Self assembled monolayer (SAM) of metallomacrocycle as a synthetic cathode catalyst for a hybrid bio-fuel-cell

ECS Transactions

Volumn 13, Issue 21, 2008, Pages 51-66

  Gervasio, D ^a   Thomson, J ^a  

^a ARIZONA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIOFUELS; BIOLOGICAL FUEL CELLS; CATHODES; COBALT COMPOUNDS; ELECTROLYTIC REDUCTION; ENZYME ELECTRODES; METALS; OXYGEN; SELF ASSEMBLED MONOLAYERS; SYNTHETIC FUELS; TIN OXIDES;

CATHODE CATALYST; COBALT PORPHYRINS; ENZYME CATALYSTS; INDIUM TIN OXIDE ELECTRODES; METALLOMACROCYCLES; OXYGEN ELECTRO REDUCTIONS; OXYGEN REDUCTION CATALYSTS; PHOSPHONATE GROUP;

CATALYST SELECTIVITY;

EID: 65849124138     PISSN: 19385862     EISSN: 19386737     Source Type: Conference Proceeding    
DOI: 10.1149/1.3036211     Document Type: Conference Paper

References (37)

1. th Edition (2002).
2. Appleby, A. J.; Ng, D. Y. C.; Weinstein, H. J, Appl, Electrochem. 1971,1, 79-90.
3. a. J. Zagal, P. Bindra, E. Yeager, J, Electrochem. Soc., 127, 1506 (1980);
4. b. J. Zagal, M. P'aez, A. A. Tanaka, J. R. Dos Santos, Jr., C. A. Linkous. J. Electroanal. Chem, 339,13 (1992);
5. c. M. P. Somashekarappa, J. Keshavayya, S. Sampath, "Self assembled films of tetra amino metal phthalocyanines", Pure Appl. Chem., Vol.74, No. 9, 1609 (2002);
6. 2+ Centers are Coordinated," B. Steiger, C. Shi and F. C. Anson, Inorg. Chem., 32, 2107 (1993);
7. e. "New Electrocatalysts for the FourElectron Reduction of Dioxygen Based on (5,10,15-Tris (penta ammine ruthenium (II) -4-cyanophenyl)-20-(l- methylpyridinium-4-yl) porphyrinato) cobalt(II) Immobilized on Graphite Electrodes," B. Steiger and F. C. Anson, Inorg. Chem., 33, 5767 (1994);
8. f. "Evidence of the Importance of Back-Bonding in Determining the Behavior of Ruthenated Cyanophenyl Cobalt Porphyrins as Electrocatalysts for the Reduction of Dioxygen," B. Steiger and F. C. Anson, Inorg. Chem., 34, 3355 (1995);
9. g. "Novel Multinuclear Catalysts for the Electroreduction of Dioxygen Directly to Water," F. C. Anson, C. Shi and B. Steiger, Accts. Chem. Research, 30, 437 (1997);
10. 2O but the Corresponding 2,6-dimethyl-4-cyanophenyl Derivative Catalyzes the Reduction only to H202", B. Steiger and F. C. Anson, Inorg. Chem., 36, 4138 (1997);
11. 2O", C. Shi and F. C. Anson, Inorg. Chem., 37, 1037 (1998);
12. j. "Functional Analogues of Cytochrome c Oxidase, Myoglobin, and Hemoglobin," J. P. Coliman, R. Boulatov, C. J. Sunderland, and L. Fu, Chem. Rev., 104, 561-588, (2004);
13. 2 Reduction by Synthetic Monometallic Fe Porphyrins," J. P. Coliman, 1. M. Shiryaeva, and R. Boulatov, Inorg. Chem., 42, 4807-4809, (2003);
14. B," R. Boulatov, J. P. Coliman, I. M. Shiryaeva, and C. J. Sunderland, J. Amer. Chem. Soc., 124, 11923-11935, (2002);
15. m. "Electrocatalytic Dioxygen Reduction by Synthetic Analogues of the Heme/Cu Site of Cytochrome Oxidase Incorporated in a Lipid Film," J. P. Coliman and R. Boulatov, Angew. Chem. Int. Ed., 41, 3487-3489, (2002);
16. n. "Biomimetic Studies of Terminal Oxidases: Trisimidazole Picket Metalloporphyrins," J. P. Coliman, C. J. Sunderland, and R. Boulatov, Inorg. Chem., 41, 2282-2291, (2002).
17. a. "Electrocatalytic four electron reduction of oxygen to water by a highly flexible cofacial cobalt bisporphyrin", Christopher J. Chang, Yongqi Deng, Chunnian Shi, C. K. Chang, Fred C. Anson and Daniel G. Nocera, Chem. Commun., 2000, 1355-1356;
