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Volumn 48, Issue 1, 2009, Pages 90-99

Synthesis and coordination properties of chelating dithiophenolate ligands

Author keywords

[No Author keywords available]

Indexed keywords

CHELATING AGENT; LIGAND; ORGANOMETALLIC COMPOUND; PHENOL DERIVATIVE; SULFUR; THIOL DERIVATIVE; THIOPHENOL; TIN; ZINC;

EID: 59849121961     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic801285u     Document Type: Article
Times cited : (23)

References (48)
  • 5
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    • McCleverty, J. A, Meyer, T. J, Eds, Elsevier: Oxford
    • Haiduc, I. In Comprehensive Coordination Chemistry II; McCleverty, J. A., Meyer, T. J., Eds.; Elsevier: Oxford, 2004; Vol. 1, pp 349-376.
    • (2004) Comprehensive Coordination Chemistry II , vol.1 , pp. 349-376
    • Haiduc, I.1
  • 11
    • 33748711147 scopus 로고
    • See, for example, a
    • See, for example, (a) Sorrell, T. N.; Ellis, D. J. J. Org. Chem. 1985, 50, 5765-5769.
    • (1985) J. Org. Chem , vol.50 , pp. 5765-5769
    • Sorrell, T.N.1    Ellis, D.J.2
  • 15
    • 85153008430 scopus 로고    scopus 로고
    • Complexes of the related naphthalene-1,8-bis(thiolato) ligand are known; see, for example, (a) Tesmer, M.; Vahrenkamp, H. Eur. J. Inorg. Chem. 2001, 1183-1188.
    • Complexes of the related naphthalene-1,8-bis(thiolato) ligand are known; see, for example, (a) Tesmer, M.; Vahrenkamp, H. Eur. J. Inorg. Chem. 2001, 1183-1188.
  • 17
    • 78751616278 scopus 로고    scopus 로고
    • and references therein. For structural trends in homoleptic metal dithiolenes, see
    • For structural trends in homoleptic metal dithiolenes, see Beswick, C. L.; Schulman, J. M.; Stiefel, E. I. Prog. Inorg. Chem. 2003, 52. 55-110; and references therein.
    • (2003) Prog. Inorg. Chem , vol.52 , pp. 55-110
    • Beswick, C.L.1    Schulman, J.M.2    Stiefel, E.I.3
  • 19
    • 78751499923 scopus 로고    scopus 로고
    • Photochemical and solid-state properties, for example, have been summarized in Cummings, S. D.; Eisenberg, R. Prog. lnorg. Chem. 2003, 52, 315-368.
    • Photochemical and solid-state properties, for example, have been summarized in Cummings, S. D.; Eisenberg, R. Prog. lnorg. Chem. 2003, 52, 315-368.
  • 30
    • 61849095838 scopus 로고    scopus 로고
    • Lemire, A.; E.; Thompson, J. C. Can. J. Chem. 1970, 48, 824-829.
    • Lemire, A.; E.; Thompson, J. C. Can. J. Chem. 1970, 48, 824-829.
  • 35
    • 61849125513 scopus 로고    scopus 로고
    • 4 = 1/141° x (360° - α - β), with α and β defined as the two largest angles (Ligand)-(Metal)-(Ligand) in the four-coordinate complex: Yang, L.; Powell, D. R.; Houser, R. P. Dalton Trans. 2007, 955-964.
    • 4 = 1/141° x (360° - α - β), with α and β defined as the two largest angles (Ligand)-(Metal)-(Ligand) in the four-coordinate complex: Yang, L.; Powell, D. R.; Houser, R. P. Dalton Trans. 2007, 955-964.
  • 36
    • 37049096497 scopus 로고    scopus 로고
    • The τ5 value has been proposed as a simple geometry index to quantify the distortion from trigonal bipyramidal geometry (τ5, 1) for five- coordinate species and is calculated by τ5, 1/60° × (β, α, with a and β defined as the two largest angles (Ligand, Metal, Ligand) in the five-coordinate complex. Thus, τ5 values for ideally square pyramidal five-coordinate complexes are equal to zero: (a) Addison, A. W, Rao, T. N, Reedijk, J, van Rijn, J, Verschoor, G. C. J. Chem. Soc, Dalton Trans. 1984, 1349-1356
    • 5 values for ideally square pyramidal five-coordinate complexes are equal to zero: (a) Addison, A. W.; Rao, T. N.; Reedijk, J.; van Rijn, J.; Verschoor, G. C. J. Chem. Soc., Dalton Trans. 1984, 1349-1356.
  • 42
    • 0000967173 scopus 로고    scopus 로고
    • 2(mnt)] (mnt = maleonitrile-2,3-dithiolate): Wang, Q.-H.; Long, D.-L.; Hu, H.-M; Cui, Y.; Huang, J.-S. J Coord. Chem. 2000, 49, 201-209. As steric effects most likely do not play a role in this case, the electronic structure of this particular dithiolene ligand seems to control the nuclearity of the complex (Note: both thiolate-sulfurs are comparatively electron-poor because of the nitrile substituents in close proximity which might disfavor a μ-S-coordination mode).
    • 2(mnt)] (mnt = maleonitrile-2,3-dithiolate): Wang, Q.-H.; Long, D.-L.; Hu, H.-M; Cui, Y.; Huang, J.-S. J Coord. Chem. 2000, 49, 201-209. As steric effects most likely do not play a role in this case, the electronic structure of this particular dithiolene ligand seems to control the nuclearity of the complex (Note: both thiolate-sulfurs are comparatively electron-poor because of the nitrile substituents in close proximity which might disfavor a μ-S-coordination mode).
  • 46
    • 84977289976 scopus 로고    scopus 로고
    • A crystallographically characterized tert-butyl substituted derivative of 2,2′- methylenedibenzenethiolate was previously reported (without explicit experimental procedure); estimation of the molecular for the unsubstituted analogue, however, is difficult from that crystal data because of the sterically demanding tert-butyl groups: Hiller, W.; Rundel, W. Acta Crystallogr. 1993, C49. 1127-1128.
    • A crystallographically characterized tert-butyl substituted derivative of 2,2′- methylenedibenzenethiolate was previously reported (without explicit experimental procedure); estimation of the molecular volume for the unsubstituted analogue, however, is difficult from that crystal data because of the sterically demanding tert-butyl groups: Hiller, W.; Rundel, W. Acta Crystallogr. 1993, C49. 1127-1128.
  • 47
    • 0038209783 scopus 로고    scopus 로고
    • Compare: Gualtieri, G.; Geib, S. J.; Curran, D. P. J. Org. Chem. 2003, 68, 5013-5019.
    • Compare: Gualtieri, G.; Geib, S. J.; Curran, D. P. J. Org. Chem. 2003, 68, 5013-5019.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.