Gas-Phase Reactivity of Ruthenium Carbonyl Cluster Anions

Journal of the American Society for Mass Spectrometry

Volumn 20, Issue 4, 2009, Pages 658-666

  Henderson, Matthew A ^a   Kwok, Samantha ^a   McIndoe, J Scott ^a  

^a UNIVERSITY OF VICTORIA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

BREAK DOWNS; C - H ACTIVATIONS; CLUSTER CORES; COLLISION-INDUCED DISSOCIATIONS; DIHYDROGEN; ELECTROSPRAY IONIZATION MASS SPECTROMETRIES; ENERGY DEPENDENTS; GAS-PHASE; GAS-PHASE REACTIVITIES; LARGE AMOUNTS OF DATUM; METAL-METAL BONDS; OXIDATIVE CLEAVAGES; RUTHENIUM CARBONYL CLUSTERS; TRIETHYLSILANE; UNSATURATED CLUSTERS;

ACTIVATION ANALYSIS; CARBON CLUSTERS; CARBON MONOXIDE; CARBONYLATION; CHEMICAL BONDS; DISSOCIATION; GASES; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; IONIZATION OF GASES; MASS SPECTROMETERS; MASS SPECTROMETRY; OLEFINS; OXYGEN; PARAFFINS; RUTHENIUM;

ELECTROSPRAY IONIZATION;

EID: 62249155479     PISSN: 10440305     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jasms.2008.12.006     Document Type: Article

References (63)

