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Volumn 30, Issue 3, 2009, Pages 726-728

Pd-mediated cross-coupling reactions between the bromide of Baylis-Hillman adduct and organostannanes

Author keywords

Baylis Hillman adduct; Cross coupling; Organostannanes; Palladium

Indexed keywords


EID: 70349219470     PISSN: 02532964     EISSN: 12295949     Source Type: Journal    
DOI: 10.5012/bkcs.2009.30.3.726     Document Type: Note
Times cited : (15)

References (63)
  • 1
    • 73249130758 scopus 로고    scopus 로고
    • Note
    • For general review on Baylis-Hillman reaction, see.
  • 3
    • 0000892247 scopus 로고    scopus 로고
    • Paquette, L.A., Ed.; John Wiley & Sons: New York
    • Ciganek, E. In Organic Reactions; Paquette, L.A., Ed.; John Wiley & Sons: New York, 1997; Vol. 51, pp 201-350.
    • (1997) Organic Reactions , vol.51 , pp. 201-350
    • Ciganek, E.1
  • 7
    • 41649086484 scopus 로고    scopus 로고
    • and further references cited therein
    • Singh, V.; Batra, S. Tetrahedron 2008, 64, 4511-4574 and further references cited therein.
    • (2008) Tetrahedron , vol.64 , pp. 4511-4574
    • Singh, V.1    Batra, S.2
  • 8
    • 73249126914 scopus 로고    scopus 로고
    • Note
    • For the synthesis of allylated Baylis-Hillman adducts, see:.
  • 13
    • 73249147084 scopus 로고    scopus 로고
    • Note
    • For the synthesis of vinyl moiety-containing Baylis-Hillman adducts, see.
  • 16
    • 73249127746 scopus 로고    scopus 로고
    • Note
    • For the synthesis of arylated Baylis-Hillman adducts by Friedel-Crafts reaction, see.
  • 22
    • 73249129503 scopus 로고    scopus 로고
    • Note
    • For the synthesis of arylated Baylis-Hillman adducts using metal catalyst, see.
  • 28
    • 73249134321 scopus 로고    scopus 로고
    • Note
    • For our recent contributions on Pd-mediated reactions of modified Baylis-Hillman adducts, see.
  • 35
    • 73249133921 scopus 로고    scopus 로고
    • Note
    • For the Pd-mediated cross-coupling reactions between allylic bromides (and acetates) and organostannanes, see.
  • 40
    • 73249141700 scopus 로고    scopus 로고
    • Note
    • At the initial stage of this work, the reaction of Baylis-Hillman alcohol 1a and allyltributylstannane was examined, however, we did not observe the formation of 3a. The reaction of the acetate of 1a was also examined. Although the reaction rate of Baylis-Hillman acetate was faster than that of the bromide, appreciable amounts of side products including 3a-Z (ca. 5%) and secondary adduct (ca. 5%) was observed.
  • 41
    • 73249119499 scopus 로고    scopus 로고
    • Note
    • For the synthesis of cinnamyl bromide derivatives in a stereoselective manner, see.
  • 51
    • 73249133713 scopus 로고    scopus 로고
    • Note
    • 1H NMR). For the stereoselective synthesis of primary alcohol, see.
  • 55
    • 73249140541 scopus 로고    scopus 로고
    • Note
    • For the similar cinnamyltin compounds, see.
  • 60
    • 73249139927 scopus 로고    scopus 로고
    • Note
    • For the dimerization product 8a, see:.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.