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Volumn 121, Issue 34, 1999, Pages 7877-7884

Electronic structure-of the H cluster in [Fe]-hydrogenases

Author keywords

[No Author keywords available]

Indexed keywords

CARBON MONOXIDE; CARBON MONOXIDE DEHYDROGENASE; CYANIDE; CYSTEINE; FERRIC ION; FERROUS ION; HYDROGENASE; IRON SULFUR PROTEIN; SULFITE REDUCTASE; THIOACETIC ACID;

EID: 0042357244     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja991243y     Document Type: Article
Times cited : (172)

References (58)
  • 27
    • 0345435131 scopus 로고    scopus 로고
    • note
    • To our knowledge, Cp Hydrogenase II preparations are currently not available in any laboratory.
  • 29
    • 0345004021 scopus 로고    scopus 로고
    • note
    • II redox couple.
  • 31
    • 0345004020 scopus 로고    scopus 로고
    • note
    • 2 Thus, the analysis of Rusnak et al. resulted in fractions corresponding almost exactly to the cluster distribution which is now established.
  • 33
    • 0345004018 scopus 로고    scopus 로고
    • note
    • ox is obtained.
  • 34
    • 0344141480 scopus 로고    scopus 로고
    • The raw data used are from the studies of Rusnak et al.; see also ref 29
    • The raw data used are from the studies of Rusnak et al.; see also ref 29.
  • 35
    • 0344572961 scopus 로고
    • Ph.D. Thesis, University of Minnesota
    • Rusnak, F. M. Ph.D. Thesis, University of Minnesota, 1988.
    • (1988)
    • Rusnak, F.M.1
  • 38
    • 0344141477 scopus 로고    scopus 로고
    • note
    • ox-CO (the so-called "axial 2.06" state in the D. vulgaris nomenclature). The values of the isomer shifts, quoted as 0.50 and 0.58 mm/s (see Table 3 of ref 32), have large uncertainties and are not suitable for a critical comparison with the data of hydrogenase II. The spectra of the D. vulgaris enzyme are presently being reanalyzed (B. H. Huynh, personal communication).
  • 43
    • 0344572959 scopus 로고    scopus 로고
    • note
    • red-CO are linked also by a cysteinyl sulfur.
  • 45
    • 0344141425 scopus 로고    scopus 로고
    • Unpublished data of Adams, M. W. W. quoted in ref 1
    • Unpublished data of Adams, M. W. W. quoted in ref 1.
  • 46
    • 33751021526 scopus 로고
    • (a) Griffith, J. S. Nature 1957, 180, 30-31.
    • (1957) Nature , vol.180 , pp. 30-31
    • Griffith, J.S.1
  • 50
    • 0345004013 scopus 로고    scopus 로고
    • note
    • ox-CO.
  • 51
    • 0345003980 scopus 로고    scopus 로고
    • note
    • For the considerations in this paragraph we assume for simplicity that the unpaired spin resides on Fe(1).
  • 53
    • 0345435095 scopus 로고    scopus 로고
    • note
    • H such that the 1+ state is not accessible anymore at potentials above -450 mV.
  • 56
    • 0345003979 scopus 로고    scopus 로고
    • note
    • ox could yield very weak MCD features and the observed signal might result from some unidentified entity.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.