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Volumn 106, Issue 9, 2009, Pages

Reactive Ni/Ti nanolaminates

Author keywords

[No Author keywords available]

Indexed keywords

BILAYER THICKNESS; FOIL THICKNESS; HIGH-TEMPERATURE SYNTHESIS; IGNITION TEMPERATURES; LAMINATE DESIGN; MULTILAYER FOILS; NANO-LAMINATES; PROPAGATION SPEED; REACTION FRONT; SELF-PROPAGATING REACTION; SELF-SUSTAINED REACTIONS; VACUUM APPARATUS;

EID: 70450227177     PISSN: 00218979     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3253591     Document Type: Article
Times cited : (47)

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    • The observation that Ni/Ti reacts in vacuum, without an abundance of oxygen present, is also interesting considering previous work by Moore and Feng. This other work reported the "initial oxidation of Ti subsequently triggered the SHS reaction Ni+Ti=NiTi." Our study conclusively shows that, at least for vapor-deposited structures having nanometer-scale periodicity, the heat of the intermetallic reaction is sufficient to drive SHS.
    • The observation that Ni/Ti reacts in vacuum, without an abundance of oxygen present, is also interesting considering previous work by Moore and Feng. This other work reported the "initial oxidation of Ti subsequently triggered the SHS reaction Ni+Ti=NiTi." Our study conclusively shows that, at least for vapor-deposited structures having nanometer-scale periodicity, the heat of the intermetallic reaction is sufficient to drive SHS.
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    • y for long time at elevated temperature (closer to equilibrium). Specifically, work with slightly Ni-rich compositions (similar to the matrix phase in our study) shows dramatically lower martensite start temperature making austenite more prevalent. [See, e.g., summary by, ()] Therefore, according to these other studies B19′ NiTi should be less prevalent. 10.1007/s11661-003-0186-x
    • y for long time at elevated temperature (closer to equilibrium). Specifically, work with slightly Ni-rich compositions (similar to the matrix phase in our study) shows dramatically lower martensite start temperature making austenite more prevalent. [See, e.g., summary by T. Sawaguchi, G. Kaistrater, A. Yawny, M. Wagner, and G. Eggeler, Metall. Mater. Trans. A 34A, 2847 (2003)] Therefore, according to these other studies B19′ NiTi should be less prevalent. 10.1007/s11661-003-0186-x
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    • See EPAPS supplementary material at E-JAPIAU-106-025921 for a more complete listing of indexed reflections and Miller index notation.
    • See EPAPS supplementary material at http://dx.doi.org/10.1063/1.3253591 E-JAPIAU-106-025921 for a more complete listing of indexed reflections and Miller index notation.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.