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A. Hamiltonian in the form. Ĥ, 2JŜ1, Ŝ2, gμB(S1, S2).B was used. Simulation of the experimental magnetic data with a full-matrix diagonalization of exchange coupling and Zeeman splitting was performed with the julX program (E. Bill, Max-Planck-Institut für Bioanorganische Chemie, Mülheim an der Ruhr, Germany, Before simulation, the experimental data were corrected for the underlying diamagnetism by using tabu-lated Pascal constants (incremental method) and for tempera-ture-independent paramagnetism (TIP, A Curie, Weiss-be-haved paramagnetic impurity (PI) with spin S, 5/2 was in-cluded according to χ, 1- PI, χ, PI.χmono. Best fit param-eters for 1 J, 180 cm-1, g, 2.000 (fixed, PI= 1.7, χ(TIP, 35.3 X 10-6 cm 3 mol-1; for 2: J, 158 cm-1, g, 2.000 fixed, PI, 0.9
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