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Volumn 48, Issue 44, 2009, Pages 8186-8195

New syntheses of diazo compounds

Author keywords

Azides; Diazo compounds; Group transfer; Nitrogen groups; Synthetic methods

Indexed keywords

AZIDES; DIAZO COMPOUNDS; GROUP TRANSFER; NITROGEN GROUPS; SYNTHETIC METHODS;

EID: 70350034042     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200902785     Document Type: Review
Times cited : (226)

References (116)
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    • Major suppliers of fine chemicals list mainly ethyl diazoacetate (dissolved in toluene or dichloromethane), tert-butyl diazoacetate, (trimethylsilyl)diazomethane, ethyl 2-diazoacetoacetate, 2-diazodimedone, and some specialties
    • Major suppliers of fine chemicals list mainly ethyl diazoacetate (dissolved in toluene or dichloromethane), tert-butyl diazoacetate, (trimethylsilyl)diazomethane, ethyl 2-diazoacetoacetate, 2-diazodimedone, and some specialties.
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    • Diazomethane (b.p. -23°C) is thermally and photochemically labile and highly acid-sensitive; it can decompose when in contact with metal surfaces and sharp glass surfaces, is a skin irritant, has a high acute toxicity, and is a powerful carcinogen
    • Diazomethane (b.p. -23°C) is thermally and photochemically labile and highly acid-sensitive; it can decompose when in contact with metal surfaces and sharp glass surfaces, is a skin irritant, has a high acute toxicity, and is a powerful carcinogen.
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    • The Diazald procedure, which is carried out in a special glass apparatus (Aldrich) allows one to work on a 200-300 mmol scale, see: T. H. Black, Aldrichimica Acta 1983, 16(1), 3-10; see also Aldrich Technical Information Bulletin No. AL-180.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.