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The complex 4 is structurally characterized but not 3; however, physicochemical studies (cf. electronic spectra, redox properties) show that the cations of these two complexes are identical
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(a) The complex 4 is structurally characterized but not 3; however, physicochemical studies (cf. electronic spectra, redox properties) show that the cations of these two complexes are identical.
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It should be mentioned here that because of solubility reasons in 33% MeOH-H2O mixture v/v; ionic strength was maintained at I= 0.1 M NaNO3, potentiometric and kinetic experiments were done with complex 3 instead of 4. Complex 4 was synthesized only to grow single-crystals
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3), potentiometric and kinetic experiments were done with complex 3 instead of 4. Complex 4 was synthesized only to grow single-crystals.
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