Oxygen electro-reduction catalysts for self-assembly on supports

Proceedings of SPIE - The International Society for Optical Engineering

Volumn 5592, Issue , 2005, Pages 220-240

  Dougan, Jennifer ^a   Panton, Raquel ^a   Cheng, Qiling ^a   Gervasio, Don ^a  

^a ARIZONA STATE UNIVERSITY   (United States)

Author keywords

Bio mimetic; Biofuel cell; Electrode catalyst; Fuel cell; Oxygen reduction; Self assembled monolayer; Sensor

Indexed keywords

BIO MIMETIC; BIOFUEL-CELL; ELECTRODE CATALYST; OXYGEN REDUCTION; SELF-ASSEMBLED MONOLAYERS;

ELECTROCHEMICAL SENSORS; ELECTRODES; FUEL CELLS; MONOLAYERS; SELF ASSEMBLY; SYNTHESIS (CHEMICAL);

CATALYSTS;

EID: 16644395634     PISSN: 0277786X     EISSN: None     Source Type: Conference Proceeding    
DOI: 10.1117/12.571378     Document Type: Conference Paper

References (34)

1. 2 Reduction in Acid Electrolytes. Volumes 1 and 2, D. Gervasio, D. Chu, S. Clouser, M. Enayetullah, E. O'Sullivan, E. Yeager, Copyright Electric Power Research Institute, Inc. (1988). "Elevated Temperature Fuel-cell System for Portable Power Applications" Don Gervasio, S. Rogers, R. Koripella, S. Samms, S. Tasic, D. Zindel, American Institute of Chemical Engineers, Spring Meeting, March 13 (2002). "Elevated Temperature Fuel-cell for Portable Power Applications", D. Gervasio, Proceedings of Electrochem. Soc., Salt Lake City, Utah (2002), in press.
2. 2 Reduction in Acid Electrolytes. Volumes 1 and 2, D. Gervasio, D. Chu, S. Clouser, M. Enayetullah, E. O'Sullivan, E. Yeager, Copyright Electric Power Research Institute, Inc. (1988). "Elevated Temperature Fuel-cell System for Portable Power Applications" Don Gervasio, S. Rogers, R. Koripella, S. Samms, S. Tasic, D. Zindel, American Institute of Chemical Engineers, Spring Meeting, March 13 (2002). "Elevated Temperature Fuel-cell for Portable Power Applications", D. Gervasio, Proceedings of Electrochem. Soc., Salt Lake City, Utah (2002), in press.
3. "Evolution of Nanoporosity in Dealloying", J.Erlebacher, M.Aziz, N.Dimitrov, K.Sieradzki, Nature 410, 450 (2001); "Metallic Mesoporous Nanocomposites for Electrocatalysis", Y.Ding, M.Chen, J.Erlebacher, J. Am. Chem. Soc. 126, 6876 (2004).
4. "Evolution of Nanoporosity in Dealloying", J.Erlebacher, M.Aziz, N.Dimitrov, K.Sieradzki, Nature 410, 450 (2001); "Metallic Mesoporous Nanocomposites for Electrocatalysis", Y.Ding, M.Chen, J.Erlebacher, J. Am. Chem. Soc. 126, 6876 (2004).
5. "Systems for Orthogonal Self-Assembly of Electroactive Monolayers on Au and ITO: An Approach to Molecular Electronics", T. Gardner, C.D. Frisbie, M. Wrighton, J. Am. Chem. Soc., 117, 6927 (1995).
6. "Harry Gray Wins Wolf Prize In Chemistry", Mitch Jacoby, Chemical and Engineering News, Vol. 82, No. 4, p. 12 January 26, 2004, and "Electron Tunneling in Biological Molecules", J. R. Winkler, A. J. Di Bilio, N. A. Farrow, J. H. Richards, and H. B. Gray, Pure Appl. Chem. 1999, 71, 1753-1764.
