-
2
-
-
4644329361
-
-
Kozak, C. M.; Mountford, P. Angew. Chem., Int. Ed. 2004, 43, 1186-1189.
-
(2004)
Angew. Chem., Int. Ed
, vol.43
, pp. 1186-1189
-
-
Kozak, C.M.1
Mountford, P.2
-
5
-
-
77956755601
-
-
Henderson, R. A.; Leigh, G. J.; Pickett, C. J. Adv. Inorg. Chem. 1983, 27, 197-292.
-
(1983)
Adv. Inorg. Chem
, vol.27
, pp. 197-292
-
-
Henderson, R.A.1
Leigh, G.J.2
Pickett, C.J.3
-
6
-
-
33947092184
-
-
Chatt, J.; Dilworth, J. R.; Richards, R. L. Chem. Rev. 1978, 78, 589-625.
-
(1978)
Chem. Rev
, vol.78
, pp. 589-625
-
-
Chatt, J.1
Dilworth, J.R.2
Richards, R.L.3
-
7
-
-
0031039732
-
-
Fryzuk, M. D.; Love, J. B.; Rettig, S. J.; Young, V. G. Science 1997, 275, 1445-1447.
-
(1997)
Science
, vol.275
, pp. 1445-1447
-
-
Fryzuk, M.D.1
Love, J.B.2
Rettig, S.J.3
Young, V.G.4
-
8
-
-
37049093194
-
-
Hussain, W.; Leigh, G. J.; Pickett, C. J. J. Chem. Soc., Chem. Commun. 1982, 747-748.
-
(1982)
J. Chem. Soc., Chem. Commun
, pp. 747-748
-
-
Hussain, W.1
Leigh, G.J.2
Pickett, C.J.3
-
9
-
-
0000829672
-
-
Ishino, H.; Tokunaga, S.; Seino, H.; Ishii, Y.; Hidai, M. Inorg. Chem. 1999, 38, 2489-2496.
-
(1999)
Inorg. Chem
, vol.38
, pp. 2489-2496
-
-
Ishino, H.1
Tokunaga, S.2
Seino, H.3
Ishii, Y.4
Hidai, M.5
-
10
-
-
2242420011
-
-
Le Grand, N.; Muir, K. W.; Petition, F. Y.; Pickett, C. J.; Schollham-mer, P.; Talarmin, J. Chem. Eur. J. 2002, 8, 3115-3127.
-
(2002)
Chem. Eur. J
, vol.8
, pp. 3115-3127
-
-
Le Grand, N.1
Muir, K.W.2
Petition, F.Y.3
Pickett, C.J.4
Schollham-mer, P.5
Talarmin, J.6
-
11
-
-
37049094844
-
-
Pickett, C. J.; Leigh, G. J. J. Chem. Soc., Chem. Commun. 1981, 1033-
-
Pickett, C. J.; Leigh, G. J. J. Chem. Soc., Chem. Commun. 1981, 1033-
-
-
-
-
12
-
-
1142280731
-
-
Pool, J. A.; Lobkovsky, E.; Chirik, P. J. Nature 2004, 427, 527-530.
-
(2004)
Nature
, vol.427
, pp. 527-530
-
-
Pool, J.A.1
Lobkovsky, E.2
Chirik, P.J.3
-
13
-
-
0001726221
-
-
Schrock, R. R.; Glassman, T. E.; Vale, M. G.; Kol, M. J. Am. Chem. Soc. 1993, 115, 1760-1772.
-
(1993)
J. Am. Chem. Soc
, vol.115
, pp. 1760-1772
-
-
Schrock, R.R.1
Glassman, T.E.2
Vale, M.G.3
Kol, M.4
-
14
-
-
0346994923
-
-
Smith, J. M.; Lachicotte, R. J.; Holland, P. L. J. Am. Chem. Soc. 2003, 125, 15752-15753.
-
(2003)
J. Am. Chem. Soc
, vol.125
, pp. 15752-15753
-
-
Smith, J.M.1
Lachicotte, R.J.2
Holland, P.L.3
-
15
-
-
34447120826
-
-
Sadique, A. R.; Gregory, E. A.; Brennessel, W. W.; Holland, P. L. J. Am. Chem. Soc. 2007, 129, 8112-8121.
