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For the synthesis of allylated Baylis-Hillman adducts, see:.
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For the synthesis of vinyl moiety-containing Baylis-Hillman adducts, see.
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For the synthesis of arylated Baylis-Hillman adducts by Friedel-Crafts reaction, see.
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For the synthesis of arylated Baylis-Hillman adducts using metal catalyst, see.
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For our recent contributions on Pd-mediated reactions of modified Baylis-Hillman adducts, see.
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For the Pd-mediated cross-coupling reactions between allylic bromides (and acetates) and organostannanes, see.
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73249141700
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At the initial stage of this work, the reaction of Baylis-Hillman alcohol 1a and allyltributylstannane was examined, however, we did not observe the formation of 3a. The reaction of the acetate of 1a was also examined. Although the reaction rate of Baylis-Hillman acetate was faster than that of the bromide, appreciable amounts of side products including 3a-Z (ca. 5%) and secondary adduct (ca. 5%) was observed.
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73249119499
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For the synthesis of cinnamyl bromide derivatives in a stereoselective manner, see.
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1H NMR). For the stereoselective synthesis of primary alcohol, see.
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55
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73249140541
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For the similar cinnamyltin compounds, see.
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