7. "Harry Gray Wins Wolf Prize In Chemistry", Mitch Jacoby, Chemical and Engineering News, Vol. 82, No. 4, p. 12 January 26, 2004, and "Electron Tunneling in Biological Molecules", J. R. Winkler, A. J. Di Bilio, N. A. Farrow, J. H. Richards, and H. B. Gray, Pure Appl. Chem. 1999, 71, 1753-1764.
8. "Electrocatalytic four-electron reduction of oxygen to water by a highly flexible cofacial cobalt bisporphyrin", Christopher J. Chang, Yongqi Deng, Chunnian Shi, C. K. Chang, Fred C. Anson and Daniel G. Nocera, Chem. Commun., 2000, 1355-1356; "Electrocatalytic activity of an immobilized cofacial porphyrin depends on the electrode material", Hutchison, J. E.; Postlethwaite, T. A.; Chen, C.-h.; Hathcock, K. W.; Ingram, R. S.; Ou, W.; Linton, R. W.; Murray, R. W.; Tyvoll, D. A.; Chng, L. L.; Collman, J. P., Langmuir 1997, 13, 2143-2148; Collman, J. P.; Wagenknecht, P. S.; Hutchison, J. E. Angew. Chem., Int. Ed. Engl. 1994, 33, 1537-1554; Collman, J. P.; Wagenknecht, P. S.; Hutchison, J. E., Angew. Chem. 1994, 106, 1620-39; "Dissolution of insoluble dicobalt cofacial porphyrins in concentrated acids to produce increased stability in their catalysis of the reduction of dioxygen", Durand, R. R., Jr.; Collman, J. P.; Anson, F. C.; J. Electroanal. Chem. 1983, 151, 289-94; J. Zagal, P. Bindra, E. Yeager, J. Electrochem. Soc. 127, 1506 (1980); J. Zagal, M. P'aez, A. A. Tanaka, J. R. Dos Santos, Jr., C. A. Linkous. J. Electroanal. Chem. 339,13 (1992); "Self-assembled films of tetraamino metal phthalocyanines", M. P. Somashekarappa, J. Keshavayya, S. Sampath, Pure Appl. Chem., Vol. 74, No. 9, 1609 (2002).
9. "Electrocatalytic four-electron reduction of oxygen to water by a highly flexible cofacial cobalt bisporphyrin", Christopher J. Chang, Yongqi Deng, Chunnian Shi, C. K. Chang, Fred C. Anson and Daniel G. Nocera, Chem. Commun., 2000, 1355-1356; "Electrocatalytic activity of an immobilized cofacial porphyrin depends on the electrode material", Hutchison, J. E.; Postlethwaite, T. A.; Chen, C.-h.; Hathcock, K. W.; Ingram, R. S.; Ou, W.; Linton, R. W.; Murray, R. W.; Tyvoll, D. A.; Chng, L. L.; Collman, J. P., Langmuir 1997, 13, 2143-2148; Collman, J. P.; Wagenknecht, P. S.; Hutchison, J. E. Angew. Chem., Int. Ed. Engl. 1994, 33, 1537-1554; Collman, J. P.; Wagenknecht, P. S.; Hutchison, J. E., Angew. Chem. 1994, 106, 1620-39; "Dissolution of insoluble dicobalt cofacial porphyrins in concentrated acids to produce increased stability in their catalysis of the reduction of dioxygen", Durand, R. R., Jr.; Collman, J. P.; Anson, F. C.; J. Electroanal. Chem. 1983, 151, 289-94; J. Zagal, P. Bindra, E. Yeager, J. Electrochem. Soc. 127, 1506 (1980); J. Zagal, M. P'aez, A. A. Tanaka, J. R. Dos Santos, Jr., C. A. Linkous. J. Electroanal. Chem. 339,13 (1992); "Self-assembled films of tetraamino metal phthalocyanines", M. P. Somashekarappa, J. Keshavayya, S. Sampath, Pure Appl. Chem., Vol. 74, No. 9, 1609 (2002).
