-
6
-
-
0042326190
-
-
For a comprehensive review, see
-
For a comprehensive review, see: J. E. Ellis, Organometallics 2003, 22, 3322-3338.
-
(2003)
Organometallics
, vol.22
, pp. 3322-3338
-
-
Ellis, J.E.1
-
9
-
-
33745381287
-
-
b). P. G. Eller, D. C. Bradley, M. B. Hursthouse, D. W. Meek, Coord. Chem. Rev. 1977, 24, 1-95.
-
(1977)
Coord. Chem. Rev
, vol.24
, pp. 1-95
-
-
Eller, P.G.1
Bradley, D.C.2
Hursthouse, M.B.3
Meek, D.W.4
-
10
-
-
0041856069
-
-
a). R. Dorta, E. D. Stevens, C. D. Hoff, S. P. Nolan, J. Am. Chem. Soc. 2003, 125, 10490-10491.
-
(2003)
J. Am. Chem. Soc
, vol.125
, pp. 10490-10491
-
-
Dorta, R.1
Stevens, E.D.2
Hoff, C.D.3
Nolan, S.P.4
-
11
-
-
14744269446
-
-
b). R. Dorta, E. D. Stevens, N. M. Scott, C. Costabile, L. Cavallo, C. D. Hoff, S. P. Nolan, J. Am. Chem. Soc. 2005, 127, 2485-2495
-
(2005)
J. Am. Chem. Soc
, vol.127
, pp. 2485-2495
-
-
Dorta, R.1
Stevens, E.D.2
Scott, N.M.3
Costabile, C.4
Cavallo, L.5
Hoff, C.D.6
Nolan, S.P.7
-
13
-
-
0001560644
-
-
W. Petz, F. Weller, J. Uddin, G. Frenking, Organometallics 1999, 18, 619-626.
-
(1999)
Organometallics
, vol.18
, pp. 619-626
-
-
Petz, W.1
Weller, F.2
Uddin, J.3
Frenking, G.4
-
14
-
-
70349955847
-
-
NHC ligands have been recognized as primarily strong σ donors with π-acidity properties that are dependent on a host of factors, see
-
NHC ligands have been recognized as primarily strong σ donors with π-acidity properties that are dependent on a host of factors, see:
-
-
-
-
16
-
-
38949179137
-
-
b). R. A. Kelly III, H. Clavier, S. Giudice, N. M. Scott, E. D. Stevens, J. Bordner, I. Samardjiev, C. D. Hoff, L. Cavallo, S. P. Nolan, Organometallics 2008, 27, 202-210.
-
(2008)
Organometallics
, vol.27
, pp. 202-210
-
-
Kelly III, R.A.1
Clavier, H.2
Giudice, S.3
Scott, N.M.4
Stevens, E.D.5
Bordner, J.6
Samardjiev, I.7
Hoff, C.D.8
Cavallo, L.9
Nolan, S.P.10
-
17
-
-
33845929780
-
-
c). M. D. Sanderson, J. W. Kamplain, C. W. Bielawski, J. Am. Chem. Soc. 2006, 128, 16514-16515
-
(2006)
J. Am. Chem. Soc
, vol.128
, pp. 16514-16515
-
-
Sanderson, M.D.1
Kamplain, J.W.2
Bielawski, C.W.3
-
18
-
-
1442334129
-
-
d). X. Hu, I. Castro Rodriguez, K. Olsen, K. Meyer, Organometallics 2004, 23, 755 -764
-
(2004)
Organometallics
, vol.23
, pp. 755-764
-
-
Hu, X.1
Castro Rodriguez, I.2
Olsen, K.3
Meyer, K.4
-
19
-
-
3342884638
-
-
e). D. Nemcsok, K. Wichmann, G. Frenking, Organometallics 2004, 23, 3640-3646.
