Rapid three-step cleavage of RNA and DNA model systems promoted by a dinuclear Cu(II) complex in methanol. Energetic origins of the catalytic efficacy

Journal of the American Chemical Society

Volumn 129, Issue 37, 2007, Pages 11642-11652

  Lu, Zhong Lin ^a,b   Liu, C Tony ^a   Neverov, Alexei A ^a   Brown, R Stan ^a  

^a QUEEN S UNIVERSITY   (Canada)

^b BEIJING NORMAL UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC EFFICACY; ENERGETIC ORIGINS; METHOXIDES;

BIOLOGICAL SYSTEMS; CATALYST ACTIVITY; COPPER COMPOUNDS; DNA; METAL COMPLEXES; PROPANE; REACTION KINETICS;

RNA;

1,3 BIS N1 (1,5,9 TRIAZACYCLODODECYL)PROPANE; 2 HYDROXYPROPYL 4 NITROPHENYL PHOSPHATE; 4 CHLOROPHENOL; COPPER COMPLEX; DNA; ISOBUTYL 4 CHLOROPHENYL PHOSPHATE; METHANOL; NITROPHENOL; PROPANE; RNA; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CRYSTAL STRUCTURE; DNA CLEAVAGE; DNA DETERMINATION; ENERGY; ENERGY TRANSFER; MICHAELIS MENTEN KINETICS; RNA ANALYSIS; RNA CLEAVAGE; X RAY DIFFRACTION;

CATALYSIS; COPPER; CRYSTALLOGRAPHY, X-RAY; DNA; ELECTRON SPIN RESONANCE SPECTROSCOPY; KINETICS; METHANOL; MODELS, CHEMICAL; MODELS, MOLECULAR; ORGANOMETALLIC COMPOUNDS; RNA; X-RAY DIFFRACTION;

EID: 35048884731     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja073780l     Document Type: Article

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