Superbasicity of a bis-guanidino compound with a flexible linker: A theoretical and experimental study

Journal of the American Chemical Society

Volumn 131, Issue 46, 2009, Pages 16858-16868

  Coles, Martyn P ^a   Aragón Sáez, Pedro J ^a   Oakley, Sarah H ^a   Hitchcock, Peter B ^a   Davidson, Matthew G ^b   Maksić, Zvonimir B ^c   Vianello, Robert ^c   Leito, Ivo ^d   Kaljurand, Ivari ^d   Apperley, David C ^e  

^a UNIVERSITY OF SUSSEX   (United Kingdom)

^b University of Bath Claverton Down   (United Kingdom)

^c RUDER BO KOVI INSTITUTE   (Croatia)

^d UNIVERSITY OF TARTU   (Estonia)

^e DURHAM UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

COMPOUND I; COMPUTATIONAL ANALYSIS; CONJUGATE ACID; ELECTRON DENSITY MAPS; EXPERIMENTAL EVIDENCE; EXPERIMENTAL STUDIES; FLEXIBLE LINKERS; GASPHASE; GUANIDINIUM; HETEROCYCLES; HIGH RESOLUTION X RAY DIFFRACTION; HIGHER TEMPERATURES; HYDROGEN BONDINGS; KINETICS METHOD; LINE BROADENING; MONOCATIONS; NITROGEN ATOM; NITROGEN BONDS; NMR SPECTROSCOPY; POLYPHOSPHAZENES; PROTON AFFINITY; PROTON SHUTTLE; PROTONATED; RELAXATION ENERGIES; RESONANCE STABILIZATION; SPECTROPHOTOMETRIC TITRATIONS; SPECTROSCOPIC DATA; TEMPERATURE RANGE; TETRAPHENYLBORATES; TRANSITION STATE; X-RAY DIFFRACTION DATA; ZERO-POINT VIBRATIONAL ENERGIES;

ACETONITRILE; CHLORINE COMPOUNDS; DIFFRACTION; FLUORINE CONTAINING POLYMERS; HYDROGEN BONDS; NITROGEN; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTONATION; X RAY DIFFRACTION;

PROTON TRANSFER;

ACETONITRILE; ACID; BASE; GUANIDINE DERIVATIVE; IMINE; NITROGEN;

ARTICLE; ATOM; BINDING AFFINITY; CALCULATION; CHEMICAL BOND; CHEMICAL STRUCTURE; COMPRESSION; CONJUGATE; ELECTRON; EXPERIMENTAL STUDY; GAS; HIGH TEMPERATURE; HYDROGEN BOND; KINETICS; NITROGEN NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; SOLID STATE; SPECTROPHOTOMETRY; TITRIMETRY; X RAY DIFFRACTION;

EID: 70450161111     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja906618g     Document Type: Article

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