-
(2004)
Organometallics
, vol.23
, pp. 3640-3646
-
-
Nemcsok, D.1
Wichmann, K.2
Frenking, G.3
-
20
-
-
0001004042
-
-
S. Otsuka, T. Yoshida, T. Tatsuno, J. Am. Chem. Soc. 1971, 93, 6462 -6469.
-
(1971)
J. Am. Chem. Soc
, vol.93
, pp. 6462-6469
-
-
Otsuka, S.1
Yoshida, T.2
Tatsuno, T.3
-
21
-
-
54249158830
-
-
B. J. Fox, Q. Y. Sun, A. G. DiPasquale, A. R. Fox, A. L. Rheingold, J. S. Figueroa, Inorg. Chem. 2008, 47, 9010-9020.
-
(2008)
Inorg. Chem
, vol.47
, pp. 9010-9020
-
-
Fox, B.J.1
Sun, Q.Y.2
DiPasquale, A.G.3
Fox, A.R.4
Rheingold, A.L.5
Figueroa, J.S.6
-
22
-
-
0035835070
-
-
V. J. Catalano, B. L. Bennett, S. Muratidis, B. C. Noll, J. Am. Chem. Soc. 2001, 123, 173-174.
-
(2001)
J. Am. Chem. Soc
, vol.123
, pp. 173-174
-
-
Catalano, V.J.1
Bennett, B.L.2
Muratidis, S.3
Noll, B.C.4
-
23
-
-
33845279244
-
-
For example, see: a
-
For example, see: a). J. K. Nagle, A. L. Balch, M. M. Olmstead, J. Am. Chem. Soc. 1988, 110, 319-321
-
(1988)
J. Am. Chem. Soc
, vol.110
, pp. 319-321
-
-
Nagle, J.K.1
Balch, A.L.2
Olmstead, M.M.3
-
24
-
-
0000792272
-
-
b). S. Wang, G. Garzon, C. King, J-.C. Wang, J. P. Fackler, Inorg. Chem. 1989, 28, 4623 - 4629
-
(1989)
Inorg. Chem
, vol.28
, pp. 4623-4629
-
-
Wang, S.1
Garzon, G.2
King, C.3
Wang, J.C.4
Fackler, J.P.5
-
26
-
-
0001692023
-
-
d). M. Dolg, P. Pyykkö, N. Runeberg, Inorg. Chem. 1996, 35, 7450 - 7451
-
(1996)
Inorg. Chem
, vol.35
, pp. 7450-7451
-
-
Dolg, M.1
Pyykkö, P.2
Runeberg, N.3
-
27
-
-
0033520799
-
-
e). V. J. Catalano, B. L. Bennett, H. M. Kar, B. C. Noll, J. Am. Chem. Soc. 1999, 121, 10235-10236
-
(1999)
J. Am. Chem. Soc
, vol.121
, pp. 10235-10236
-
-
Catalano, V.J.1
Bennett, B.L.2
Kar, H.M.3
Noll, B.C.4
-
28
-
-
0034684275
-
-
f). V. J. Catalano, B. L. Bennett, R. L. Yson, B. C. Noll, J. Am. Chem. Soc. 2000, 122, 10056-10062
-
(2000)
J. Am. Chem. Soc
, vol.122
, pp. 10056-10062
-
-
Catalano, V.J.1
Bennett, B.L.2
Yson, R.L.3
Noll, B.C.4
-
29
-
-
11044234764
-
-
g). N. Oberbeckmann-Winter, P. Braunstein, R. Welter, Organometallics 2004, 23, 6311 -6318
-
(2004)
Organometallics
, vol.23
, pp. 6311-6318
-
-
Oberbeckmann-Winter, N.1
Braunstein, P.2
Welter, R.3
-
30
-
-
3142715970
-
-
III interactions, see: G. Ma, M. Kritikos, M. Maliarik, J. Glaser, Inorg. Chem. 2004, 43, 4328 -4340 and references therein.
-
III interactions, see: G. Ma, M. Kritikos, M. Maliarik, J. Glaser, Inorg. Chem. 2004, 43, 4328 -4340 and references therein.
