Vegetable oil deodorizer distillate: Characterization, utilization and analysis

Separation and Purification Reviews

Volumn 38, Issue 3, 2009, Pages 207-241

  Gunawan, Setiyo ^a,b   Ju, Yi Hsu ^a  

^a NATIONAL TAIWAN UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Taiwan)

^b DEPARTMENT OF ELECTRICAL ENGINEERING   (Indonesia)

Author keywords

Analysis methods; Characterization; Deodorizer distillates; Utilizations

Indexed keywords

ANALYSIS METHOD; ANALYSIS METHODS; BIOACTIVE COMPOUNDS; DEODORIZER DISTILLATES; FUTURE PERSPECTIVES; MARINE ANIMALS; METHODS OF ANALYSIS; NATURAL SOURCES; SEPARATION TECHNIQUES; SOYBEAN OIL DEODORIZER DISTILLATES; STERYL ESTERS;

ACIDS; ANIMALS; ESTERS; FATTY ACIDS; LUBRICATING OILS; VEGETABLE OILS;

TERNARY SYSTEMS;

EID: 70449652275     PISSN: 15422119     EISSN: 15422127     Source Type: Journal    
DOI: 10.1080/15422110903095151     Document Type: Article

References (73)

1. Bockisch, M. (1998) Fats and Oils Handbook; American Oil Chemist Society: Champaign, IL, pp. 613-718.
2. Newkirk, D.R. (1982) Studies on Vegetable Oil Deodorization Distillates with Respect to Lipid and Pesticide Content; The American University: Washington, DC.
3. http://www.asa-europe.org/pdf/oilref.pdf (Accessed May 30, 2008).
4. http://www.asa-europe.org/pdf/sboprocess.pdf. (Accessed May 30, 2008).
5. Aparicio, R., and Ruiz, R.A. (2000) Authentication of vegetable oils by chromatographic techniques. J. Chromatogr. A, 881: 93-104
6. Verleyen, T., Verhe, R., Garcia, L., Dewettinck, K., Huyghebaert, A., and De Greyt, W.F. (2001) Gas chromatographic characterization of vegetable oil deodorization distillate. J. Chromatogr. A, 921: 277-285
7. Winters, R.L. (1986) in Proceeding: World Conference on Emerging Technologies in the Fats and Oils Industry, American Oil Chemist Society: Champaign, IL, p.186
8. Watanabe, Y., Hirota, Y., Nagao, T., Kitano, M., and Shimada, Y. (2004) Purification of tocopherols and phytosterols by two-step in situ enzymatic reaction. J. Am. Oil Chem. Soc., 81: 339-345
9. Nagao, T., Kobayashi, T., Hirota, Y., Kitano, M., Kishimoto, N., Fujita, T., Watanabe, Y., and Shimada, Y. (2005) Improvement of a process for purification of tocopherols and sterols from soybean oil deodorizer distillate. J. Mol. Catal. B-Enzym., 37: 56-62
10. Gunawan, S., Kasim, N.S., and Ju, Y.H. (2008a) Separation and purification of squalene from soybean oil deodorizer distillate. Sep. Purif. Technol., 60: 128-135
11. Gunawan, S., Fabian, C., and Ju, Y.H. (2008b) Isolation and purification of fatty acid steryl esters from soybean oil deodorizer distillate. Ind. Eng. Chem. Res., 47: 7013-7018
12. Bondioli, P., Carlo M., Armando L., Enzo F., and Muller, A. (1993) Squalene recovery from olive oil deodorizer distillate. J. Am. Oil Chem. Soc., 70: 763-766
13. Zehnder, C.T. (1995) Practical Handbook of Soybean Processing and Utilization; American Oil Chemist Society: Champaign, IL, pp. 239-257
14. Borher, J.R.Z., Goncalves, L.A.G., and de Felicio, P.E. (2002) a- and c- Tocopherol levels in nelore steer blood plasma after a single oral treatment of soybean oil deodorizer distillate (SODD). Meat Sci., 61: 301-306
15. Poku, K. (2002) Small-scale palm oil processing in Africa. FAO Agricultural Services Bulletin, 148: 1-47
