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Volumn 52, Issue 11, 2009, Pages 1723-1733

Reactivities of d0 transition metal complexes toward oxygen: Synthetic and mechanistic studies

Author keywords

Amide; Gate insulator; Metal oxide; Oxygen; Theoretical study

Indexed keywords

BIOLOGICAL FUNCTIONS; D ELECTRONS; GATE INSULATOR; GATE MATERIALS; MECHANISTIC STUDIES; METAL OXIDE; METAL OXIDE THIN FILMS; METAL OXIDES; MICRO-ELECTRONIC DEVICES; MICROELECTRONIC MATERIALS; PORPHYRIN COMPLEXES; THEORETICAL STUDY; TIO;

EID: 72149120865     PISSN: 10069291     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11426-009-0253-2     Document Type: Article
Times cited : (14)

References (38)
  • 1
    • 0034180064 scopus 로고    scopus 로고
    • Chemical vapour deposition of the oxides of titanium, zirconium and hafnium for use as high-k materials in microelectronic devices. A carbon-free precursor for the synthesis of hafnium dioxide
    • DOI 10.1002/1099-0712(200005/10)10:3/5<105::AID-AMO402>3.0.CO;2-J
    • R. C. Smith T. Ma N. Hoilien L. Y. Tsung M. J. Bevan L. Colombo J. Roberts S. A. Campbell W. L. Gladfelter 2000 Chemical vapour deposition of the oxides of titanium, zirconium and hafnium for use as high-k materials in microelectronic devices. A carbon-free precursor for the synthesis of hafnium dioxide Adv Mater Opt Electron 10 105 114 10.1002/1099-0712(200005/10)10:3/ 5<105::AID-AMO402>3.0.CO;2-J 1:CAS:528:DC%2BD3cXoslyjurY%3D (Pubitemid 32032854)
    • (2000) Advanced Materials for Optics and Electronics , vol.10 , Issue.3-5 , pp. 105-114
    • Smith, R.C.1    Ma, T.2    Hoilien, N.3    Tsung, L.Y.4    Bevan, M.J.5    Colombo, L.6    Roberts, J.7    Campbell, S.A.8    Gladfelter, W.L.9
  • 3
    • 0009411657 scopus 로고
    • Reactions of non-heme iron(II) centers with dioxygen in biology and chemistry
    • 10.1021/cr00027a011 1:CAS:528:DyaK2cXivVygs7k%3D
    • A. L. Feig S. J. Lippard 1994 Reactions of non-heme iron(II) centers with dioxygen in biology and chemistry Chem Rev 94 759 805 10.1021/cr00027a011 1:CAS:528:DyaK2cXivVygs7k%3D
    • (1994) Chem Rev , vol.94 , pp. 759-805
    • Feig, A.L.1    Lippard, S.J.2
  • 4
    • 85009192854 scopus 로고
    • Metal-dioxygen complexes: A perspective
    • 10.1021/cr00027a001 1:CAS:528:DyaK2cXivVygs7g%3D
    • I. M. Klotz D. M. Kurtz 1994 Metal-dioxygen complexes: A perspective Chem Rev 94 567 568 10.1021/cr00027a001 1:CAS:528:DyaK2cXivVygs7g%3D
    • (1994) Chem Rev , vol.94 , pp. 567-568
    • Klotz, I.M.1    Kurtz, D.M.2
  • 5
    • 1542675143 scopus 로고    scopus 로고
    • Toward benign synthesis via catalytic oxidations using dioxygen or nitrous oxide
    • 10.1021/bk-2002-0823.ch006 1:CAS:528:DC%2BD38XmsV2hs7w%3D
    • K. H. Theopold O. M. Reinaud S. Blanchard S. Leelasubeharoen A. Hess S. Thyagarajan 2002 Toward benign synthesis via catalytic oxidations using dioxygen or nitrous oxide ACS Symp Ser 823 75 85 10.1021/bk-2002-0823.ch006 1:CAS:528:DC%2BD38XmsV2hs7w%3D
    • (2002) ACS Symp ser , vol.823 , pp. 75-85
    • Theopold, K.H.1    Reinaud, O.M.2    Blanchard, S.3    Leelasubeharoen, S.4    Hess, A.5    Thyagarajan, S.6
  • 6
    • 0000955949 scopus 로고
    • Electrophilic cleavage of the carbon-zirconium(IV) bond. Comparison and contrast with other transition metal alkyl systems
    • 10.1021/ja00846a068 1:CAS:528:DyaE2MXkslynsbY%3D
    • J. A. Labinger D. W. Hart W. E. Seibert J. Schwartz 1975 Electrophilic cleavage of the carbon-zirconium(IV) bond. Comparison and contrast with other transition metal alkyl systems J Am Chem Soc 97 3851 3852 10.1021/ja00846a068 1:CAS:528:DyaE2MXkslynsbY%3D
