ESIMS studies and calculations on alkali-metal adduct Ions of ruthenium olefin metathesis catalysts and their catalytic activity in metathesis reactions

Chemistry - A European Journal

Volumn 15, Issue 41, 2009, Pages 10948-10959

  Wang, Hao Yang ^a,b   Yim, Wai Leung ^a,c   Klüner, Thorsten ^a   Metzger, Jürgen O ^a  

^a UNIVERSITY OF OLDENBURG   (Germany)

^b SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

^c INSTITUTE OF HIGH PERFORMANCE COMPUTING   (Singapore)

Author keywords

Alkali metals; Cations; Mass spectrometry; Olefination; Pi interactions; Reactive intermediates

Indexed keywords

1-BUTENE; ACYCLIC DIENE METATHESIS; ADDUCT ION; ALKALI CATIONS; ALKYLIDENE CHAINS; ALKYLIDENES; BISPHOSPHINE; CATALYTIC ACTIVITY; CATALYTIC CYCLES; CATIONIZATION; CATIONIZED; CATIONS; CYCLOOCTENE; DOUBLE BONDS; ELECTROSPRAY IONIZATION MASS SPECTROMETRY; ENERGY PROFILE; ESI-MS/MS; GAS-PHASE REACTIONS; HEXADIENE; IN-SITU; ISOTOPIC PATTERN; MASS SPECTROMETRIC DETECTION; METATHESIS REACTIONS; MICRO-REACTOR; OCTADIENE; OLEFIN METATHESIS; OLEFINATION; ORMATION; PI INTERACTIONS; REACTION SOLUTIONS; REACTIVE INTERMEDIATES; RING OPENING METATHESIS POLYMERIZATION; RING-CLOSING METATHESIS REACTIONS; RUTHENIUM ALKYLIDENES; RUTHENIUM CATALYSTS; RUTHENIUM COMPLEXES; RUTHENIUM SPECIES; SIGNAL INTENSITIES; TANDEM MASS SPECTROMETRY;

BUTENES; CATALYSIS; CATALYST ACTIVITY; CESIUM; ELECTROCHEMICAL SENSORS; ELECTROSPRAY IONIZATION; ETHYLENE; HYDROCARBONS; ION SOURCES; IONIZATION OF GASES; MASS SPECTROMETERS; MASS SPECTROMETRY; METAL IONS; METALS; PHASE INTERFACES; POLYMERS; POSITIVE IONS; RING OPENING POLYMERIZATION; RUTHENIUM; STRUCTURAL METALS;

RUTHENIUM COMPOUNDS;

EID: 70350218752     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200900565     Document Type: Article

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