10. "Electrocatalytic four-electron reduction of oxygen to water by a highly flexible cofacial cobalt bisporphyrin", Christopher J. Chang, Yongqi Deng, Chunnian Shi, C. K. Chang, Fred C. Anson and Daniel G. Nocera, Chem. Commun., 2000, 1355-1356; "Electrocatalytic activity of an immobilized cofacial porphyrin depends on the electrode material", Hutchison, J. E.; Postlethwaite, T. A.; Chen, C.-h.; Hathcock, K. W.; Ingram, R. S.; Ou, W.; Linton, R. W.; Murray, R. W.; Tyvoll, D. A.; Chng, L. L.; Collman, J. P., Langmuir 1997, 13, 2143-2148; Collman, J. P.; Wagenknecht, P. S.; Hutchison, J. E. Angew. Chem., Int. Ed. Engl. 1994, 33, 1537-1554; Collman, J. P.; Wagenknecht, P. S.; Hutchison, J. E., Angew. Chem. 1994, 106, 1620-39; "Dissolution of insoluble dicobalt cofacial porphyrins in concentrated acids to produce increased stability in their catalysis of the reduction of dioxygen", Durand, R. R., Jr.; Collman, J. P.; Anson, F. C.; J. Electroanal. Chem. 1983, 151, 289-94; J. Zagal, P. Bindra, E. Yeager, J. Electrochem. Soc. 127, 1506 (1980); J. Zagal, M. P'aez, A. A. Tanaka, J. R. Dos Santos, Jr., C. A. Linkous. J. Electroanal. Chem. 339,13 (1992); "Self-assembled films of tetraamino metal phthalocyanines", M. P. Somashekarappa, J. Keshavayya, S. Sampath, Pure Appl. Chem., Vol. 74, No. 9, 1609 (2002).
11. "Electrocatalytic four-electron reduction of oxygen to water by a highly flexible cofacial cobalt bisporphyrin", Christopher J. Chang, Yongqi Deng, Chunnian Shi, C. K. Chang, Fred C. Anson and Daniel G. Nocera, Chem. Commun., 2000, 1355-1356; "Electrocatalytic activity of an immobilized cofacial porphyrin depends on the electrode material", Hutchison, J. E.; Postlethwaite, T. A.; Chen, C.-h.; Hathcock, K. W.; Ingram, R. S.; Ou, W.; Linton, R. W.; Murray, R. W.; Tyvoll, D. A.; Chng, L. L.; Collman, J. P., Langmuir 1997, 13, 2143-2148; Collman, J. P.; Wagenknecht, P. S.; Hutchison, J. E. Angew. Chem., Int. Ed. Engl. 1994, 33, 1537-1554; Collman, J. P.; Wagenknecht, P. S.; Hutchison, J. E., Angew. Chem. 1994, 106, 1620-39; "Dissolution of insoluble dicobalt cofacial porphyrins in concentrated acids to produce increased stability in their catalysis of the reduction of dioxygen", Durand, R. R., Jr.; Collman, J. P.; Anson, F. C.; J. Electroanal. Chem. 1983, 151, 289-94; J. Zagal, P. Bindra, E. Yeager, J. Electrochem. Soc. 127, 1506 (1980); J. Zagal, M. P'aez, A. A. Tanaka, J. R. Dos Santos, Jr., C. A. Linkous. J. Electroanal. Chem. 339,13 (1992); "Self-assembled films of tetraamino metal phthalocyanines", M. P. Somashekarappa, J. Keshavayya, S. Sampath, Pure Appl. Chem., Vol. 74, No. 9, 1609 (2002).
12. "Electrocatalytic four-electron reduction of oxygen to water by a highly flexible cofacial cobalt bisporphyrin", Christopher J. Chang, Yongqi Deng, Chunnian Shi, C. K. Chang, Fred C. Anson and Daniel G. Nocera, Chem. Commun., 2000, 1355-1356; "Electrocatalytic activity of an immobilized cofacial porphyrin depends on the electrode material", Hutchison, J. E.; Postlethwaite, T. A.; Chen, C.