16. http://www.panda.org/downloads/forest/oilpalmchainpartaandb-esri.pdf (Accessed Nov. 20, 2008)
17. De Greyt, W. F., and Kellens, M. (2000) Refining Practice, in Edible Oil Refining, edited by W. Hamm, and R.J. Hamilton; Sheffield Academic Press: Sheffield, UK, pp. 79-128
18. Inform (2006) Global oilseed market prospect look good, Inform, 17: 82
19. http://www.apo-tokyo.org/gp/manila-conf02/resource-papers/narrative/ bohra. pdf, (Accessed May 30, 2008)
20. Ramamurthi, S. and Mc Curdy, A.R. (1993) Enzymatic pretreatment of deodororizer distillate for concentration of sterols and tocopherols. J. Am Oil Chem. Soc., 70: 287-295
21. Fizet, C. (1996) Process for tocopherols and sterols from natural sources. U.S. Patent 5,487,817
22. Hirota, Y., Nagao, T., Watanabe, Y., Suenaga, M., Nakai, S., Kitano, M., Sugihara, A., and Shimada, Y. (2003) Purification of steryl esters from soybean oil deodorizer distillate. J. Am. Oil Chem. Soc., 80: 341-346
23. Copeland, D. and Belcher, M. (2004) Methods for treating deodorizer distillate. U.S. Patent 6,750,359
24. Moreira, E.A. and Baltanas, M.A. (2004) Recovery of phytosterols from sunflower oil deodorizer distillates. J. Am. Oil Chem. Soc., 81: 339-345
25. Gast, K., Jungfer, M., Saure, C., and Brunner, G. (2005) Purification of tocochromanols from edible oil. J. Supercrit. Fluids, 34: 17-25
26. Jacobs, L. (2005) Process for the production of tocotrienols. U.S. Patent 6,838,104
27. Martins, P.F., Batistella, C.B., Maciel-Filho, R., and Wolf-Maciel, M.R. (2006) Comparison of two different startegies for tocopherols enrichment using a molecular distillation process. Ind. Eng. Chem. Res., 45: 753-758
28. Mendes, M.F., Pessoa, F.L.P., and Uller, A.M.C. (2002) An economic evaluation based on experimental study of the vitamin E concentration present in deodorizer distillate of soybean oil using supercritical CO2. J. Supercrit. Fluids, 23: 257-265
29. Mendes, M.F., Pessoa, F.L.P., Coelho, G.V., and Uller, A.M.C. (2005) Recovery of the high aggregated compounds present in the deodorizer distillate of the vegetable oils using supercritical fluids. J. Supercrit. Fluids, 34: 157-162
30. De Greyt, W.F., Kellens, M., and Huyghebaert, A.D. (1999) Effect of physical refining on selected minor components in vegetable oils. Fett/Lipid, 101: 428-432
31. Mensink, R.P. and Katan, M.B. (1990) Effect of dietary trans fatty acids on high-density and low-density lipoprotein cholesterol levels in healthy subjects. N. Engl. J. Med., 323: 439-445
32. Willet, W.C., Stampfer, J.M., and Manson, J.E. (1993) Intake of trans fatty acids and risk of coronary heart disease among woman. Lancet, 341: 581-586
33. Judd, J. T., Clevidence, B. A., and Meusing, R. A. (1994) Dietary trans fatty acids: effect on plasma lipids and lipoprotein of healthy men and women. Am. J. Clin. Nutr., 59: 861-868
34. http://www.chem.qmul.ac.uk/iupac/misc/noGreek/toc.html (Accessed April 7, 2009)
35. Traber, M.G. and Packer, L. (1995) Vitamin E: beyond antioxidant function. Am. J. Clin. Nutr., 62: 1501-1509
36. Niki, E., Yamamoto, Y., Takahashi, M., Komuro, E., and Miyama, Y. (1989) Inhibition of oxidation of biomembranes by tocopherol. Ann. N.Y. Acad. Sci., 570: 23-31
