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C,P-Cyclometallated complexes have been reported as robust catalysts for 1,4-additions of arylboronic acids and arylsiloxanes to enones see: (a) 1,2-additions and 1,4 additions of arylboronic acids to aldehydes, aldimines, α,βunsaturated ketones, and a-ketoesters see
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C,P-Cyclometallated complexes have been reported as robust catalysts for 1,4-additions of arylboronic acids and arylsiloxanes to enones (see: (a) Bedford, R. B.; Betham, M.; Charmant, J. P. H.; Haddow, M. F.; Orpen, A. G.; Pilarski, L. T. Organometallics 2007, 26, 6346), 1,2-additions and 1,4 additions of arylboronic acids to aldehydes, aldimines, α,βunsaturated ketones, and a-ketoesters (see:,
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Our work in preparing the chiral C, P-cyclopalladated and -platinated complexes 12-14 could pave a route to access the asymmetric catalytic version of these reactions.
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(e) Bedford, R. B.; Pilarski, L. T. Tetrahedron Lett. 2008, 49, 4216). Our work in preparing the chiral C, P-cyclopalladated and -platinated complexes 12-14 could pave a route to access the asymmetric catalytic version of these reactions.
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