-h.; Hathcock, K. W.; Ingram, R. S.; Ou, W.; Linton, R. W.; Murray, R. W.; Tyvoll, D. A.; Chng, L. L.; Collman, J. P., Langmuir 1997, 13, 2143-2148; Collman, J. P.; Wagenknecht, P. S.; Hutchison, J. E. Angew. Chem., Int. Ed. Engl. 1994, 33, 1537-1554; Collman, J. P.; Wagenknecht, P. S.; Hutchison, J. E., Angew. Chem. 1994, 106, 1620-39; "Dissolution of insoluble dicobalt cofacial porphyrins in concentrated acids to produce increased stability in their catalysis of the reduction of dioxygen", Durand, R. R., Jr.; Collman, J. P.; Anson, F. C.; J. Electroanal. Chem. 1983, 151, 289-94; J. Zagal, P. Bindra, E. Yeager, J. Electrochem. Soc. 127, 1506 (1980); J. Zagal, M. P'aez, A. A. Tanaka, J. R. Dos Santos, Jr., C. A. Linkous. J. Electroanal. Chem. 339,13 (1992); "Self-assembled films of tetraamino metal phthalocyanines", M. P. Somashekarappa, J. Keshavayya, S. Sampath, Pure Appl. Chem., Vol. 74, No. 9, 1609 (2002).
13. "Electrocatalytic four-electron reduction of oxygen to water by a highly flexible cofacial cobalt bisporphyrin", Christopher J. Chang, Yongqi Deng, Chunnian Shi, C. K. Chang, Fred C. Anson and Daniel G. Nocera, Chem. Commun., 2000, 1355-1356; "Electrocatalytic activity of an immobilized cofacial porphyrin depends on the electrode material", Hutchison, J. E.; Postlethwaite, T. A.; Chen, C.-h.; Hathcock, K. W.; Ingram, R. S.; Ou, W.; Linton, R. W.; Murray, R. W.; Tyvoll, D. A.; Chng, L. L.; Collman, J. P., Langmuir 1997, 13, 2143-2148; Collman, J. P.; Wagenknecht, P. S.; Hutchison, J. E. Angew. Chem., Int. Ed. Engl. 1994, 33, 1537-1554; Collman, J. P.; Wagenknecht, P. S.; Hutchison, J. E., Angew. Chem. 1994, 106, 1620-39; "Dissolution of insoluble dicobalt cofacial porphyrins in concentrated acids to produce increased stability in their catalysis of the reduction of dioxygen", Durand, R. R., Jr.; Collman, J. P.; Anson, F. C.; J. Electroanal. Chem. 1983, 151, 289-94; J. Zagal, P. Bindra, E. Yeager, J. Electrochem. Soc. 127, 1506 (1980); J. Zagal, M. P'aez, A. A. Tanaka, J. R. Dos Santos, Jr., C. A. Linkous. J. Electroanal. Chem. 339,13 (1992); "Self-assembled films of tetraamino metal phthalocyanines", M. P. Somashekarappa, J. Keshavayya, S. Sampath, Pure Appl. Chem., Vol. 74, No. 9, 1609 (2002).
14. "Electrocatalytic four-electron reduction of oxygen to water by a highly flexible cofacial cobalt bisporphyrin", Christopher J. Chang, Yongqi Deng, Chunnian Shi, C. K. Chang, Fred C. Anson and Daniel G. Nocera, Chem. Commun., 2000, 1355-1356; "Electrocatalytic activity of an immobilized cofacial porphyrin depends on the electrode material", Hutchison, J. E.; Postlethwaite, T. A.; Chen, C.-h.; Hathcock, K. W.; Ingram, R. S.; Ou, W.; Linton, R. W.; Murray, R. W.; Tyvoll, D. A.; Chng, L. L.; Collman, J. P., Langmuir 1997, 13, 2143-2148; Collman, J. P.; Wagenknecht, P. S.; Hutchison, J. E. Angew. Chem., Int. Ed. Engl. 1994, 33, 1537-1554; Collman, J. P.; Wagenknecht, P. S.; Hutchison, J. E., Angew. Chem. 1994, 106, 1620-39; "Dissolution of insoluble dicobalt cofacial porphyrins in concentrated acids to produce increased stability in their catalysis of the reduction of dioxygen", Durand, R. R., Jr.; Collman, J. P.; Anson, F. C.; J. Electroanal. Chem. 1983, 151, 289-94; J. Zagal, P. Bindra, E. Yeager, J. Electrochem. Soc. 127, 1506 (1980); J. Zagal, M. P'aez, A. A. Tanaka, J. R. Dos Santos, Jr., C. A. Linkous. J. Electroanal. Chem. 339,13 (1992); "Self-assembled films of tetraamino metal phthalocyanines", M. P. Somashekarappa, J. Keshavayya, S. Sampath, Pure Appl. Chem., Vol. 74, No. 9, 1609 (2002).