37. Fukuzawa, K., Kurotori, Y., Tokumura, A., and Tsukatani, H. (1989) Increased platelet-activating factor (PAF) synthesis in polymorphonuclear leukocytes of vitamin E-deficient rats. Ann. N.Y. Acad. Sci., 570: 449-454 (Pubitemid 20103430)
38. Machlin, L.J. (1984) Vitamin E in Handbook of Vitamins: Nutritional, Biochemical and Clinical Aspects; Marcel Dekker: New York, pp. 99-145
39. Traber, M.G. (1999) Vitamin E in Modern Nutrition in Health and Disease, 10th edition; edited by Shils, M.E., Olson J.A., Shike M., and Ross A.C., Williams and Wilkins: Baltimore, pp. 347-362
40. Farrel, P. and Roberts, R., (1994) edited by Shils, M. E., Olson J. A., Shike M., and Ross A. C., 8th Ed. Vitamin E in Modern Nutrition in Health and Disease; Lea and Febiger: Philadelphia, PA, pp. 326-341
41. Burton, G.W., Traber, M.G., Acuff, R.V., Walters, D.N., Kayden, H., Hughes, L., and Ingold, K. (1998) Human plasma and tissue alphatocopherol concentrations in response to supplementation with deuterated natural and synthetic vitamin E. Am. J. Clin. Nutr., 67: 669-684
42. Helzlsouer, K.J., Huang, H.Y., Alberg, A.J., Hoffman, S., Burke, A., Norkus, E.P., Morris, J.S., and Comstock, G.W. (2000) Association between a-tocopherol, c-tocopherol, selenium, and subsequent prostate cancer. J. Natl. Cancer Inst., 92: 2018-2023
43. Christen, S., Woodall, A.A., Shigenaga, M.K., Southwell-Keely, P.T., Duncan, M.W., and Ames, B.N. (1997) a-Tocopherol traps mutagenic electrophiles such as NOx and complements a-tocopherol: Physiological implications. Proc. Natl. Acad. Sci. USA, 94: 3217-3222
44. Bartok, L., Hilaly, A., Schuette, C.M., and Shukla, R. (2005) Process for separation of tocopherols. U.S. Patent 6,867,308
45. Piironen, V., Lindsay, D., Miettinen, T.A., Toivo, J., and Lampi, A.M. (2000) Plant sterols: Biosynthesis, biological function and their importance to human nutrition. J. Sci. Food Agric., 80: 939-966
46. Moreau, R. A., Whitaker, B. D., and Hicks, K. B. (2002) Phytosterols, phytostanols, and their conjugates in foods: Structural diversity, quantitative analysis, and health-promoting uses. Prog. Lipid Res., 41: 457-500
47. http://www.chem.qmul.ac.uk/iupac/lipid/ (Accessed April 7, 2008)
48. http://www.chem.qmul.ac.uk/iupac/steroid/ (Accessed April 7, 2008)
49. Lorentz, R. T., Haeckler, K., and Fenner, G., (1989) edited by Nes, W.D. and Parish, E.J. Analysis of steryl esters In Analysis of Sterols and Other Biologically Significant Steroid; Academic Press Inc: San Diego, pp. 33-48
50. Moreau, R. A., (2004) edited by Dutta, P. C. Plant Sterols in Functional Food, in Phytosterols as Functional Food Components and Nutraceuticals; Marcel Dekker Inc.: New York, pp. 317-345
51. Moreda, W., Perez-Camino, M.C., and Cert, A. (2001) Gas and liquid chromatography of hydrocarbons in edible vegetable oils. J. Chromatogr. A., 936: 159-171
52. Jasperson, H. and Jones, R. (1947) Some unsaponifiable constitutes of deodorization distillate of vegetable oils. J. Soc. Chem. Ind., 66: 13-17
53. Goh, S.H., Choo, Y.M., and Ong, S.H. (1985) Minor constituents of palm oil. J. Am. Oil Chem. Soc., 62: 237-240
54. Christian, M. S. (1982) Final report on the safety assessment of squalane and squalene. J. Amer. Coll. Toxicol., 1: 37-56
55. Yarkoni, E. and Rapp, H.J. (1980) Influence of type of oil and surfactant concentration on the efficacy of emulsified Mycobacterium bovis BCG cell walls to induce tumor regression in guinea pigs. Infect Immun., 28: 881-886