1. O'Hair R.A.J., and Khairallah G.N. Gas Phase Ion Chemistry of Transition Metal Clusters: Production, Reactivity, and Catalysis. J. Clust. Sci. 15 (2004) 331-363
2. Armentrout P.B. Reactions and Thermochemistry of Small Transition Metal Cluster ions. Annu. Rev. Phys. Chem. 52 (2001) 423-461
3. Plattner D.A. Electrospray Mass Spectrometry Beyond Analytical Chemistry: Studies of Organometallic Catalysis in the Gas Phase. Int. J. Mass Spectrom. 207 (2001) 125-144
4. Bohme D.K., and Schwarz H. Gas-Phase Catalysis by Atomic and Cluster Metal Ions: The Ultimate Single-Site Catalysts. Angew. Chem. Int. Ed. 44 (2005) 2336-2354
5. +. Organometallics 22 (2003) 2217-2225
6. Gerdes G., and Chen P. Response to: "C-H Activation by Platinum(II): What Do Gas-Phase Studies Tell Us About the Solution-Phase Mechanism?". Organometallics 25 (2006) 809-811
7. Labinger J.A., Bercaw J.E., and Tilset M. C-H Activation by Platinum(II): What Do Gas-Phase Studies Tell Us About the Solution-Phase Mechanism?. Organometallics 25 (2006) 805-808
8. Zemski K.A., Justes D.R., and Castleman Jr. A.W. Studies of Metal Oxide Clusters: Elucidating Reactive Sites Responsible for the Activity of Transition Metal Oxide Catalysts. J. Phys. Chem. B 106 (2002) 6136-6148
9. +. Int. J. Mass Spectrom. 204 (2001) 233-245
10. 2: "Micro-Oxides of Iron". Chem. Eur. J. 2 (1996) 598-603
11. Bell R.C., Zemski K.A., and Castleman A.W. Size-Specific Reactivities of Vanadium Oxide Cluster Cations. J. Clust. Sci. 10 (1999) 509-524
12. + and its mediation of the C-C Coupling of Allyl Bromide. Angew. Chem. Int. Ed. 44 (2005) 728-731
13. + (M = V, Fe; X = O, S; N = 2, 3) in the Gas Phase. Inorg. Chim. Acta. 273 (1998) 111-115
14. y] Clusters. J. Am. Chem. Soc. 113 (1991) 5141-5148
15. 3 in the Gas Phase: An experimental and DFT study. Chem. Phys. Lett. 413 (2005) 429-433
16. 2. J. Phys. Chem. A 110 (2006) 3505-3513
17. 2O: Coupling Processes versus Carbide Formation. Organometallics 22 (2003) 3809-3819
18. + (R = Me and Ph). Dalton Trans. (2006) 3699-3707
19. Waters T., O'Hair R.A.J., and Wedd A.G. Catalytic Gas Phase Oxidation of Methanol to Formaldehyde. J. Am. Chem. Soc. 125 (2003) 3384-3396
20. nBu). Inorg. Chem. 44 (2005) 3356-3366
21. Deng H.T., Kerns K.P., and Castleman A.W. Formation, Structures, and Reactivities of Niobium Oxide Cluster Ions. J. Phys. Chem. 100 (1996) 13386-13392
22. + in the Gas Phase and Over Real Catalysts. J. Phys. Chem. B 101 (1997) 5772-5773
23. Freas R.B., and Ridge D.P. Effect of a Carbonyl Ligand on the rReactivity of Cobalt(2+) Ion Toward Alkanes. J. Am. Chem. Soc. 106 (1984) 825-826
24. Pan Y.H., and Ridge D.P. Reactions of Cyclohexane with Tetrairidium Carbonyl Cluster Ions: Electronic Criteria for Carbon-Hydrogen Bond Activation in Alkanes. J. Phys. Chem. 93 (1989) 3375-3378
25. Butcher C.P.G., Dyson P.J., Johnson B.F.G., Khimyak T., and McIndoe J.S. Fragmentation of Transition Metal Carbonyl Cluster Anions: Structural Insights from Mass Spectrometry. Chem. Eur. J. 9 (2003) 944-950
26. Butcher C.P.G., Dinca A., Dyson P.J., Johnson B.F.G., Langridge-Smith P.R.R., and McIndoe J.S. A Strategy for Generating Naked-Metal Clusters for Gas-Phase Reactivity Studies by FTICR-MS. Angew. Chem. Int. Ed. 42 (2003) 5752-5755
27. - X-Ray Crystallographic Determination of Two Structural Isomers. J. Chem. Soc. Chem. Commun. (1978) 920-921
28. Dyson P.J., Hearley A.K., Johnson B.F.G., McIndoe J.S., Langridge-Smith P.R.R., and Whyte C. Combining Energy-Dependent Electrospray Ionization with Tandem Mass Spectrometry for the Analysis of Inorganic Compounds. Rapid Commun. Mass Spectrom. 15 (2001) 895-897
29. Butcher C.P.G., Dyson P.J., Johnson B.F.G., Langridge-Smith P.R.R., McIndoe J.S., and Whyte C. On the Use of Breakdown Graphs Combined with Energy-Dependent Mass Spectrometry to Provide a Complete Picture of Fragmentation Processes. Rapid Commun. Mass Spectrom. 16 (2002) 1595-1598
30. Husheer S.L.G., Forest O., Henderson M., and McIndoe J.S. EDit: A Computer Program to Assist in the Presentation of Energy-Dependent Mass Spectra. Rapid Commun. Mass Spectrom. 19 (2005) 1352-1354
31. Freiser B.S. Gas-Phase Metal Ion Chemistry. J. Mass Spectrom. 31 (1996) 703-715
32. Chen P. Electrospray Ionization Tandem Mass Spectrometry in High-Throughput Screening of Homogeneous Catalysts. Angew. Chem. Int. Ed. 42 (2003) 2832-2847
33. Gerlich D. Experimental Investigations of Ion-Molecule Reactions Relevant to Interstellar Chemistry. J. Chem. Soc. Faraday Trans. 89 (1993) 2199-2208