15. "Electrocatalytic four-electron reduction of oxygen to water by a highly flexible cofacial cobalt bisporphyrin", Christopher J. Chang, Yongqi Deng, Chunnian Shi, C. K. Chang, Fred C. Anson and Daniel G. Nocera, Chem. Commun., 2000, 1355-1356; "Electrocatalytic activity of an immobilized cofacial porphyrin depends on the electrode material", Hutchison, J. E.; Postlethwaite, T. A.; Chen, C.-h.; Hathcock, K. W.; Ingram, R. S.; Ou, W.; Linton, R. W.; Murray, R. W.; Tyvoll, D. A.; Chng, L. L.; Collman, J. P., Langmuir 1997, 13, 2143-2148; Collman, J. P.; Wagenknecht, P. S.; Hutchison, J. E. Angew. Chem., Int. Ed. Engl. 1994, 33, 1537-1554; Collman, J. P.; Wagenknecht, P. S.; Hutchison, J. E., Angew. Chem. 1994, 106, 1620-39; "Dissolution of insoluble dicobalt cofacial porphyrins in concentrated acids to produce increased stability in their catalysis of the reduction of dioxygen", Durand, R. R., Jr.; Collman, J. P.; Anson, F. C.; J. Electroanal. Chem. 1983, 151, 289-94; J. Zagal, P. Bindra, E. Yeager, J. Electrochem. Soc. 127, 1506 (1980); J. Zagal, M. P'aez, A. A. Tanaka, J. R. Dos Santos, Jr., C. A. Linkous. J. Electroanal. Chem. 339,13 (1992); "Self-assembled films of tetraamino metal phthalocyanines", M. P. Somashekarappa, J. Keshavayya, S. Sampath, Pure Appl. Chem., Vol. 74, No. 9, 1609 (2002).
16. "New phosphate/phosphonate; a modular approach to functional SAMs", F.Durmaz, S.Zürcher & N.D.Spencer, European Cells and Materials, Vol. 6. Suppl. 1, 2001 (page 55).
17. "Langmuir-Blodgett Film Formation of Polymerisable Amphiphilic Metal Complexes", P.J. Werkman Ph.D. Thesis University of Groningen, The Netherlands, 1998; G. Wegner, Z. Naturforsch., Teil B 1969, 24, 824; G. Wegner, Pure Appl. Chem. 1977, 49, 443.
18. "Langmuir-Blodgett Film Formation of Polymerisable Amphiphilic Metal Complexes", P.J. Werkman Ph.D. Thesis University of Groningen, The Netherlands, 1998; G. Wegner, Z. Naturforsch., Teil B 1969, 24, 824; G. Wegner, Pure Appl. Chem. 1977, 49, 443.
19. "Langmuir-Blodgett Film Formation of Polymerisable Amphiphilic Metal Complexes", P.J. Werkman Ph.D. Thesis University of Groningen, The Netherlands, 1998; G. Wegner, Z. Naturforsch., Teil B 1969, 24, 824; G. Wegner, Pure Appl. Chem. 1977, 49, 443.
20. "Elastomeric and nanoporous membranes via Langmuir Blodgett transfer of cross-linked monolayers", Hui Xu, Robert Heger, Frank Mallwitz, Marita Blankenhagel, Claire Peyratout and Werner. A. Goedel, Mat. Res. Soc. Symp. Proc. Vol. 752 AA3.5.1-AA3.5.6 (2003).
21. "Highly Cross-linked Self-Assembled Monolayer Stationary Phases: A New Approach for Greatly Enhancing the Low pH Stability of RPLC Silica", Trammell, B.C., Ma, L., Luo, H., Jin, D., Hillmyer, M.A., Carr, P.W., Analytical Chemistry, (2002); "Highly Cross-linked Self-Assembled Monolayer Stationary Phases: A New Approach for Greatly Enhancing the Low pH Stability of RPLC Silica", Trammell, B.C., Hillmyer, M.A., Carr, P.W., The Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy, New Orleans, LA, March (2002).
