Experimental and theoretical analysis of asymmetric induction in heterogeneous catalysis: Diastereoselective hydrogenation of chiral a-hydroxyketones over Pt catalyst

Journal of the American Chemical Society

Volumn 131, Issue 12, 2009, Pages 4449-4462

  Busygin, Igor ^a,d   Taskinen, Antti ^b   Nieminen, Ville ^b   Toukoniitty, Esa ^b   Stillger, Thomas ^c   Leino, Reko ^a   Murzin, Dmitry Yu ^b  

^a ÅBO AKADEMI UNIVERSITY   (Finland)

^b LABORATORY OF INDUSTRIAL CHEMISTRY AND REACTION ENGINEERING   (Finland)

^c UNIVERSITY OF FREIBURG   (Germany)

^d RWTH Aachen University   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONE; ADSORPTION; CATALYSIS; CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; HYDROGEN; PLATINUM; PROBABILITY DENSITY FUNCTION; STEREOSELECTIVITY; SULFUR COMPOUNDS; TOLUENE;

2-BUTANONE; ADSORPTION MODES; ASYMMETRIC INDUCTION; CHIRAL COMPOUNDS; CLUSTER MODELS; COMPLEX ORGANIC MOLECULES; CYCLOHEXANONE; DFT CALCULATION; DIASTEREOMERIC; DIASTEREOSELECTIVE HYDROGENATION; DOUBLE BONDS; HETEROGENEOUS CATALYSIS; HYDROGEN ADDITION; POTENTIAL ENERGY PROFILES; PROPANEDIOL; PROPANONE; PT CATALYSTS; PT(111); PT-CATALYZED; REACTION MECHANISM; REACTION PATHS;

HYDROGENATION;

(1,2) 1 PHENYL 1,2 PROPANEDIOL; 1 HYDROXY 1 PHENYL 2 PROPANONE; 2 HYDROXY 1 CYCLOHEXANONE; ACETOIN; ACETONE; ALPHA HYDROXY KETONE DERIVATIVE; CARBON; CYCLOHEXANONE DERIVATIVE; HYDROGEN; KETOL; OXYGEN; PROPANEDIOL DERIVATIVE; UNCLASSIFIED DRUG; 1-PHENYL-1,2-PROPANEDIONE; CHALCONE DERIVATIVE; KETONE; PLATINUM;

ADSORPTION KINETICS; ARTICLE; ASYMMETRIC CATALYSIS; CALCULATION; CATALYST; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CHIRALITY; CYCLOADDITION; DENSITY FUNCTIONAL THEORY; DIASTEREOISOMER; ELECTRIC POTENTIAL; ENERGY ABSORPTION; EXPERIMENTAL DESIGN; HYDROGENATION; STEREOCHEMISTRY; THEORETICAL MODEL; THERMODYNAMICS; ADSORPTION; CATALYSIS; CHEMISTRY; CONFORMATION; KINETICS; ORGANIC CHEMISTRY; PROCEDURES; STEREOISOMERISM;

ADSORPTION; CATALYSIS; CHALCONES; CHEMISTRY, ORGANIC; HYDROGEN; HYDROGENATION; KETONES; KINETICS; MOLECULAR CONFORMATION; PLATINUM; STEREOISOMERISM; THERMODYNAMICS;

EID: 67849114704     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja809070g     Document Type: Article

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