Carbon-rich SiCN ceramics derived from phenyl-containing poly(silylcarbodiimides)

Journal of the European Ceramic Society

Volumn 29, Issue 13, 2009, Pages 2873-2883

  Mera, Gabriela ^a   Riedel, Ralf ^a   Poli, Fabrizia ^b   Müller, Klaus ^b,c,d  

^a DARMSTADT UNIVERSITY OF TECHNOLOGY   (Germany)

^b UNIVERSITY OF STUTTGART   (Germany)

^c UNIVERSITY OF TRENTO   (Italy)

^d INSTM   (Italy)

Author keywords

C rich SiCN ceramics; Carbon; Precursors organic; Spectroscopy; Thermal properties

Indexed keywords

C-RICH SICN CERAMICS; CARBON CONTENT; CARBON RICH; CRYSTALLIZATION BEHAVIOR; DICHLOROSILANES; HIGHEST TEMPERATURE; MATRIX; ORGANIC SUBSTITUENTS; PRECERAMIC POLYMER; PRECURSORS-ORGANIC; STRUCTURAL FEATURE; TEMPERATURE OF CRYSTALLIZATION; THERMAL PROPERTIES; THERMAL STABILITY;

CERAMIC MATERIALS; CRYSTALLIZATION; SILANES; SILICON CARBIDE; THERMODYNAMIC PROPERTIES; THERMOLYSIS;

AMORPHOUS CARBON;

EID: 67449110715     PISSN: 09552219     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jeurceramsoc.2009.03.026     Document Type: Article

References (45)

