1.13(2) Å bond length of the hydrogen atom not interacting with the cation is marginally shorter than those for the interacting pair where B(2)-H(2B) 1.15(2) and B(2)-H(2C) 1.15(2) Å.
    • In 4, the B(2)-H(2A) 1.13(2) Å bond length of the hydrogen atom not interacting with the cation is marginally shorter than those for the interacting pair where B(2)-H(2B) 1.15(2) and B(2)-H(2C) 1.15(2) Å.
  • 36
    • 72949083146 scopus 로고    scopus 로고
    • As in 4, the B-H bond length of the non-interacting hydrogen in 5 is marginally shorter than the other two, ( 1.08(3) versus 1.10(3) and 1.16(2) Å).
    • As in 4, the B-H bond length of the non-interacting hydrogen in 5 is marginally shorter than the other two, ( 1.08(3) versus 1.10(3) and 1.16(2) Å).
  • 38
    • 72949084683 scopus 로고    scopus 로고
    • In 6a, there is also a close interaction between one of the 'Bu hydrogen atoms and an o-F of a second C6F5 ring (C(44)-H(44a)⋯F(36) 2.31 Å
    • 5 ring (C(44)-H(44a)⋯F(36) 2.31 Å).
  • 40
    • 54749110969 scopus 로고    scopus 로고
    • Chase, P. A,;Stephan, D. W. Angew. Chem., Int. Ed. 2008, 47, 7433.
    • (a) Chase, P. A,;Stephan, D. W. Angew. Chem., Int. Ed. 2008, 47, 7433.
  • 44
    • 72949099753 scopus 로고    scopus 로고
    • The anionic part of 11 is essentially the same as that reported in reference 37; our results are reported in the Electronic Supporting Information.
    • The anionic part of 11 is essentially the same as that reported in reference 37; our results are reported in the Electronic Supporting Information.
  • 51
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    • Oxford. Diffraction Ltd: Abingdon, U.K
    • Programs CrysAlis-CCD and-RED; Oxford. Diffraction Ltd: Abingdon, U.K., 2008.
    • (2008) Programs CrysAlis-CCD and-RED
  • 54
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    • International Tables for X-Ray Crystallography; Wilson, A. J. C., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1992, C, pp 193, 219, and. 500.
    • International Tables for X-Ray Crystallography; Wilson, A. J. C., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1992, Vol. C, pp 193, 219, and. 500.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.