-
-
-
-
33
-
-
70349946462
-
-
Complexes containing M → Lewis acid reverse-dative σ interactions have received increased attention in recent years. See
-
Complexes containing M → Lewis acid reverse-dative σ interactions have received increased attention in recent years. See:
-
-
-
-
34
-
-
60749083081
-
-
a). S. Bontemps, G. Bouhadir, W. Gu, M. Mercy, C.-H. Chen, B. M. Foxman, L. Maron, O. V. Ozerov, D. Bourissou, Angew. Chem. 2008, 120, 1503-1506;
-
(2008)
Angew. Chem
, vol.120
, pp. 1503-1506
-
-
Bontemps, S.1
Bouhadir, G.2
Gu, W.3
Mercy, M.4
Chen, C.-H.5
Foxman, B.M.6
Maron, L.7
Ozerov, O.V.8
Bourissou, D.9
-
35
-
-
41749100255
-
-
Angew. Chem. Int. Ed. 2008, 47, 1481-1484;
-
(2008)
Angew. Chem. Int. Ed
, vol.47
, pp. 1481-1484
-
-
-
36
-
-
54149101511
-
-
H. Braunschweig, K. Gruss, K. Radacki, Inorg. Chem. 2008, 47, 8595 - 8597
-
(2008)
Inorg. Chem
, vol.47
, pp. 8595-8597
-
-
Braunschweig, H.1
Gruss, K.2
Radacki, K.3
-
37
-
-
55249089738
-
-
b). D. J. H. Emslie, L. E. Harrington, H. A. Jenkins, C. M. Robertson, J. F. Britten, Organometallics 2008, 27, 5317-5325
-
(2008)
Organometallics
, vol.27
, pp. 5317-5325
-
-
Emslie, D.J.H.1
Harrington, L.E.2
Jenkins, H.A.3
Robertson, C.M.4
Britten, J.F.5
-
38
-
-
33847766232
-
-
c). J. B. Bonanno, T. P. Henry, P. T. Wolczanski, A. W. Pierpont, T. R. Cundari, Inorg. Chem. 2007, 46, 1222-1232
-
(2007)
Inorg. Chem
, vol.46
, pp. 1222-1232
-
-
Bonanno, J.B.1
Henry, T.P.2
Wolczanski, P.T.3
Pierpont, A.W.4
Cundari, T.R.5
-
39
-
-
33748774699
-
-
d). S. Bontemps, G. Bouhadir, K. Miqueu, D. Bourissou, J. Am. Chem. Soc. 2006, 128, 12056-12057
-
(2006)
J. Am. Chem. Soc
, vol.128
, pp. 12056-12057
-
-
Bontemps, S.1
Bouhadir, G.2
Miqueu, K.3
Bourissou, D.4
-
40
-
-
33751006589
-
-
e). B. Buchin, C. Gemel, T. Cadenbach, I. Fernandez, G. Frenking, R. A. Fischer, Angew. Chem. 2006, 118, 5331 -5334;
-
(2006)
Angew. Chem
, vol.118
, pp. 5331-5334
-
-
Buchin, B.1
Gemel, C.2
Cadenbach, T.3
Fernandez, I.4
Frenking, G.5
Fischer, R.A.6
-
41
-
-
33747266391
-
-
Angew. Chem. Int. Ed. 2006, 45, 5207-5210
-
(2006)
Angew. Chem. Int. Ed
, vol.45
, pp. 5207-5210
-
-
-
43
-
-
0031139306
-
-
P. Pyykkö, Chem. Rev. 1997, 97, 597 - 636.
-
(1997)
Chem. Rev
, vol.97
, pp. 597-636
-
-
Pyykkö, P.1
-
44
-
-
0000459933
-
-
L. Gade, Angew. Chem. 2001, 113, 3685-3688;
-
(2001)
Angew. Chem
, vol.113
, pp. 3685-3688
-
-
Gade, L.1
-
45
-
-
0035477037
-
-
Angew. Chem. Int. Ed. 2001, 40, 3573 -3575.
-
(2001)
Angew. Chem. Int. Ed
, vol.40
, pp. 3573-3575
-
-
-
46
-
-
34250701639
-
-
The Cambridge Structural Database contains several complexes featuring first-row metal-Tl bonds where the Tl atom is coordinated by several additional ligands. CSD v. 5.29, Nov. 2007. For a recent example featuring a divalent Ni center, see: M. Maliarik, J. K. Nagle, A. Ilyukhin, E. Murashova, J. Mink, M. Skripkin, J. Glaser, M. Kovacs, A. Horváth, Inorg. Chem. 2007, 46, 4642 -4653.