-
(2007)
J. Am. Chem. Soc
, vol.129
, pp. 8112-8121
-
-
Sadique, A.R.1
Gregory, E.A.2
Brennessel, W.W.3
Holland, P.L.4
-
20
-
-
37049107490
-
-
Chatt, J.; Pearman, A. J.; Richards, R. L. J. Chem. Soc., Dalton Trans. 1976, 1520-1524.
-
(1976)
J. Chem. Soc., Dalton Trans
, pp. 1520-1524
-
-
Chatt, J.1
Pearman, A.J.2
Richards, R.L.3
-
21
-
-
0032538475
-
-
Tuczek, F.; Lehnert, N. Angew. Chem., Int. Ed. 1998, 37, 2636-2638.
-
(1998)
Angew. Chem., Int. Ed
, vol.37
, pp. 2636-2638
-
-
Tuczek, F.1
Lehnert, N.2
-
22
-
-
0002173638
-
-
Chatt, J.; Pearman, A. J.; Richards, R. L. Nature 1975, 253, 39-40.
-
(1975)
Nature
, vol.253
, pp. 39-40
-
-
Chatt, J.1
Pearman, A.J.2
Richards, R.L.3
-
23
-
-
0345275976
-
-
Tuczek, F.; Horn, K. H.; Lehnert, N. Coord. Chem. Rev. 2003, 245, 107-120.
-
(2003)
Coord. Chem. Rev
, vol.245
, pp. 107-120
-
-
Tuczek, F.1
Horn, K.H.2
Lehnert, N.3
-
25
-
-
37049076161
-
-
Galindo, A.: Hills, A.; Hughes, D. L.; Richards, R. L.; Hughes, M.; Mason, J. J. Chem. Soc., Dalton Trans. 1990, 283-288.
-
(1990)
J. Chem. Soc., Dalton Trans
, pp. 283-288
-
-
Galindo, A.1
Hills, A.2
Hughes, D.L.3
Richards, R.L.4
Hughes, M.5
Mason, J.6
-
26
-
-
0037463680
-
-
Horn, K. H.; Lehnert, N.; Tuczek, F. Inorg. Chem. 2003, 42, 1076-1086.
-
(2003)
Inorg. Chem
, vol.42
, pp. 1076-1086
-
-
Horn, K.H.1
Lehnert, N.2
Tuczek, F.3
-
27
-
-
64549100985
-
-
Henderson, R. A.; Leigh, G. J.; Pickett, C. J. J. Chem. Soc., Dalton Trans. 1989, 4205-430.
-
(1989)
J. Chem. Soc., Dalton Trans
, pp. 4205-4430
-
-
Henderson, R.A.1
Leigh, G.J.2
Pickett, C.J.3
-
28
-
-
19944398162
-
-
Horn, K. H.; Böres, N.; Lehnert, N.; Mersmann, K.; Nather, C.; Peters, G.; Tuczek, F. Inorg. Chem. 2005, 44, 3016-3030.
-
(2005)
Inorg. Chem
, vol.44
, pp. 3016-3030
-
-
Horn, K.H.1
Böres, N.2
Lehnert, N.3
Mersmann, K.4
Nather, C.5
Peters, G.6
Tuczek, F.7
-
29
-
-
19844365918
-
-
Mersmann, K.; Horn, K. H.; Bores, N.; Lehnert, N.; Studt, F.; Paulat, F.; Peters, G.; Ivanovic-Burmazovic, I.; van Eldik, R.; Tuczek, F. Inorg. Chem. 2005, 44, 3031-3045.
-
(2005)
Inorg. Chem
, vol.44
, pp. 3031-3045
-
-
Mersmann, K.1
Horn, K.H.2
Bores, N.3
Lehnert, N.4
Studt, F.5
Paulat, F.6
Peters, G.7
Ivanovic-Burmazovic, I.8
van Eldik, R.9
Tuczek, F.10
-
30
-
-
37049095557
-
-
Chatt, J.; Hussain, W.; Leigh, G. J.; Terreros, R P. J. Chem. Soc., Dalton Trans. 1980, 1408-1415.
-
(1980)
J. Chem. Soc., Dalton Trans
, pp. 1408-1415
-
-
Chatt, J.1
Hussain, W.2
Leigh, G.J.3
Terreros, R.P.4
-
32
-
-
0037155540
-
-
Rodima, T.; Kaljurand, I.; Pihl, A.; Maemets, V.; Leito, L.; Koppel, I. A. J. Org. Chem. 2002, 67, 1873-1881.
