Spectroscopic characterization of molybdenum dinitrogen complexes containing a combination of di- and triphosphine coligands: 31P NMR analysis of five-spin systems

Inorganic Chemistry

Volumn 47, Issue 14, 2008, Pages 6541-6550

  Klatt, Kristina ^a   Stephan, Gerald ^a   Peters, Gerhard ^a   Tuczek, Felix ^a  

^a UNIVERSITY OF KIEL   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 48649105618     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic800389g     Document Type: Article

References (39)

1. (a) Henry, R. M.; Shoemaker, R. K.; Newell, R. H.; Jacobsen, G. M.; DuBois, D. L.; Rakowski DuBois, M. Organometallics 2005, 24, 2481.
2. (b) Pregosin, P. S.; Kunz, R. W., NMR Basic Principles and Progress; Springer Verlag: New York, 1979; Vol. 16.
3. (c) Verkade, J. G. Coord. Chem. Rev. 1972, 9, 1.
4. (a) MacKay, B. A.; Fryzuk, M. D. Chem. Rev. 2004, 104, 385.
5. (b) Hidai, M.; Mizobe, Y. Chem. Rev. 1995, 95, 1115.
6. (c) Henderson, R. A.; Leigh, G. J.; Pickett, C. J. Adv. Inorg. Chem. Radiochem. 1983, 27, 197.
7. (d) Chatt, J.; Dilworth, J. R.; Richards, R. L. Chem. Rev. 1978, 78, 589.
8. (a) Prokaryotic Nitrogen Fixation: A Model System for the Analysis of a Biological Process; Triplett, E. W., Ed.; Horizon Scientific Press: Norfolk, U.K., 2000.
9. (b) Burgess, B. K.; Lowe, D. J. Chem. Rev. 1996, 96, 2983.
10. (a) Pickett, C. J.; Talarmin, J. Nature 1985, 317, 652.
11. (b) Pickett, C. J.; Ryder, K. S.; Talarmin, J. J. C. S. Dalton Trans., Inorg. Chem. 1986, 7, 1453.
12. (a) Yandulov, D. V.; Schrock, R. R. J. Am. Chem. Soc. 2002, 124, 6252.
13. (b) Yandulov, D. V.; Schrock, R. R.; Rheingold, A. L.; Ceccarelli, C.; Davis, W. M. Inorg. Chem. 2003, 42, 796.
14. (c) Yandulov, D. V.; Schrock, R. R. Science 2003, 301, 76.
15. (d) Ritleng, V.; Yandulov, D. V.; Weare, W. W.; Schrock, R. R.; Hock, A. S.; Davis, W. M. J. Am. Chem. Soc. 2004, 126, 6150.
16. (e) Yandulov, D. V.; Schrock, R. R. Inorg. Chem. 2005, 44, 1103.
17. (f) Yandulov, D. V.; Schrock, R. R. Inorg. Chem. 2005, 44, 5542.
18. (g) Yandulov, D. V.; Schrock, R. R. Can. J. Chem. 2005, 83, 341.
19. Stephan, G.; Sivasankar, Ch.; Tuczek, F. Chem. Eur. J. 2008, 14, 644-652.
20. Studt, F.; Tuczek, F. Angew. Chem., Int. Ed. 2005, 44, 5639-5642.
21. (a) George, T. A.; Tisdale, R. C. Inorg. Chem. 1988, 27, 2909.
22. (b) George, T. A.; Tisdale, R. C. J. Am. Chem. Soc. 1985, 107, 5157.
23. (c) George, T. A.; Ma, L.; Shailh, S. N.; Tisdale, R. C.; Zubieta, J. Inorg. Chem 1990, 29, 4789.
24. Stephan, G. C.; Peters, G.; Lehnert, N.; Habeck, C. M.; Näther, C.; Tuczek, F. Can. J. Chem. 2005, 83, 385.
25. Stephan, G.; Tuczek, F. In Activating Unreactive Substrates; Bolm, C. , Hahn, E., Eds.; Wiley VCH: New York, 2008;. submitted for publication.
26. Mestrec, Mestrelab Research, Santiago de Compostela.
27. Tuczek, F.; Horn, K. H.; Lehnert, N. Coord. Chem. Rev. 2003, 245, 107-120.
28. Günther, H. Angew. Chem. 1972, 19, 907.
29. Fontaine, X. L. R.; Kennedy, J. D.; Shaw, B. L.; Vila José, M. J. Chem. Soc., Dalton Trans. 1987, 2401.
30. 13C NMR of Transition Metal Phosphine Complexes; Springer-Verlag: New York, 1979.
31. Friebolin, H. Ein- und zweidimensionale NMR-Spektroskopie; Wiley VCH: Weinheim, 2006.
32. (a) Bertrand, R. D.; Ogilie, F. B.; Verkade, J. G. J. Am. Chem. Soc. 1970, 92, 1916.
33. (b) Ogilie, F. B.; Jenkins, J. M.; Verkade, J. G. J. Am. Chem. Soc., 1970, 92, 1908.
34. (c) Crumbliss, A. L.; Topping, R. J. Phosphorus-31 NMR: Spectral Properties in Compound Characterization and Structural Analysis; VCH: New York, 1987; Vol. 15.
35. (d) Hughes, A. N. Phosphorus-31 NMR: Spectral Properties in Compound Characterization and Structural Analysis; VCH: New York, 1987; Vol. 19.
36. (e) Clark, H. C.; Kapoor, P. N.; McMahon, I. J. J. Organomet. Chem. 1984, 190, C101.
37. (f) Airey, A. A.; Swiegers, G. F.; Willis, A. C.; Wild, S. B. Inorg. Chem. 1997, 36, 1588.
38. trans values for metal complexes in the first transition-metal series can be of similar magnitude whereas in the second and third series the trans-coupling is usually much larger.
39. Stephan, G.; Näther, C. N.; Sivasankar, C.; Tuczek, F. Inorg. Chim. Acta 2008, 361, 1008-1019.