56. Allison, A.C. (1999) Squalene and squalane emulsions as adjuvants. Methods, 19: 87-93
57. Hickman, K.C.D. (1944) Purification of sludges, scums and the like to prepare relatively purified tocopherols. U.S. Patent 2,349,270
58. Brown, W. and Smith, F.E. (1964) Process for separating tocopherols and sterols from deodorizer sludge and the like. U.S. Patent 3,153,055
59. Ghosh, S. and Bhattacharyya, D.K. (1996) Isolation of tocopherols and sterols concentrate from sunflower oil deodorizer distillate. J. Am. Oil Chem. Soc., 73: 1271-1274
60. Shimada, Y.,Nakai, S., Suenaga, M., Sugihara, A.,Kitano, M., and Tominaga, Y. (2000) Facile purification of tocopherols from soybean oil deodorizer distillate in high yield using lipase. J. Am. Oil Chem. Soc., 77: 1009-1013
61. Martins P.F., Ito, V.M., Batistella, C.B., and Maciel, M.R.W. (2005) Free fatty acid separation from vegetable oil deodorizer distillate using molecular distillation process. Sep. Purif. Technol., 48: 78-84
62. Lee, H., Chung, B.H., and Park, Y.H. (1991) Concentration of tocopherols from soybean sludge by supercritical carbon dioxide. J. Am. Oil Chem. Soc., 68: 571-573
63. Nagesha, G., Manohar, B., and Sankar, K.U. (2003) Enrichment of tocopherols in modified soy deodorizer distillate using supercritical carbon dioxide extraction. Eur. Food Res. Technol., 217: 427-433
64. Chang, C., Chang, Y.F., Lee, H.Z., Lin, J.Q., and Yang, P.W. (2000) Supercritical carbon dioxide extraction of high-value substances from sunflower oil deodorizer distillate. Ind. Eng. Chem. Res., 39: 4521-4525
65. Ruthven, D.M. (1984) Principles of Adsorption and Adsorption Process; John Wiley and Sons Inc.: New York
66. Chu, B.S., Baharin, B.S., Che Man, Y.B., and Quek, S.Y. (2004) Separation of vitamin E from palm fatty acid distillate using silica: I Equilibrium of batch adsorption. J. Food Eng., 62: 97-103
67. Gunawan, S., Ismadji, S., and Ju, Y.H. (2008c) Design and operation of a modified silica gel column chromatography. J. Chin. Inst. Chem. Eng., 39: 625-633
68. Lietz, G. and Henry, C.J.K. (1997) A modified method to minimize losses of carotenoids and tocopherols during HPLC analysis of red plam oil. Food Chem., 60: 109-117
69. Slover, H.T., Thompson, R.H.J.R., and Merola, G. V. (1983) Determination of tocopherols and sterols by capillary gas chromatography. J. Am. Oil Chem. Soc., 60: 1524-1528
70. AOCS Official Method Ce 3-74, D. Firestone, 5th Ed. (1997) Tocopherols and Sterols in Soya Residue by GLC, Official Methods and Recommended Practices of the AOCS; American Oil Chemists' Society: Champaign, IL, U.S.A
71. Ruiz-Méndev, M.V. and Dobarganes, M.C. (2007) Combination of chromatographic techniques for the analysis of complex deodorizer distillates from an edible oil refining process. Food Chem., 103: 1502-1507
72. AOCS Official Method Ce 7-87, D. Firestone, 5th Ed. (1997) Tocopherols (total) in deodorizer distillate, Official Methods and Recommended Practices of the AOCS; American Oil Chemists' Society: Champaign, IL
73. Dumont, M.J. and Narine, S.S. (2007) Characterization of flax and soybean soapstocks, and soybean deodorizer distillate by GC-FID. J. Am. Oil Chem. Soc., 84: 1101-1105