22. "Highly Cross-linked Self-Assembled Monolayer Stationary Phases: A New Approach for Greatly Enhancing the Low pH Stability of RPLC Silica", Trammell, B.C., Ma, L., Luo, H., Jin, D., Hillmyer, M.A., Carr, P.W., Analytical Chemistry, (2002); "Highly Cross-linked Self-Assembled Monolayer Stationary Phases: A New Approach for Greatly Enhancing the Low pH Stability of RPLC Silica", Trammell, B.C., Hillmyer, M.A., Carr, P.W., The Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy, New Orleans, LA, March (2002).
23. "Conductivity in redox modified conducting polymers. 2. Enhanced redox conductivity in ferrocene-substituted polypyrroles and polythiophenes", Zotti, G.; Zecchin, S.; Schiavaon, G., Chem. Mater. 1995, 7, 2309-2315.
24. Lee, E. J., "Energy and Electron Transfer in Some Donor-Chromophore-Acceptor Compounds", Ph.D. Thesis, Massachusetts Institute of Technology, 1993.
25. "Porphyrins bearing mono or tripodal benzylphosphonic acid tethers for attachment to oxide surface", Loewe, R. S.; Ambroise, A.; Muthukumaran, K.; Padmaja, K.; Lysenko, A. B.; Mathur, G.; Li, Q.; Bocian, D. F,; Misra, V.; Lindsey J. S. J. Org. Chem. 2004, 69, 1453-1460.
26. "A simplified synthesis for meso-tetraphenylporphine", Adler, A. D.; Longo, F. R.; Finarelli, J. D.; Goldmacher, J.; Assour, J.; Korsakoff, L., J. Org. Chem., 1967, 32, 476.
27. "Synthesis and catalytic properties of manganese porphyrins incorporated into phosphonate networks", Deniaud, D.; Schollorn, B.; Mansuy, D.; Rouxel, J.; Battioni, P.; Bujoli, B., Chem. Mater. 1995, 7, 995-1000.
28. "Porphyrins bearing mono or tripodal benzylphosphonic acid tethers for attachment to oxide surface", Loewe, R. S.; Ambroise, A.; Muthukumaran, K.; Padmaja, K.; Lysenko, A. B.; Mathur, G.; Li, Q.; Bocian, D. F,; Misra, V.; Lindsey J. S., J. Org. Chem., 2004, 69, 1453-1460.
29. "Porphyrins bearing arylphosphonic acid tethers for attachment to oxide surface", Muthukumaran, K.; Loewe, R. S.; Ambroise, A.; Tamaru, S.; Li, Q.; Mathur, G.; Bocian, D. F.; Misra, V.; Lindsey, J. S., J. Org. Chem., 2004, 69, 1444-1452.
30. "On the preparation of metalloporphyrins", Adler, A. D.; Longo, F. R.; Kampas, F.; Kim, J. J., Inorg. Nucl. Chem., 1970, Vol. 32 2443-2445.
31. "The Chemist's Companion A Chemist Companion handbook of practical data, techniques, and references", Arnold J. Gordon, Richard A. Ford, John Willey & Sons, Inc., New York, 1972
32. "Chemistry of the iron group metallocenes", Myron Rosenblum, John Willey & Sons, Inc., New York, 1965
33. "Rothemund and Adler-Longo Reactions Revisited: Synthesis of Tetraphenylphophyrins under Equilibrium conditions", Jonathan S. Lindsey, Irwin C. Schreiman, Henry C. Hsu, Patrick C Kearney, and Anne M. Marguerettaz, J.Org.Chem., 1987, 52, 827-836
34. Manuscript in preparation to be submitted and to be orally discussed at the meeting of SPIE Optics East, Philadelphia, PA, October 27, 2004.