-
(2002)
J. Org. Chem
, vol.67
, pp. 1873-1881
-
-
Rodima, T.1
Kaljurand, I.2
Pihl, A.3
Maemets, V.4
Leito, L.5
Koppel, I.A.6
-
35
-
-
0003568278
-
-
3rd ed, Schaefer, H. F, Ed, Plenum: New York
-
Dunning, T. H., Jr.; Hay, P. J. In Modern Theoretical Chemistry, 3rd ed.; Schaefer, H. F., Ed.: Plenum: New York, 1976.
-
(1976)
Modern Theoretical Chemistry
-
-
Dunning Jr., T.H.1
Hay, P.J.2
-
39
-
-
64549087006
-
-
Frisch, M. J, Trucks, G. W, Schlegel, H. B, Scuseria, G. E, Robb, M. A, Cheeseman, J. R, Montgomery, J. J. A, Vreven, T, Kudin, K. N, Burant, J. C, Millam, J. M, Iyengar, S. S, Tomasi, J, Barone, V, Mennucci, B, Cossi, M, Scalmani, G, Rega, N, Petersson, G. A, Nakatsuji, H, Hada, M, Ehara, M, Toyota, K, Fukuda, R, Hasegawa, J, Ishida, M, Nakajima, T, Honda, Y, Kitao, O, Nakai, H, Klene, M, Li, X, Knox, J. E, Hratchian, H. P, Cross, J. B, Bakken, V, Adamo, C, Jaramillo, J, Gomperts, R, Stratmann, R. E, Yazyev, O, Austin, A. J, Cammi, R, Pomelli, C, Ochterski, J. W, Ayala, P. Y, Morokuma, K, Voth, G. A, Salvador, P, Dannenberg, J. J, Zakrzewski, V. G, Dapprich, S, Daniels, A. D, Strain, M. C, Farkas, O, Malick, D. K, Rabuck, A. D, Raghavachari, K, Foresman, J. B, Ortiz, J. V, Cui, Q, Baboul, A. G, Clifford, S, Cioslowski, J, Stefanov, B. B, Liu, G, Liashenko, A, Piskorz, P, Komaromi, I, Martin, R. L, Fox, D. J, Keith
-
Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.: Robb, M. A.; Cheeseman, J. R.; Montgomery, J. J. A.; Vreven, T.; Kudin, K. N.; Burant, J. C.; Millam, J. M.; Iyengar, S. S.; Tomasi, J.; Barone, V.; Mennucci, B.; Cossi, M.; Scalmani, G.; Rega, N.; Petersson, G. A.; Nakatsuji, H.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Klene, M.; Li, X.; Knox, J. E.; Hratchian, H. P.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Ayala, P. Y.; Morokuma, K.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Zakrzewski, V. G.; Dapprich, S.; Daniels, A. D.; Strain, M. C.; Farkas, O.; Malick, D. K.; Rabuck, A. D.; Raghavachari, K.; Foresman, J. B.; Ortiz, J. V.; Cui, Q.: Baboul, A. G.; Clifford, S.; Cioslowski, J.; Stefanov, B. B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Martin, R. L.; Fox, D. J.; Keith, T.; Al-Laham, M. A.; Peng, C. Y.; Nanayakkara, A.; Challacombe, M.; Gill, P. M. W.; Johnson, B.; Chen, W.; Wong, M. W.; Gonzalez, C.; Pople, J. A. Gaussian 03, Revision C.02; Gaussian, Inc.: Wallingford, CT, 2003.
-
-
-
-
40
-
-
64549139569
-
-
0)) is in favor of the initial rapid protonation, since without protonation the reaction would not occur.
-
0)) is in favor of the initial rapid protonation, since without protonation the reaction would not occur.
-
-
-
-
41
-
-
64549111589
-
-
2+ that can be present in the initial solution most probably is negligible even at the highest acid concentrations that were applied.
-
2+ that can be present in the initial solution most probably is negligible even at the highest acid concentrations that were applied.
