Electrospray mass spectrometry beyond analytical chemistry: Studies of organometallic catalysis in the gas phase

International Journal of Mass Spectrometry

Volumn 207, Issue 3, 2001, Pages 125-144

  Plattner, Dietmar A ^a  

^a ETH ZURICH   (Switzerland)

Author keywords

CID threshold measurements; Electrospray ionization; Tandem mass spectrometry; Transition metal catalysis, Ion molecule chemistry

Indexed keywords

ACETONITRILE; ALKENE; CARBON; CATION; DEUTERIUM; HYDROGEN; INORGANIC COMPOUND; IRIDIUM COMPLEX; LIGAND; MANGANESE DERIVATIVE; METAL ION; ORGANOMETALLIC COMPOUND; OXYGEN; ZIRCONIUM DERIVATIVE;

ANALYTIC METHOD; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; CHEMISTRY; DISSOCIATION; EPOXIDATION; GAS; HYDROGEN BOND; IONIZATION; LIGAND BINDING; MACROMOLECULE; MASS SPECTROMETRY; OXIDATION; PHASE TRANSITION; POLYMERIZATION; REACTION ANALYSIS; REVIEW; TANDEM MASS SPECTROMETRY;

EID: 0035897558     PISSN: 13873806     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1387-3806(01)00371-2     Document Type: Review

References (97)

