Spontaneous reduction of mixed 2,2′-bipyridine/methylamine/chloro complexes of PtIV in water in the presence of light is accompanied by complex isomerization, loss of methylamine, and formation of a strong oxidant, presumably HOCl

Chemistry - A European Journal

Volumn 13, Issue 14, 2007, Pages 3980-3988

  Nakabayashi, Yasuo ^a,b   Erxleben, Andrea ^a   Létinois, Ulla ^c   Pratviel, Geneviève ^c   Meunier, Bernard ^c   Holland, Lars ^a   Lippert, Bernhard ^a  

^a TU DORTMUND UNIVERSITY   (Germany)

^b KANSAI UNIVERSITY   (Japan)

^c CNRS   (France)

Author keywords

Oxidation; Platinum; Reductive elimination; Solvolysis

Indexed keywords

AMINES; COMPLEXATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDANTS; OXIDATION; PYRIDINE; REDUCTION;

COUPLING CONSTANTS; HYPOCHLOROUS ACID; REDUCTIVE ELIMINATION; SOLVOLYSIS;

PLATINUM COMPOUNDS;

2,2' BIPYRIDINE; CHLORINE; HYPOCHLOROUS ACID; METHYLAMINE; PLATINUM DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; ISOMERISM; LIGHT; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION REDUCTION REACTION;

2,2'-DIPYRIDYL; CHLORINE; HYPOCHLOROUS ACID; ISOMERISM; LIGHT; MAGNETIC RESONANCE SPECTROSCOPY; METHYLAMINES; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; PLATINUM COMPOUNDS;

EID: 34250375945     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200601271     Document Type: Article

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