1. Riedel R., Mera G., Hauser R., and Klonczynski A. Silicon-based polymer-derived ceramics: synthesis properties and applications-a review. J. Ceram. Soc. Jpn. 114 6 (2006) 425-444
2. Mera, G. and Riedel, R., Organosilicon-based polymers as precursors for ceramics. In Polymer Derived Ceramics, DEStech Publications, Inc., Lancaster, PA, USA, 2009, pp. 50-88, in press.
3. Kleebe H.-J., Blum Y.D., and MacQueen D.B. SiOC ceramic with high excess free carbon. J. Eur. Ceram. Soc. 28 5 (2008) 1037-1042
4. Kleebe H.-J., Gregori G., Babonneau F., Blum Y.D., MacQueen D.B., and Masse S. Evolution of C-rich SiOC ceramics-part I. Characterization by integral spectroscopic techniques: solid-state NMR and Raman spectroscopy. Int. J. Mater. Res. 97 6 (2006) 699-709
5. Gregori G., Kleebe H.-J., Blum Y.D., and Babonneau F. Evolution of C-rich SiOC ceramics-part II. Characterization by high lateral resolution techniques: electron energy-loss spectroscopy, high-resolution TEM and energy-filtered TEM. Int. J. Mater. Res. 97 6 (2006) 710-720
6. Saha A., Raj R., Williamson D.L., and Kleebe H.-J. Characterization of nanodomains in polymer-derived SiCN ceramics employing multiple techniques. J. Am. Ceram. Soc. 88 1 (2005) 232-234
7. Störmer H., Kleebe H.-J., and Ziegler G. Metastable SiCN glass matrices studied by energy-filtered electron diffraction pattern analysis. J. Non-Cryst. Solids 353 (2007) 2867-2877
8. Hörz M., Zern A., Berger F., Haug J., Müller K., Aldinger F., and Weinmann M. Novel polysilazanes as precursors for silicon nitride/silicon carbide composites without "free" carbon. J. Eur. Ceram. Soc. 25 (2005) 99-110
9. Hurwitz F.I., Heimann P., Farmer S.C., and Hembree Jr. D.M. Characterization of the pyrolytic conversion of polysilsesquioxanes to silicon oxycarbides. J. Mater. Sci. 28 (1993) 6622-6630
10. Hurwitz F.I., Heimann P.J., and Kacik T.A. Redistribution reactions in Blackglas™ during pyrolysis and their effect on oxidative stability. Ceram. Eng. Sci. Proc. 16 (1995) 217
11. Turquat C., Kleebe H.-J., Gregori G., Walter S., and Soraru G.D. TEM and EELS study of non-stoichiometric SiCO glasses. J. Am. Ceram. Soc. 84 (2001) 2189-2196
12. Raj R., Riedel R., and Soraru G.D. Introduction to the special topical issue on ultrahigh-temperature polymer-derived ceramics. J. Am. Ceram. Soc. 84 10 (2001) 2158-2159
13. Riedel R., Kroke E., Greiner A., Gabriel A.O., Ruwisch L., and Nicolich J. Inorganic solid state chemistry with main group element carbodiimides. J. Chem. Mater. 10 (1998) 2964-2979
14. Iwamoto Y., Völger W., Kroke E., and Riedel R. Crystallization behavior of amorphous Si-C-N ceramics derived from organometallic precursors. J. Am. Ceram. Soc. 84 10 (2001) 2170-2178
15. Klebe, J. F. and Murray, J. G., Organosiliconcarbodiimide polymers and process for their preparation. US Patent 3352799, 14 November 1967.
16. Kumar P., and Shankar R. Thermal studies on oligosilylbiguanides: a mechanistic approach. Silicon Chem. 1 (2002) 233-237
17. Vostokov I.A., Dergunov Y.I., and Gordetsov A.S. Reaction of organosilicon, organogermanium, and organotin compounds with dicyanodiamide. New method for obtaining organoelemental carbodiimides. Zh. Obshch. Khim. 47 8 (1977) 1769-1771
18. Shriver D.F., and Drezdzon M.A. The Manipulation of Air-sensitive Compounds. 2nd ed. (1986), Wiley, New York
19. Metz G., Xiaoling W., and Smith S.O. Ramped-amplitude cross polarization in magic-angle-spinning NMR. J. Magn. Res. Ser. A 110 (1994) 219-227
20. Schuhmacher J., Weinmann M., Bill J., Aldinger F., and Müller K. Solid state NMR studies of the preparation of Si-C-N ceramics from polysilylcarbodiimide polymers. Chem. Mater. 10 (1998) 3913-3922
21. Schädler H.-D., Jäger L., and Senf I. Pseudoelementverbindungen V. Pseudochalkogene-versuch der empirischen und theoretischen Charakterisierung. Z. Anorg. Allg. Chem. 619 (1993) 1115-1120
22. Gädda T.M., and Weber W.P. Polydiphenylsiloxane-polydimethylsiloxane-polydiphenylsiloxane triblock copolymers. J. Polym. Sci. Part A: Polym. Chem. 44 11 (2006) 3629-3639
23. Marsmann H. 29Si-NMR Spectroscopic Results, NMR (1981), Springer, Grundlagen und Fortschritte
