Palladium-catalyzed hydroalkynylation of alkylidenecyclopropanes

Chemistry - A European Journal

Volumn 15, Issue 48, 2009, Pages 13308-13312

  Villarino, Lara ^a   López, Fernando ^b   Castedo, Luis ^a   Mascareñas, José L ^a  

^a UNIVERSITY OF SANTIAGO DE COMPOSTELA   (Spain)

^b INSTITUTO DE QUÍMICA ORGÁNICA GENERAL   (Spain)

Author keywords

Alkylidenecyclopropanes; Alkynes; C c coupling; C h activation; Palladium

Indexed keywords

ACTIVATION ANALYSIS; CATALYSIS; CHEMICAL ACTIVATION; CHEMICAL BONDS; HYDROCARBONS; PALLADIUM;

ALKYLIDENECYCLOPROPANES; ALKYNES; C-C COUPLING; C-H ACTIVATION; CHEMICAL EQUATIONS; DIBENZYLIDENEACETONE; PALLADIUM-CATALYZED; REDUCTIVE ELIMINATION;

PALLADIUM COMPOUNDS;

EID: 72449138603     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200901821     Document Type: Article

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91. 3] (6%) and L1 (20%), in the absence of 2a, led to the recovery of 1b [Eq. (2)]. "chemical equation presented"
92. This type of isomerization process has been previously proposed in a related hyfrofunctionalization os ACPs, see reference [16e].