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A related palladium-coordinated quinone methide has been proposed: Schultz, M. J.; Sigman, M. J. Am. Chem. Soc. 2006, 128, 1460-1461.
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A related palladium-coordinated quinone methide has been proposed: Schultz, M. J.; Sigman, M. J. Am. Chem. Soc. 2006, 128, 1460-1461.
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5
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In analogy to electrocyclizations of quinone methides: Van De Water, R. W, Pettus, T. Tetrahedron 2002, 58, 5367-5405
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In analogy to electrocyclizations of quinone methides: Van De Water, R. W.; Pettus, T. Tetrahedron 2002, 58, 5367-5405.
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While the isolated yield of 3b is low, the compound is formed cleanly as determined by 1NMR spectroscopy
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The electrophilicity of p-methoxybenzylidene malononitriles (-10.8) is less than that of a π-allyl palladium complex (-10.1). (a) Kuhn, O.; Mayr, H. Angew. Chem., Int. Ed. 1999, 38, 343-346.
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The electrophilicity of p-methoxybenzylidene malononitriles (-10.8) is less than that of a π-allyl palladium complex (-10.1). (a) Kuhn, O.; Mayr, H. Angew. Chem., Int. Ed. 1999, 38, 343-346.
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