Combined spectroscopic/computational study of binuclear Fe(I)-Fe(I) complexes: Implications for the fully-reduced active-site cluster of Fe-only hydrogenases

Inorganic Chemistry

Volumn 44, Issue 6, 2005, Pages 1794-1809

  Fiedler, Adam T ^a   Brunold, Thomas C ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

1,3 PROPANE DITHIOLATE; DIMER; DITHIOL DERIVATIVE; HYDROGENASE; IRON COMPLEX; UNCLASSIFIED DRUG;

ABSORPTION; ARTICLE; CATALYSIS; CIRCULAR DICHROISM; CLUSTER ANALYSIS; DENSITY FUNCTIONAL THEORY; MATHEMATICAL ANALYSIS; RAMAN SPECTROMETRY; SPECTROSCOPY;

BINDING SITES; CATALYSIS; CHEMISTRY, PHYSICAL; COMPUTATIONAL BIOLOGY; DESULFOVIBRIO; HYDROGENASE; IRON; IRON-SULFUR PROTEINS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; SPECTROPHOTOMETRY; THERMODYNAMICS;

EID: 15944389809     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic048739n     Document Type: Article

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101. -1.
102. Cys bond distance was fixed at 2.35 Å, which is compatible with the distance of 2.38 Å found crystallographically.
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107. b conformation.
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110. -1.