Transition-state charge transfer reveals electrophilic, ambiphilic, and nucleophilic carbon-hydrogen bond activation

Journal of the American Chemical Society

Volumn 131, Issue 33, 2009, Pages 11686-11688

  Ess, Daniel H ^a,b   Nielsen, Robert J ^a   Goddard III, William A ^a   Periana, Roy A ^b  

^a California Institute of Technology   (United States)

^b SCRIPPS RESEARCH INSTITUTE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION REACTION; ANTIBONDING ORBITAL; BOND METATHESIS; C-H ACTIVATION; C-H BOND; FUNCTIONALIZATION REACTIONS; HYDROGEN MIGRATION; LOCALIZED MOLECULAR ORBITALS; METAL CENTERS; NUCLEOPHILIC ACTIVATION; NUCLEOPHILIC CARBON; ORBITAL STABILIZATION; OXIDATIVE ADDITIONS; TRANSITION STATE;

CHARGE TRANSFER; CHEMICAL ACTIVATION; GOLD COMPOUNDS; HYDROGEN; HYDROGEN BONDS; ION EXCHANGE; IRIDIUM; MASS TRANSFER; MOLECULAR ORBITALS; PLATINUM; SCANDIUM;

ACTIVATION ANALYSIS;

ELECTROPHILE; NUCLEOPHILE;

ARTICLE; CARBON HYDROGEN BOND; CATALYST; CHEMICAL BOND; PROTON TRANSPORT;

EID: 69049101135     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja902748c     Document Type: Article

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