18. b. "Electrocatalytic activity of an immobilized cofacial porphyrin depends on the electrode material", Hutchison, J. E.; Postlethwaite, T. A.; Chen, Ch.; Hathcock, K. W.; Ingram, R. S.; Ou, W.; Linton, R. W.; Murray, R. W.; Tyvoll, D. A.; Chng, L. L.; Coliman, J. P., Langmuir, 13, 2143-2148 (1997);
19. c. Coliman, J. P.; Wagenknecht, P. S.; Hutchison, J. E. Angew. Chem., Int. Ed. Engl. 1994, 33, 1537-1554;
20. d. Coliman, J. P.; Wagenknecht, P. S.; Hutchison, J. E., Angew. Chem., 106, 1620-39 (1994);
21. e. Durand, R. R., Jr.; Coliman, J. P.; Anson, F. C; "Dissolution of insoluble dicobalt cofacial porphyrins in concentrated acids to produce increased stability in their catalysis of the reduction of dioxygen", J. Electroanal. Chem., 151, 289-94 (1983).
22. Pourbaix, M., Atlas of Electrochemical Equilibria in Aqueous Solutions, 2nd edition, 1974.
23. "Systems for Orthogonal Self Assembly of Electroactive Monolayers on Au and ITO: An Approach to Molecular Electronics", T. Gardner, C.D. Frisbie, M. Wrighton, J. Am. Chem. Soc., 117, 6927 (1995).
24. a. "Evolution of Nanoporosity in Dealloying", J.Erlebacher, M.Aziz, N.Dimitrov, K.Sieradzki, Nature, 410, 450 (2001);
25. b. Y.Ding, M.Chen, J.Erlebacher, "Metallic Mesoporous Nanocomposites for Electrocatalysis", J. Am. Chem. Soc., 126, 6876 (2004).
26. "A simplified synthesis for meso-tetraphenylporphine", Adler, A. D.; Longo, F. R.; Finarelli, J. D.; Goldmacher, J.; Assour, J.; Korsakoff, L., J. Org. Chem., 1967, 32, 476.
27. 9. "Porphyrins bearing mono or tripodal benzylphosphonic acid tethers for attachment to oxide surface", Loewe, R. S.; Ambroise, A.; Muthukumaran, K.; Padmaja, K.; Lysenko, A. B.; Mathur, G.; Li, Q.; Bocian, D. F,; Misra, V.; Lindsey J. S., J. Org. Chem., 2004, 69, 1453-1460. (Pubitemid 38292093)
28. "Synthesis and catalytic properties of manganese porphyrins incorporated into phosphonate networks", Deniaud, D.; Schollorn, B.; Mansuy, D.; Rouxel, J.; Battioni, P.; Bujoli, B., Chem. Mater. 1995, 7, 995-1000.
29. "Oxygen electro-reduction catalysts self-assembled on supports", Jennifer. Dougan, Raquel Panton, Qiling Cheng, Don F. Gervasio, Proc. SPIE Vol. 5592, p. 220-240(2005).
30. "On the preparation of metalloporphyrins", Adler, A. D.; Longo, F. R.; Kampas, F.; Kim, J. J., Inorg. Nucl. Chem., 1970, Vol.32 2443-2445.
31. "Conductivity in redox modified conducting polymers. 2. Enhanced redox conductivity in ferrocene-substituted polypyrroles and polythiophenes", Zotti, G.; Zecchin, S.; Schiavaon, G., Chem. Mater. 1995, 7, 2309-2315.
32. Lee, E. J., "Energy and Electron Transfer in Some Donor-Chromophore-Acceptor Compounds", Ph.D. Thesis, Massachusetts Institute of Technology, 1993.
33. 15. "Porphyrins bearing mono or tripodal benzylphosphonic acid tethers for attachment to oxide surface", Loewe, R. S.; Ambroise, A.; Muthukumaran, K.; Padmaja, K.; Lysenko, A. B.; Mathur, G.; Li, Q.; Bocian, D. F,; Misra, V.; Lindsey J. S. J. Org. Chem. 2004, 69, 1453-1460. (Pubitemid 38292093)
34. 16. "The modeling of molecular structure and ion transport in sulfonic acid based ionomer membranes", S. J. Paddison, J. New. Mat. Electrochem. Systems, 4, 197207 (2001) (Pubitemid 33687276)
35. "Electron Tunneling in Biological Molecules", J. R. Winkler, A. J. Di Bilio, N. A. Farrow, J. H. Richards, and H. B. Gray, Pure Appl. Chem. 1999, 71, 1753-1764.
36. Swavey, Shawn Michael, "Transition metal complexes with redox-active ligands", Ph.D. Thesis, Case Western Reserve University, Cleveland, Ohio (1998).
37. Fuel Cell Technology Handbook, Section I Chapter 2, "History", Eric Chen, Section 2.6.1, CRC Press (2003).