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33748361789
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Similar protonation products have been observed in the decarboxylative allylations of enolates
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72849122706
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Scheme 3 shows potential mechanistic "cartoons" that ignore the ligation state of palladium. We presume that the bidentate BINAP ligand remains bound throughout the catalysis
-
Scheme 3 shows potential mechanistic "cartoons" that ignore the ligation state of palladium. We presume that the bidentate BINAP ligand remains bound throughout the catalysis.
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33845374102
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0001647635
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C-allylation vs. N-allylation see: (a)
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34848926246
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A similar mechanism has been proposed for the decarboxylative allylation of enolates: (a)
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A similar mechanism has been proposed for the decarboxylative allylation of enolates: (a) Keith, J. A.; Behenna, D. C.; Mohr, J. T.; Ma, S.; Marinescu, S. C.; Oxgaard, J.; Stoltz, B. M.; Goddard, W. A., III J. Am. Chem. Soc. 2007, 129, 11876.
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