-
-
-
-
42
-
-
64549089891
-
-
Notably, this is a gas-phase result, and more elaborate treatments including intermolecular interactions and solvent effects may provide evidence for some barriers for N-N cleavage. These, however, should be small and, in particular, in view of the large exothermicity of the N-N cleavage, should not alter the validity of the above statement
-
Notably, this is a gas-phase result, and more elaborate treatments including intermolecular interactions and solvent effects may provide evidence for some barriers for N-N cleavage. These, however, should be small and, in particular, in view of the large exothermicity of the N-N cleavage, should not alter the validity of the above statement.
-
-
-
-
43
-
-
37549021889
-
-
Selby, J. D.; Manley, C. D.; Feliz, M.; Schwarz, A. D.; Clot, E.; Mountford, P. Chem. Commun. 2007, 4937-4939.
-
(2007)
Chem. Commun
, pp. 4937-4939
-
-
Selby, J.D.1
Manley, C.D.2
Feliz, M.3
Schwarz, A.D.4
Clot, E.5
Mountford, P.6
-
44
-
-
64549152733
-
-
The activated characteristics of the acid-dependent pathways could also be associated with rate-limiting protonation reactions. This would be evident from deuterium effects. We have looked for this, employing the deuterated acid DNEt3, but found that the rate constants were not affected
-
+, but found that the rate constants were not affected.
-
-
-
-
45
-
-
64549124168
-
-
X intermediates are possible; cf. refs 46 and 52.
-
X intermediates are possible; cf. refs 46 and 52.
-
-
-
-
46
-
-
38149075096
-
-
Stephan, G. C.; Sivasankar, C.; Studt, F.; Tuczek, F. Chem. Eur. J. 2008, 14, 644-652.
-
(2008)
Chem. Eur. J
, vol.14
, pp. 644-652
-
-
Stephan, G.C.1
Sivasankar, C.2
Studt, F.3
Tuczek, F.4
-
48
-
-
0000107639
-
-
George, T. A.; Ma, L.; Shailh, S. N.; Tisdale, R. C.; Zubieta, J. Inorg. Chem. 1990, 29, 4789-4796.
-
(1990)
Inorg. Chem
, vol.29
, pp. 4789-4796
-
-
George, T.A.1
Ma, L.2
Shailh, S.N.3
Tisdale, R.C.4
Zubieta, J.5
-
50
-
-
24944561154
-
-
Studt, F.; Tuczek, F. Angew. Chem., Int. Ed. 2005, 44, 5639-5642.
-
(2005)
Angew. Chem., Int. Ed
, vol.44
, pp. 5639-5642
-
-
Studt, F.1
Tuczek, F.2
-
51
-
-
48649105618
-
-
Klatt, K.; Stephan, G.; Peters, G.; Tuczek, F. Inorg. Chem. 2008, 47, 6541-6550.
-
(2008)
Inorg. Chem
, vol.47
, pp. 6541-6550
-
-
Klatt, K.1
Stephan, G.2
Peters, G.3
Tuczek, F.4
-
52
-
-
67649672247
-
In Metal Ion Controlled Reactivity
-
C. Hubbard, R. v. Eldik; Eds, in press
-
Dreher, A.; Stephan, G.; Tuczek, F. In Metal Ion Controlled Reactivity; C. Hubbard, R. v. Eldik; Eds.; Adv. Inorg. Chem. 2009, Vol. 61, in press.
-
(2009)
Adv. Inorg. Chem
, vol.61
-
-
Dreher, A.1
Stephan, G.2
Tuczek, F.3
-
54
-
-
33751232674
-
-
Barney, B. M.; Lukoyanov, D.; Yang, T. C.; Dean, D. R.; Hoffman, B. M.; Seefeldt, L. C. Proc. Natl. Acad. Sci U.S.A. 2006, 103, 17113-17118.
-
(2006)
Proc. Natl. Acad. Sci U.S.A
, vol.103
, pp. 17113-17118
-
-
Barney, B.M.1
Lukoyanov, D.2
Yang, T.C.3
Dean, D.R.4
Hoffman, B.M.5
Seefeldt, L.C.6
-
55
-
-
64549159190
-
-
In fact, this is the most exothermic step of the Chatt cycle (cf. refs 46 and 52) and the Schrock cycle cf. ref 50
-
In fact, this is the most exothermic step of the Chatt cycle (cf. refs 46 and 52) and the Schrock cycle (cf. ref 50).
-
-
-
|