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70849116933
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The angle tτ defined here for [2]metallocenophanes should not be confused with the definition proposed by Addison and Reedijk as an index of the degree of trigonality in five-coordinate complexes.
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The angle tτ defined here for [2]metallocenophanes should not be confused with the definition proposed by Addison and Reedijk as an index of the degree of trigonality in five-coordinate complexes.
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Insoluble polymers containing ferrocene units in the main chain have been obtained through ROMP of relatively unstrained monomers as well.
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Insoluble polymers containing ferrocene units in the main chain have been obtained through ROMP of relatively unstrained monomers as well.
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70849093038
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Metallocenophanes with diatomic bridges composed of one heteroatom and one carbon atom show selective reactivity at the heteroatom.
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[2]Metallocenophanes with diatomic bridges composed of one heteroatom and one carbon atom show selective reactivity at the heteroatom.
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70849119444
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Photolytically-induced polymerization of [l]ferrocenophanes was first reported for phosphorus-bridged species but these reactions were not living.
-
Photolytically-induced polymerization of [l]ferrocenophanes was first reported for phosphorus-bridged species but these reactions were not living.
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The [2]ferrocenophane 8 has been mentioned in the literature, although no synthetic details or characterization data were provided.
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The [2]ferrocenophane 8 has been mentioned in the literature, although no synthetic details or characterization data were provided.
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70849101239
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13C NMR spectra in the ipso carbon region, regioselective Fe-Cp bond cleavage appears unlikely to have occurred in the ROP of 8. The phenyl substituents of the carbon-carbon bridge in 13 are necessarily oriented rac to one another, however the relative orientation of phenyl substituents separated by ferrocene units could not be determined.
-
13C NMR spectra in the ipso carbon region, regioselective Fe-Cp bond cleavage appears unlikely to have occurred in the ROP of 8. The phenyl substituents of the carbon-carbon bridge in 13 are necessarily oriented rac to one another, however the relative orientation of phenyl substituents separated by ferrocene units could not be determined.
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67
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70849103099
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For a discussion of the relative merits of using triple-detection calibration and polystyrene standards to evaluate molecular weight values obtained from GPC
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For a discussion of the relative merits of using triple-detection calibration and polystyrene standards to evaluate molecular weight values obtained from GPC,
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