-
The Cambridge Structural Database contains several complexes featuring first-row metal-Tl bonds where the Tl atom is coordinated by several additional ligands. CSD v. 5.29, Nov. 2007. For a recent example featuring a divalent Ni center, see: M. Maliarik, J. K. Nagle, A. Ilyukhin, E. Murashova, J. Mink, M. Skripkin, J. Glaser, M. Kovacs, A. Horváth, Inorg. Chem. 2007, 46, 4642 -4653.
-
-
-
-
47
-
-
70349951477
-
-
3]X complexes. See ref. [9].
-
3]X complexes. See ref. [9].
-
-
-
-
48
-
-
84874241260
-
-
The LUMO of the model [Ni(CNArPh2)3] is also supplemented with π* character from the isocyanide ligands
-
* character from the isocyanide ligands. See the Supporting Information for details.
-
See the Supporting Information for details
-
-
-
49
-
-
0034804183
-
-
For recent examples of monovalent Ni complexes, see: a
-
For recent examples of monovalent Ni complexes, see: a) D. J. Mindiola, G. L. Hillhouse, J. Am. Chem. Soc. 2001, 123, 4623 - 4624
-
(2001)
J. Am. Chem. Soc
, vol.123
, pp. 4623-4624
-
-
Mindiola, D.J.1
Hillhouse, G.L.2
-
50
-
-
0037021483
-
-
b). P. L. Holland, T. R. Cundari, L. L. Perez, N. A. Eckert, R.J. Lachicotte, J. Am. Chem. Soc. 2002, 124, 14416-14424.
-
(2002)
J. Am. Chem. Soc
, vol.124
, pp. 14416-14424
-
-
Holland, P.L.1
Cundari, T.R.2
Perez, L.L.3
Eckert, N.A.4
Lachicotte, R.J.5
-
51
-
-
3242749800
-
-
c). C. E. MacBeth, J. C. Thomas, T. A. Betley, J. C. Peters, Inorg. Chem. 2004, 43, 4645 - 4662
-
(2004)
Inorg. Chem
, vol.43
, pp. 4645-4662
-
-
MacBeth, C.E.1
Thomas, J.C.2
Betley, T.A.3
Peters, J.C.4
-
52
-
-
4344700854
-
-
d). K. D. Kitiachvili, D. J. Mindiola, G. L. Hillhouse, J. Am. Chem. Soc. 2004, 126, 10554-10555
-
(2004)
J. Am. Chem. Soc
, vol.126
, pp. 10554-10555
-
-
Kitiachvili, K.D.1
Mindiola, D.J.2
Hillhouse, G.L.3
-
54
-
-
23844474002
-
-
f). E. Kogut, H. L. Wiencko, L. Zhang, D. E. Cordeau, T. H. Warren, J. Am. Chem. Soc. 2005, 127, 11248-11249
-
(2005)
J. Am. Chem. Soc
, vol.127
, pp. 11248-11249
-
-
Kogut, E.1
Wiencko, H.L.2
Zhang, L.3
Cordeau, D.E.4
Warren, T.H.5
-
56
-
-
44149112067
-
-
h). B. C. Fullmer, M. Pink, H. Fan, X. Yang, M.-H. Baik, K. G. Caulton, Inorg. Chem. 2008, 47, 3888-3892.
-
(2008)
Inorg. Chem
, vol.47
, pp. 3888-3892
-
-
Fullmer, B.C.1
Pink, M.2
Fan, H.3
Yang, X.4
Baik, M.-H.5
Caulton, K.G.6
-
57
-
-
0343967297
-
-
See for example: a
-
See for example: a). A. Gleizes, M. Dartiguenave, Y. Dartiguenave, J. Galy, H. F. Klein, J. Am. Chem. Soc. 1977, 99, 5187-5189
-
(1977)
J. Am. Chem. Soc
, vol.99
, pp. 5187-5189
-
-
Gleizes, A.1
Dartiguenave, M.2
Dartiguenave, Y.3
Galy, J.4
Klein, H.F.5
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