    • (1975) J Am Chem Soc , vol.97 , pp. 3851-3852
    • Labinger, J.A.1    Hart, D.W.2    Seibert, W.E.3    Schwartz, J.4
  • 7
    • 0001150276 scopus 로고
    • Hydrozirconation. IV. Oxidation of alkylzirconium(IV) complexes to alcohols
    • 10.1016/S0040-4039(00)75067-2
    • T. F. Blackburn J. A. Labinger J. Schwartz 1975 Hydrozirconation. IV. Oxidation of alkylzirconium(IV) complexes to alcohols Tetrahedron Lett 16 3041 3044 10.1016/S0040-4039(00)75067-2
    • (1975) Tetrahedron Lett , vol.16 , pp. 3041-3044
    • Blackburn, T.F.1    Labinger, J.A.2    Schwartz, J.3
  • 8
    • 33845376915 scopus 로고
    • Reactivity of dioxygen with group 4A alkoxy alkyls: Epoxidation via metal alkyl mediated oxygen atom transfer
    • 10.1021/ja00289a030 1:CAS:528:DyaL2MXnvFSntg%3D%3D
    • T. V. Lubben P. T. Wolczanski 1985 Reactivity of dioxygen with group 4A alkoxy alkyls: epoxidation via metal alkyl mediated oxygen atom transfer J Am Chem Soc 107 701 703 10.1021/ja00289a030 1:CAS:528:DyaL2MXnvFSntg%3D%3D
    • (1985) J Am Chem Soc , vol.107 , pp. 701-703
    • Lubben, T.V.1    Wolczanski, P.T.2
  • 9
    • 21044453336 scopus 로고
    • 2)
    • 10.1021/om00127a025 1:CAS:528:DyaL2MXksFCiu7s%3D
    • 2) Organometallics 4 1452 1457 10.1021/om00127a025 1:CAS:528:DyaL2MXksFCiu7s%3D
    • (1985) Organometallics , vol.4 , pp. 1452-1457
    • Tilley, T.D.1
  • 10
    • 22944487280 scopus 로고    scopus 로고
    • CVD of titanium oxide thin films from the reaction of tetrakis(dimethylamido)titanium with oxygen
    • DOI 10.1002/cvde.200504205
    • J. B. Woods D. B. Beach C. L. Nygren Z. -L. Xue 2005 CVD of titanium oxide thin films from the reaction of tetrakis(dimethylamido)titanium with oxygen Chem Vapor Deposition 11 289 291 10.1002/cvde.200504205 1:CAS:528:DC%2BD2MXntFCktLc%3D (Pubitemid 41048512)
    • (2005) Chemical Vapor Deposition , vol.11 , Issue.6-7 , pp. 289-291
    • Woods, J.B.1    Beach, D.B.2    Nygren, C.L.3    Xue, Z.-L.4
  • 13
    • 64349089492 scopus 로고    scopus 로고
    • Synthesis and characterization of siloxy, aminoxy, and oxo complexes from the reaction of a tantalum amide silyl complex with oxygen
    • 10.1021/ic802380u 1:CAS:528:DC%2BD1MXitlyrtrk%3D
    • H. Qiu S. J. Chen C. S. Wang Y. D. Wu I. A. Guzei X.-T. Chen Z. L. Xue 2009 Synthesis and characterization of siloxy, aminoxy, and oxo complexes from the reaction of a tantalum amide silyl complex with oxygen Inorg Chem 48 3073 3079 10.1021/ic802380u 1:CAS:528:DC%2BD1MXitlyrtrk%3D
    • (2009) Inorg Chem , vol.48 , pp. 3073-3079
    • Qiu, H.1    Chen, S.J.2    Wang, C.S.3    Wu, Y.D.4    Guzei, I.A.5    Chen, X.-T.6    Xue, Z.L.7
  • 16
    • 20144389150 scopus 로고    scopus 로고
    • A tungsten silyl alkylidyne complex and its bis(alkylidene) tautomer. Their interconversion and an unusual silyl migration in their reaction with dioxygen
    • DOI 10.1021/om049031j
    • T. Chen X. H. Zhang C. Wang S. Chen Z. Wu L. Li K. R. Sorasaenee J. B. Diminnie H. Pan I. A. Guzei A. L. Rheingold Y. D. Wu Z. Xue 2005 A tungsten silyl alkylidyne complex and its bis(alkylidene) tautomer. Their interconversion and an unusual silyl migration in their reaction with dioxygen Organometallics 24 1214 1224 10.1021/om049031j 1:CAS:528:DC%2BD2MXhtlChtL4%3D (Pubitemid 40436973)
    • (2005) Organometallics , vol.24 , Issue.6 , pp. 1214-1224
