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The observation that Ni/Ti reacts in vacuum, without an abundance of oxygen present, is also interesting considering previous work by Moore and Feng. This other work reported the "initial oxidation of Ti subsequently triggered the SHS reaction Ni+Ti=NiTi." Our study conclusively shows that, at least for vapor-deposited structures having nanometer-scale periodicity, the heat of the intermetallic reaction is sufficient to drive SHS.
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The observation that Ni/Ti reacts in vacuum, without an abundance of oxygen present, is also interesting considering previous work by Moore and Feng. This other work reported the "initial oxidation of Ti subsequently triggered the SHS reaction Ni+Ti=NiTi." Our study conclusively shows that, at least for vapor-deposited structures having nanometer-scale periodicity, the heat of the intermetallic reaction is sufficient to drive SHS.
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