Synthesis and reactivity of the octahedral d6 parent amido complexes TpRu(L)(L′)(NH2) (Tp = hydridotris(pyrazolyl)borate; L = L′ = PMe3, P(OMe)3; L = CO, L′ = PPh3) and [TpRu(PPh3)(NH2)2][Li]

Organometallics

Volumn 20, Issue 25, 2001, Pages 5254-5256

  Jayaprakash, K N ^a   Conner, David ^a   Gunnoe, T Brent ^a  

^a NORTH CAROLINA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMIDO COMPLEXES; HYDRIDOTRIS PYRAZOLYL BORATE; PHENYLACETYLENE;

ACETYLENE; COMPLEXATION; ELECTRONIC STRUCTURE; HYDROGEN BONDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RUTHENIUM COMPOUNDS; SYNTHESIS (CHEMICAL);

ORGANOMETALLICS;

EID: 0035843064     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010739x     Document Type: Article

References (23)

1. Mayer, J. M. Comments Inorg. Chem. 1988, 8, 125-135.
2. Bergman, R. G. Polyhedron 1995, 14, 3227-3237.
3. Holland, P. L.; Andersen, R. A.; Bergman, R. G. Comments Inorg. Chem. 1999, 21, 115-129.
4. Cundari, T. R. Chem. Rev. 2000, 100, 807-818.
5. Sharp, P. R. Comments Inorg. Chem. 1999, 21, 85-114.
6. Sharp, P. R. J. Chem. Soc., Dalton Trans. 2000, 2647-2657.
7. Bryndza, H. E.; Fong, L. K.; Paciello, R. A.; Tam, W.; Bercaw, J. E. J. Am. Chem. Soc. 1987, 109, 1444-1456.
8. Hartwig, J. F.; Andersen, R. A.; Bergman, R. G. Organometallics 1991, 10, 1875-1887.
9. Caulton, K. G. New J. Chem. 1994, 18, 25-41.
10. Kaplan, A. W.; Ritter, J. C. M.; Bergman, R. G. J. Am. Chem. Soc. 1998, 120, 6828-6829.
11. Fulton, J. R.; Bouwkamp, M. W.; Bergman, R. G. J. Am. Chem. Soc. 2000, 122, 8799-8800.
12. Joslin, F. L.; Johnson, M. P.; Mague, J. T.; Roundhill, D. M. Organometallics 1991, 10, 2781-2794.
13. Slugovc, C.; Schmid, R.; Kirchner, K. Coord. Chem. Rev. 1999, 185-186, 109-126.
14. Buriez, B.; Burns, I. D.; Hill, A. F.; White, A. J. P.; Williams, D. J.; Wilton-Ely, J. D. E. T. Organometallics 1999, 18, 1504-1516.
15. Sun, N.-Y.; Simpson, S. J. J. Organomet. Chem. 1992, 434, 341-349.
16. 2RuS: C, 26.39; H, 4.29; N, 13.46; Found: C, 26.22; H, 4.23; N, 13.23.
17. Macgregor, S. A.; MacQueen, D. Inorg. Chem. 1999, 38, 4868-4876.
18. Dewey, M. A.; Knight, D. A.; Arif, A.; Gladysz, J. A. Chem. Ber. 1992, 125, 815-824.
19. +.
20. Lowry, T. H.; Richardson, K. S. Mechanism and Theory in Organic Chemistry, 3rd ed.; Harper Collins: New York, 1987.
21. Conner, D.; Jayaprakash, K. N.; Gunnoe, T. B. Manuscript in preparation.
22. (a) Jayaprakash, K. N.; Gunnoe, T. B. Inorg. Chem., in press.
23. 3)(NHPh) does react with phenylacetylene at elevated temperatures. This reaction will be detailed in a future publication.