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Volumn 48, Issue 44, 2009, Pages 8321-8324

Microwave chemistry in silicon carbide reaction vials: Separating thermal from nonthermal effects

Author keywords

Electromagnetic fields; Microwave chemistry; Silicon carbide; Thermochemistry

Indexed keywords

BATH CHEMISTRY; CONDUCTIVE HEATING; MICROWAVE CHEMISTRY; MICROWAVE EFFECTS; MICROWAVE REACTORS; NON THERMAL EFFECT;

EID: 70350031640     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200904185     Document Type: Article
Times cited : (219)

References (24)
  • 1
    • 67349161331 scopus 로고    scopus 로고
    • For a recent review with more than 900 references and a tabular survey of ca. 200 microwave chemistry review articles, books, and book chapters, see: C. O. Kappe, D Dallinger, Mol. Diversity 2009, 13, 71.
    • (2009) Mol. Diversity , vol.13 , pp. 71
    • Kappe, C.O.1    Dallinger, D.2
  • 4
    • 18244368519 scopus 로고    scopus 로고
    • For a definition and examples for thermal, specific, and nonthermal microwave effects, see: a) C. O. Kappe, Angew. Chem. 2004, 116, 6408;
    • (2004) Angew. Chem. , vol.116 , pp. 6408
    • Kappe, C.O.1
  • 10
    • 70350039394 scopus 로고    scopus 로고
    • note
    • It should be emphasized, however, that it is rather difficult to perform appropriate control experiments to compare microwave- and conventionally heated processes in an oil bath, or autoclave, since these must be conducted at the exact same temperature (including heating and cooling profiles); other processing details such as vessel geometry, stirring speed, and the method of temperature monitoring should ideally also be identical. For a discussion, see:
  • 13
    • 70350040669 scopus 로고    scopus 로고
    • Experiments were performed in a commercial 2.45 GHz singlemode microwave reactor from Anton Paar GmbH (Monowave 300). For further details, see the Supporting Information and
    • Experiments were performed in a commercial 2.45 GHz singlemode microwave reactor from Anton Paar GmbH (Monowave 300). For further details, see the Supporting Information and http://www.anton-paar.com/monowave300.
  • 17
    • 70350027517 scopus 로고    scopus 로고
    • note
    • 0.5]. The thermal effusivity of the SiC used in these studies (Ekasic F SSiC, ESK Ceramics) is ≈ 10 times higher than that of standard Pyrex glass. See Table S1 in the Supporting Information.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.