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Volumn 126, Issue 45, 2004, Pages 14704-14705

Nickel(II)-catalyzed highly enantioselective hydrophosphination of methacrylonitrile

Author keywords

[No Author keywords available]

Indexed keywords

METAL COMPLEX; METHACRYLONITRILE; NICKEL; ORGANIC COMPOUND; PHOSPHINE DERIVATIVE; TRANSITION ELEMENT;

EID: 8844228155     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0449574     Document Type: Article
Times cited : (162)

References (24)
  • 19
    • 0001166795 scopus 로고
    • The % ee of 3e was determined by reaction of the oxidized product and a chiral shift reagent tris(3-trifluoromethylhydroxymethylene-d-camphorate) europium. See: McCreary, M. D.; Lewis, D. W.; Wernick, D. L.; Whitesides, G. M. J. Am. Chem. Soc. 1974, 96, 1038-1054.
    • (1974) J. Am. Chem. Soc. , vol.96 , pp. 1038-1054
    • McCreary, M.D.1    Lewis, D.W.2    Wernick, D.L.3    Whitesides, G.M.4
  • 23
    • 8844253177 scopus 로고    scopus 로고
    • note
    • (a) See Supporting Information,
  • 24
    • 8844253350 scopus 로고    scopus 로고
    • note
    • (b) Absolute configurations were determined by X-ray crystallographic analysis of adducts derived from 3 and an enantiopure Pd complex of known absolute configuration. Note that the sense of chiral induction is the same in both reactions, although the descriptor of the absolute configuration of the major enantiomers changes from R (hydroamination) to S (hydrophosphination) due to different priority sequences of the substituents at the respective stereogenic center.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.