34. O'Hair R.A.J. The 3D Quadrupole Ion Trap Mass Spectrometer as a Complete Chemical Laboratory for Fundamental Gas-Phase Studies of Metal Mediated Chemistry. Chem. Commun. (2006) 1469-1481
35. + Complexes Generated by Electrospray Ionization. Int. J. Mass Spectrom. 219 (2002) 729-738
36. Trage C., Diefenbach M., Schroder D., and Schwarz H. Innocent and Less-Innocent Solvent Ligands: A Systematic Investigation of Cationic Iron Chloride/Alcohol Complexes by Electrospray Ionization Mass Spectrometry Complemented by DFT Calculations. Chem. Eur. J. 12 (2006) 2454-2464
37. Fenn J.B., Mann M., Meng C.K., Wong S.F., and Whitehouse C.M. Electrospray Ionization for Mass Spectrometry of Large Biomolecules. Science 246 (1989) 64-71
38. Henderson W., and McIndoe J.S. Mass Spectrometry of Inorganic and Organometallic Compounds: ToolsTechniquesTips (2005), Wiley, Chichester p. 90
39. Sakamoto S., Fujita M., Kim K., and Yamaguchi K. Characterization of Self-Assembling Nano-Sized Structures by Means of Coldspray Ionization Mass Spectrometry. Tetrahedron 56 (2000) 955-964
40. 2. Angew. Chem. Int. Ed. 44 (2005) 6875-6878
41. Schneider B.B., and Chen D.D.Y. Collision-Induced Dissociation of Ions Within the Orifice-Skimmer Region of an Electrospray Mass Spectrometer. Anal. Chem. 72 (2000) 791-799
42. Spence T.G., Burns T.D., and Posey L.A. Controlled Synthesis of Transition-Metal Ion Complex Solvent Clusters by Electrospray. J. Phys. Chem. A 101 (1997) 139-144
43. Ikonomou M.G., Blades A.T., and Kebarle P. Electrospray Ion Spray-a Comparison of Mechanisms and Performance. Anal. Chem. 63 (1991) 1989-1998
44. Spence T.G., Trotter B.T., Burns T.D., and Posey L.A. Metal-to-Ligand Charge Transfer in the Gas-Phase Cluster Limit. J. Phys. Chem. A 102 (1998) 6101-6106
45. Schlosser G., Takats Z., and Vékey K. Formation of Solvated Ions in the Atmospheric Interface of an Electrospray Ionization Triple-Quadrupole Mass Spectrometer. J. Mass Spectrom. 38 (2003) 1245-1251
46. McQuinn K., Hof F., and McIndoe J.S. Direct Observation of Ion Evaporation from a Triply Charged Nanodroplet. Chem. Commun. (2007) 4099-4101
47. McQuinn K., McIndoe L.S., and Hof F. Insights into the Post-Translational Methylation of Arginine from Studies of Guanidinium-Water Nanodroplets. Chem. Eur. J. 14 (2008) 6483-6489
48. Chisholm D.M., and McIndoe J.S. Charged Ligands for Catalyst Immobilization and Analysis. Dalton Trans. (2008) 3933-3945
49. Johnson B.F.G., and McIndoe J.S. Spectroscopic and Mass Spectrometric Methods for the Characterization of Metal Clusters. Coord. Chem. Rev. 200/202 (2000) 901-932
50. Ungermann C., Landis V., Moya S.A., Cohen H., Walker H., Pearson R.G., Rinker R.G., and Ford P.C. Homogeneous Catalysis of the Water Gas Shift Reaction by Ruthenium and Other Metal Carbonyls. Studies in Alkaline Solutions. J. Am. Chem. Soc. 101 (1979) 5922-5929
51. Bricker J.C., Nagel C.C., and Shore S.G. Reactivities of Ruthenium Cluster Anions: Implications for Catalysis of the Water-Gas Sshift Reaction. J. Am. Chem. Soc. 104 (1982) 1444-1445
52. - as catalyst. J. Organomet. Chem. 355 (1988) 379-384
53. Suess-Fink G., Herrmann G., and Schmidt G.F. Novel Catalytic Applications of Anionic Ruthenium Clusters in Isocyanate Chemistry. Polyhedron 7 (1988) 2341-2344
54. 12. Inorg. Chem. 21 (1982) 2732-2736
55. Bhaduri S., Sharma K., and Mukesh D. Transfer Hydrogenation of Ketones with Dodecacarbonyltrihydridotetraruthenate(-) as the Orecatalyst. J. Chem. Soc. Dalton Trans. (1993) 1191-1199
56. 12]. Identification of Organometallic Products and a Discussion of Their Role. J. Organomet. Chem. 491 (1995) 111-120
57. Tominaga K.-I., and Sasaki Y. Ruthenium-Catalyzed One-Pot Hydroformylation of Alkenes Using Carbon Dioxide as a Reactant. J. Mol. Catal. A: Chemical. 220 (2004) 159-165
58. Farrer N.J., McDonald R., and McIndoe J.S. Proton Sponge Phosphines: Electrospray-Active Ligands. Dalton Trans. (2006) 4570-4579
59. Dyson P.J., Johnson B.F.G., McIndoe J.S., and Langridge-Smith P.R.R. Energy-Dependent Electrospray Ionization Mass Spectrometry: Applications in Transition Metal Carbonyl Chemistry. Rapid Commun. Mass Spectrom. 14 (2000) 311-313
60. Crabtree R.H. The Organometallic Chemistry of the Transition Metals. 3rd ed. (2001), John Wiley and Sons, New York p. 137
61. Dyson P.J., and McIndoe J.S. Transition Metal Carbonyl Cluster Chemistry (2000), Gordon and Breach, Amsterdam p. 43
62. Crabtree R.H. The Organometallic Chemistry of Alkanes. Chem. Rev. 85 (1985) 245-269
63. Molina-Svendsen H., Bojesen G., and McKenzie C.J. Gas-Phase Reactivity of Coordinatively Unsaturated Transition Metal Complex Ions Toward Molecular Oxygen. Inorg. Chem. 37 (1998) 1981-1983