24. Gabriel A.O., Riedel R., Dressler W., Reichert S., Gervais C., Maquet J., and Babonneau F. Thermal decomposition of poly(methylsilsesquicarbodiimide) to amorphous Si-C-N Ceramics. Chem. Mater. 11 (1999) 412-420
25. Riedel R., Greiner A., Miehe G., Dressler W., Fuess H., Bill J., and Aldinger F. The first crystalline solids in the ternary Si-C-N system. Angew. Chem., Int. Ed. Engl. 36 (1997) 603-606
26. Berger F., Weinmann M., Aldinger F., and Müller K. Solid-state NMR studies of the preparation of Si-Al-C-N ceramics from aluminum-modified polysilazanes and polysilylcarbodiimides. Chem. Mater. 16 (2004) 919-929
27. Schuhmacher J., Berger F., Weinmann M., Bill J., Aldinger F., Müller K., and Solid-state N.M.R. FT-IR studies of the preparation of Si-B-C-N ceramics from boron-modified polysilazanes. Appl. Organomet. Chem. 15 (2001) 809-819
28. Soraru G.D., Babonneau F., and Mackenzie J.D. Structural evolutions from polycarbosilane to SiC ceramic. J. Mater. Sci. 9 (1990) 3886-3893
29. Bois L., Maquet J., Babonneau F., Mutin P.H., and Bahloul D. Structural characterization of sol-gel derived oxycarbide glasses. 1. Study of the pyrolysis process. Chem. Mater. 6 (1994) 796-802
30. Gerardin C., Tauelelle F., and Bahloul D. Pyrolysis chemistry of polysilazane precursors to silicon carbonitride. J. Mater. Chem. 7 (1997) 117-126
31. Lewis R.H., and Maciel G.E. Magnetic resonance characterization of solid-state intermediates in the generation of ceramics by pyrolysis of hydridopolysilazane. J. Mater. Sci. 30 (1995) 5020-5030
32. Gervais C., Babonneau F., Ruwisch L., Hauser R., and Riedel R. Solid-state NMR investigations of the polymer route to SiBCN ceramics. Can. J. Chem. 81 (2003) 1359-1369
33. Sehlleier Y.H., Verhoeven A., and Jansen M. NMR studies of short and intermediate range ordering of amorphous Si-B-N-C-H pre-ceramic at the pyrolysis stage of 600 °C. J. Mater. Chem. 17 (2007) 4316-4319
34. 13C nuclear magnetic resonance spectroscopy. Phys. Rev. B 66 (2002) 153402-1-153402-4
35. Socrates G. Infrared and Raman Characteristic Group Frequencies: Tables and Charts (2004), Wiley & Sons Auflage 0003
36. Kaufman J.H., Metin S., and Saperstein D.D. Symmetry breaking in nitrogen-doped amorphous carbon: infrared observation of the Raman-active G and D bands. Phys. Rev. B: Condens. Matter 39 18 (1989) 13053-13060
37. Bouchet-Fabre B., Marino E., Lazar G., Zellam K., Clin M., Ballutaud D., Abel F., and Godet C. Spectroscopic study using FTIR, Raman, XPS and NEXAFS of carbon nitride thin films deposited by RF magnetron sputtering. Thin Solid Films 482 (2005) 167-171
38. Gabriel A.O., Riedel R., Storck S., Maier W.F., and Synthesis. Thermally induced ceramisation of a polymethylsilsesquicarbodiimide-gel. Appl. Organomet. Chem. 11 (1997) 833-841
39. Kim D.S., Kroke E., Riedel R., Gabriel A.O., and Shim S.C. An anhydrous sol-gel system derived from methyldichlorosilane. Appl. Organomet. Chem. 13 (1999) 495-499
40. Riedel R., and Gabriel A.O. Synthesis of polycrystalline silicon carbide by a liquid phase process. Adv. Mater. 11 3 (1999) 207-209
41. Ferrari A.C., and Robertson J. Interpretation of Raman spectra of disordered and amorphous carbon. Phys. Rev. B 61 (2000) 14095-14107
42. Ferrari A.C., Meyer J.C., Scardaci V., Casiraghi C., Lazzeri M., Mauri F., Piscanec S., Jiang D., Novoselov K.S., Roth S., and Geim A.K. Raman spectrum of graphene and graphene layers. Phys. Chem. Lett. 97 (2006) 187401-1-187401-4
43. Pimenta M.A., Dresselhaus G., Dresselhaus M.S., Cançado L.G., Jorio A., and Saito R. Studying disorder in graphite-based systems by Raman spectroscopy. Phys. Chem. Chem. Phys. 9 (2007) 1276-1290
44. Ferrari A.C. Raman spectroscopy of graphene and graphite: disorder, electron-phonon coupling, doping and nonadiabatic effects. Solid State Commun. 143 (2007) 47-57
45. Cançado L.G., Takai K., Enold E., Endo M., Kim Y.A., Mizusaki H., Jorio A., Coelho L.N., Magalhaes-Paniago R., and Pimenta M.A. General equation for the determination of the crystallite size La of nanographite by Raman spectroscopy. Appl. Phys. Lett. 88 (2006) 163106-1-163106-3