    • Chen, T.1    Zhang, X.-H.2    Wang, C.3    Chen, S.4    Wu, Z.5    Li, L.6    Sorasaenee, K.R.7    Diminnie, J.B.8    Pan, H.9    Guzei, I.A.10    Rheingold, A.L.11    Wu, Y.-D.12    Xue, Z.-L.13
  • 20
    • 0037993949 scopus 로고    scopus 로고
    • Understanding the reactivity of transition metal complexes involving multiple spin states
    • 347-361
    • Harvey J N, Poli R, Smith K M. Understanding the reactivity of transition metal complexes involving multiple spin states. Coord Chem Res, 2003, 238-239, 347-361
    • (2003) Coord Chem Res , pp. 238-239
    • Harvey, J.N.1    Poli, R.2    Smith, K.M.3
  • 23
    • 34247616018 scopus 로고    scopus 로고
    • 5 thin films using electrostatic spray deposition for microelectronic applications
    • DOI 10.1021/jp0676585
    • 5 thin films using electrostatic spray deposition for microelectronic applications J Phys Chem C 111 5708 5714 10.1021/jp0676585 1:CAS:528:DC%2BD2sXjsVGrtr0%3D (Pubitemid 46686251)
    • (2007) Journal of Physical Chemistry C , vol.111 , Issue.15 , pp. 5708-5714
    • Lintanf, A.1    Mantoux, A.2    Blanquet, E.3    Djurado, E.4
  • 25
    • 41749084167 scopus 로고    scopus 로고
    • Unexpected formation of (dimethylaminomethylene) methylamide complexes from the reactions between metal chlorides and lithium dimethylamide
    • 10.1021/om701173m 1:CAS:528:DC%2BD1cXitVyit78%3D
    • X. H. Zhang S. J. Chen H. Cai H. J. Im T. Chen X. Yu X. Chen Z. Lin Y. D. Wu Z. L. Xue 2008 Unexpected formation of (dimethylaminomethylene) methylamide complexes from the reactions between metal chlorides and lithium dimethylamide Organometallics 27 1338 1341 10.1021/om701173m 1:CAS:528:DC%2BD1cXitVyit78%3D
    • (2008) Organometallics , vol.27 , pp. 1338-1341
    • Zhang, X.H.1    Chen, S.J.2    Cai, H.3    Im, H.J.4    Chen, T.5    Yu, X.6    Chen, X.7    Lin, Z.8    Wu, Y.D.9    Xue, Z.L.10
  • 26
    • 0003584418 scopus 로고
    • S. Patai Z. Rappoport (eds). Wiley New York
    • Tilley T D. In: Patai S, Rappoport Z. eds. The Silicon-Heteroatom Bond. New York: Wiley, 1991. Chapters 9 and 10
    • (1991) The Silicon-Heteroatom Bond
    • Tilley, T.D.1
  • 28
    • 0028768946 scopus 로고
    • Early-transition-metal silyl complexes free from anionic. pi.-Ligands. A new family of alkyl, alkylidene, and alkylidyne compounds
    • 10.1021/ja00084a077 1:CAS:528:DyaK2cXhvFWkt7g%3D
    • Z. Xue L. Li L. K. Hoyt J. B. Diminnie J. L. Pollitte 1994 Early-transition-metal silyl complexes free from anionic. pi.-Ligands. A new family of alkyl, alkylidene, and alkylidyne compounds J Am Chem Soc 116 2169 2170 10.1021/ja00084a077 1:CAS:528:DyaK2cXhvFWkt7g%3D
    • (1994) J Am Chem Soc , vol.116 , pp. 2169-2170
    • Xue, Z.1    Li, L.2    Hoyt, L.K.3    Diminnie, J.B.4    Pollitte, J.L.5
  • 30
    • 0000780883 scopus 로고    scopus 로고
    • 3 (E = C, Si). Kinetic and mechanistic studies of the formation of a silyl alkylidene complex through preferential silane elimination
    • 10.1021/om960382a 1:CAS:528:DyaK28XktlWmsrk%3D
    • 3 (E = C, Si). Kinetic and mechanistic studies of the formation of a silyl alkylidene complex through preferential silane elimination Organometallics 15 3520 3527 10.1021/om960382a 1:CAS:528:DyaK28XktlWmsrk%3D
    • (1996) Organometallics , vol.15 , pp. 3520-3527
    • Li, L.1    Diminnie, J.B.2    Liu, X.3    Pollitte, J.L.4    Xue, Z.5
  • 31
    • 0001394344 scopus 로고    scopus 로고
    • Reactions of alkyl alkylidene complexes with silanes. Synthesis and characterization of novel tantalum 1,1-metallasilacyclobutadiene and disilyl-substituted alkylidene complexes
