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Crystal data of compound 6b: C24H23 N 3O6 (from methanol, M, 449.45, Orthorhombic, Pna2 (1, a, 18.34(3, b, 9.076 (214.746(2, c, 8.374(1) Å, V, 2264.7(6) Å3, Z, 4, D c, 1.318 g cm-3, μ (Mo-Kα, 0.096 mm-1, F (000, 944, colorless block, dimension 0.275 mm x 0.25 mm x 0.15 mm, 2804 reflections measured (Rint, 0.0234, 2436 unique, wR2, 0.1112, conventional R, 0.0517 on F values of 1235 reflections with I > 2σ(I, Δ/σ)max, 000, S, 0.999 for all data and 184 parameters. Unit cell determination and intensity data collection (2θ, 50°) was performed on a Bruker P4 diffractometer at 293 (2) K. Structure solutions by direct methods and refinements by full-matrix least-squares
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2. Programs: XSCANS (Siemens Analytical X-ray Instrument: Madison, WI, USA, 1996) for data collection and data processing; SHELXTL-NT (Bruker AXS: Madison, Wisconsin, USA, 1997) for structure determination, refinements and molecular graphics. Further details of the crystal structure investigation can be obtained from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge, CB2 1EZ, UK (CCDC deposition no.: 715052). This is CDRI communication no. 7689.
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