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37
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65549141344
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note
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Because 13b was isolated exclusively in the conversion of 12 to 13b it was concluded that the C3-TBS silyl group did not migrate to the C2-position. Thus, no rapid equivilation of the silyl group was taking place.
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38
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65549149239
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note
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We have not observed separation of the diastereomers caused by rac-10 throughout the syntheses of 21 and 22.
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39
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18444380851
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Harding J.R., King C.D., Perrie J.A., Sinnott D., and Stachulski A.V. Org. Biomol. Chem. 3 (2005) 1501
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Sinnott, D.4
Stachulski, A.V.5
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40
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65549100278
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note
-
Trace amounts of the desired coupling product were isolated with the pivaloyl-or benzoyl-protected imidate of D-manno-pyranuronate.
-
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-
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41
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65549165596
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note
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3 in MeOH (for 12 h) to regenerate 10 in quantitative yield.
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42
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65549088153
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note
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+: 549.1809; found: 549.1815.
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