    • 10.1021/ja972302f 1:CAS:528:DyaK1cXhs1ClsA%3D%3D
    • J. B. Diminnie Z. Xue 1997 Reactions of alkyl alkylidene complexes with silanes. Synthesis and characterization of novel tantalum 1,1- metallasilacyclobutadiene and disilyl-substituted alkylidene complexes J Am Chem Soc 119 12657 12658 10.1021/ja972302f 1:CAS:528:DyaK1cXhs1ClsA%3D%3D
    • (1997) J Am Chem Soc , vol.119 , pp. 12657-12658
    • Diminnie, J.B.1    Xue, Z.2
  • 32
    • 0001622467 scopus 로고    scopus 로고
    • t)Cl•2THF
    • 10.1021/om980148f 1:CAS:528:DyaK1cXjs1Srsrg%3D
    • t)Cl•2THF Organometallics 17 2917 2920 10.1021/om980148f 1:CAS:528:DyaK1cXjs1Srsrg%3D
    • (1998) Organometallics , vol.17 , pp. 2917-2920
    • Wu, Z.1    Diminnie, J.B.2    Xue, Z.3
  • 33
    • 0001447269 scopus 로고    scopus 로고
    • 3 (E = C, Si) with 2,6-dimethylphenyl isocyanide. Preferential isocyanide insertion into Zr-Silyl bonds
    • 10.1021/om980485o 1:CAS:528:DyaK1cXmsVWjtL8%3D
    • 3 (E = C, Si) with 2,6-dimethylphenyl isocyanide. Preferential isocyanide insertion into Zr-Silyl bonds Organometallics 17 4853 4860 10.1021/om980485o 1:CAS:528:DyaK1cXmsVWjtL8%3D
    • (1998) Organometallics , vol.17 , pp. 4853-4860
    • Wu, Z.1    McAlexander, L.H.2    Diminnie, J.B.3    Xue, Z.4
  • 34
    • 0033526303 scopus 로고    scopus 로고
    • 0 Bis(silyl) complexes free of anionic π-ligands: Syntheses, structures, and a novel exchange between silyl ligands and silyl anions
    • DOI 10.1021/ja984424t
    • 0 Bis(silyl) complexes free of anionic π-ligands: Syntheses, structures, and a novel exchange between silyl ligands and silyl anions J Am Chem Soc 121 4300 4301 10.1021/ja984424t 1:CAS:528:DyaK1MXitlCls7k%3D (Pubitemid 29220315)
    • (1999) Journal of the American Chemical Society , vol.121 , Issue.17 , pp. 4300-4301
    • Wu, Z.1    Diminnie, J.B.2    Xue, Z.3
  • 35
    • 1842738745 scopus 로고    scopus 로고
    • Unusual Equilibria Involving Group 4 Amides, Silyl Complexes, and Silyl Anions via Ligand Exchange Reactions
    • DOI 10.1021/ja031899y
    • X. H. Yu H. Cai I. A. Guzei Z. L. Xue 2004 Unusual equilibria involving group 4 amides, silyl complexes, and silyl anions via ligand exchange reactions J Am Chem Soc 126 4472 4473 10.1021/ja031899y 1:CAS:528:DC%2BD2cXitFyis7g%3D (Pubitemid 38469068)
    • (2004) Journal of the American Chemical Society , vol.126 , Issue.14 , pp. 4472-4473
    • Yu, X.1    Cai, H.2    Guzei, I.A.3    Xue, Z.4
  • 36
    • 23844447348 scopus 로고    scopus 로고
    • Disilyl complexes of zirconium, hafnium, and tantalum. Their synthesis, characterization, and exchanges with silyl anions
    • DOI 10.1021/om050302f
    • H. Qiu H. Cai J. B. Woods Z. Wu T. Chen X. H. Yu Z. L. Xue 2005 Disilyl complexes of zirconium, hafnium, and tantalum. Their synthesis, characterization, and exchanges with silyl anions Organometallics 24 4190 4197 10.1021/om050302f 1:CAS:528:DC%2BD2MXmt1WrsL0%3D (Pubitemid 41178554)
    • (2005) Organometallics , vol.24 , Issue.17 , pp. 4190-4197
    • Qiu, H.1    Cai, H.2    Woods, J.B.3    Wu, Z.4    Chen, T.5    Yu, X.6    Xue, Z.-L.7
  • 37
    • 0000048336 scopus 로고    scopus 로고
    • 2(X)
    • 10.1021/om990501x 1:CAS:528:DyaK1MXnsFOrsbY%3D
    • 2(X) Organometallics 18 5488 5495 10.1021/om990501x 1:CAS:528:DyaK1MXnsFOrsbY%3D
    • (1999) Organometallics , vol.18 , pp. 5488-5495
    • Choi, S.H.1    Lin, Z.2    Xue, Z.3


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