1. Freiser B.S. Organometallic Ion Chemistry. 1996;Kluwer, Dordrecht.
2. Schröder D., Schwarz H. J. Phys. Chem. A. 103:1999;7385.
3. Schröder D., Schwarz H. Angew. Chem. Int. Ed. Engl. 34:1995;1973.
4. Armentrout P.B. Acc. Chem. Res. 28:1995;430.
5. Rodgers M.T., Armentrout P.B. Mass Spectrom. Rev. 19:2000;215.
6. Recent, representative work: I. Kretzschmar, D. Schröder, H. Schwarz, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 5046; M. Brönstrup, C. Trage, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 122 (2000) 699; M. Diefenbach, M. Brönstrup, M. Aschi, D. Schröder, H. Schwarz, ibid. 121 (1999) 10614; M. Brönstrup, D. Schröder, H. Schwarz, Organometallics 18 (1999) 1939; G. Hornung, S. Bärsch, D.Schröder, H. Schwarz, ibid. 17 (1998) 2271; M. Aschi, M. Brönstrup, M. Diefenbach, J.N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. Int. Ed. Engl. 37 (1998) 829; A. Andersen, F. Muntean, D. Walter, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 692; M.T. Rodgers, P.B. Armentrout, ibid. 103 (1999) 4955; M.R. Sievers, P.B. Armentrout, Inorg. Chem. 38 (1999) 397; P.A.M. van Koppen, M.T. Bowers, C.L. Haynes, P.B. Armentrout, J. Am. Chem. Soc. 120 (1998) 5704; D. Walter, P.B. Armentrout, ibid. 120 (1998) 3176; S.W. Lee, S.B. Chang, D. Kossakovski, H. Cox, J.L. Beauchamp, ibid. 121 (1999) 10152; K.C. Crellin, J.L. Beauchamp, W.A. Goddard, S. Geribaldi, M. Decouzon, Int. J. Mass Spectrom. 183 (1999) 121; K.C. Crellin, J.L. Beauchamp, S. Geribaldi, M. Decouzon, Organometallics 15 (1996) 5368; H.P. Chen, D.B. Jacobson, B.S. Freiser, J. Phys. Chem. A 103 (1999) 10884; Q. Chen, C. Sioma, S.Z. Kan, B.S. Freiser, Int. J. Mass Spectrom. 180 (1998) 231; Q. Chen, B.S. Freiser, J. Phys. Chem. A 102 (1998) 3343.
7. Recent, representative work: I. Kretzschmar, D. Schröder, H. Schwarz, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 5046; M. Brönstrup, C. Trage, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 122 (2000) 699; M. Diefenbach, M. Brönstrup, M. Aschi, D. Schröder, H. Schwarz, ibid. 121 (1999) 10614; M. Brönstrup, D. Schröder, H. Schwarz, Organometallics 18 (1999) 1939; G. Hornung, S. Bärsch, D.Schröder, H. Schwarz, ibid. 17 (1998) 2271; M. Aschi, M. Brönstrup, M. Diefenbach, J.N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. Int. Ed. Engl. 37 (1998) 829; A. Andersen, F. Muntean, D. Walter, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 692; M.T. Rodgers, P.B. Armentrout, ibid. 103 (1999) 4955; M.R. Sievers, P.B. Armentrout, Inorg. Chem. 38 (1999) 397; P.A.M. van Koppen, M.T. Bowers, C.L. Haynes, P.B. Armentrout, J. Am. Chem. Soc. 120 (1998) 5704; D. Walter, P.B. Armentrout, ibid. 120 (1998) 3176; S.W. Lee, S.B. Chang, D. Kossakovski, H. Cox, J.L. Beauchamp, ibid. 121 (1999) 10152; K.C. Crellin, J.L. Beauchamp, W.A. Goddard, S. Geribaldi, M. Decouzon, Int. J. Mass Spectrom. 183 (1999) 121; K.C. Crellin, J.L. Beauchamp, S. Geribaldi, M. Decouzon, Organometallics 15 (1996) 5368; H.P. Chen, D.B. Jacobson, B.S. Freiser, J. Phys. Chem. A 103 (1999) 10884; Q. Chen, C. Sioma, S.Z. Kan, B.S. Freiser, Int. J. Mass Spectrom. 180 (1998) 231; Q. Chen, B.S. Freiser, J. Phys. Chem. A 102 (1998) 3343.
8. Recent, representative work: I. Kretzschmar, D. Schröder, H. Schwarz, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 5046; M. Brönstrup, C. Trage, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 122 (2000) 699; M. Diefenbach, M. Brönstrup, M. Aschi, D. Schröder, H. Schwarz, ibid. 121 (1999) 10614; M. Brönstrup, D. Schröder, H. Schwarz, Organometallics 18 (1999) 1939; G. Hornung, S. Bärsch, D.Schröder, H. Schwarz, ibid. 17 (1998) 2271; M. Aschi, M. Brönstrup, M. Diefenbach, J.N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. Int. Ed. Engl. 37 (1998) 829; A. Andersen, F. Muntean, D. Walter, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 692; M.T. Rodgers, P.B. Armentrout, ibid. 103 (1999) 4955; M.R. Sievers, P.B. Armentrout, Inorg. Chem. 38 (1999) 397; P.A.M. van Koppen, M.T. Bowers, C.L. Haynes, P.B. Armentrout, J. Am. Chem. Soc. 120 (1998) 5704; D. Walter, P.B. Armentrout, ibid. 120 (1998) 3176; S.W. Lee, S.B. Chang, D. Kossakovski, H. Cox, J.L. Beauchamp, ibid. 121 (1999) 10152; K.C. Crellin, J.L. Beauchamp, W.A. Goddard, S. Geribaldi, M. Decouzon, Int. J. Mass Spectrom. 183 (1999) 121; K.C. Crellin, J.L. Beauchamp, S. Geribaldi, M. Decouzon, Organometallics 15 (1996) 5368; H.P. Chen, D.B. Jacobson, B.S. Freiser, J. Phys. Chem. A 103 (1999) 10884; Q. Chen, C. Sioma, S.Z. Kan, B.S. Freiser, Int. J. Mass Spectrom. 180 (1998) 231; Q. Chen, B.S. Freiser, J. Phys. Chem. A 102 (1998) 3343.
9. Recent, representative work: I. Kretzschmar, D. Schröder, H. Schwarz, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 5046; M. Brönstrup, C. Trage, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 122 (2000) 699; M. Diefenbach, M. Brönstrup, M. Aschi, D. Schröder, H. Schwarz, ibid. 121 (1999) 10614; M. Brönstrup, D. Schröder, H. Schwarz, Organometallics 18 (1999) 1939; G. Hornung, S. Bärsch, D.Schröder, H. Schwarz, ibid. 17 (1998) 2271; M. Aschi, M. Brönstrup, M. Diefenbach, J.N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. Int. Ed. Engl. 37 (1998) 829; A. Andersen, F. Muntean, D. Walter, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 692; M.T. Rodgers, P.B. Armentrout, ibid. 103 (1999) 4955; M.R. Sievers, P.B. Armentrout, Inorg. Chem. 38 (1999) 397; P.A.M. van Koppen, M.T. Bowers, C.L. Haynes, P.B. Armentrout, J. Am. Chem. Soc. 120 (1998) 5704; D. Walter, P.B. Armentrout, ibid. 120 (1998) 3176; S.W. Lee, S.B. Chang, D. Kossakovski, H. Cox, J.L. Beauchamp, ibid. 121 (1999) 10152; K.C. Crellin, J.L. Beauchamp, W.A. Goddard, S. Geribaldi, M. Decouzon, Int. J. Mass Spectrom. 183 (1999) 121; K.C. Crellin, J.L. Beauchamp, S. Geribaldi, M. Decouzon, Organometallics 15 (1996) 5368; H.P. Chen, D.B. Jacobson, B.S. Freiser, J. Phys. Chem. A 103 (1999) 10884; Q. Chen, C. Sioma, S.Z. Kan, B.S. Freiser, Int. J. Mass Spectrom. 180 (1998) 231; Q. Chen, B.S. Freiser, J. Phys. Chem. A 102 (1998) 3343.
10. Recent, representative work: I. Kretzschmar, D. Schröder, H. Schwarz, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 5046; M. Brönstrup, C. Trage, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 122 (2000) 699; M. Diefenbach, M. Brönstrup, M. Aschi, D. Schröder, H. Schwarz, ibid. 121 (1999) 10614; M. Brönstrup, D. Schröder, H. Schwarz, Organometallics 18 (1999) 1939; G. Hornung, S. Bärsch, D.Schröder, H. Schwarz, ibid. 17 (1998) 2271; M. Aschi, M. Brönstrup, M. Diefenbach, J.N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. Int. Ed. Engl. 37 (1998) 829; A. Andersen, F. Muntean, D. Walter, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 692; M.T. Rodgers, P.B. Armentrout, ibid. 103 (1999) 4955; M.R. Sievers, P.B. Armentrout, Inorg. Chem. 38 (1999) 397; P.A.M. van Koppen, M.T. Bowers, C.L. Haynes, P.B. Armentrout, J. Am. Chem. Soc. 120 (1998) 5704; D. Walter, P.B. Armentrout, ibid. 120 (1998) 3176; S.W. Lee, S.B. Chang, D. Kossakovski, H. Cox, J.L. Beauchamp, ibid. 121 (1999) 10152; K.C. Crellin, J.L. Beauchamp, W.A. Goddard, S. Geribaldi, M. Decouzon, Int. J. Mass Spectrom. 183 (1999) 121; K.C. Crellin, J.L. Beauchamp, S. Geribaldi, M. Decouzon, Organometallics 15 (1996) 5368; H.P. Chen, D.B. Jacobson, B.S. Freiser, J. Phys. Chem. A 103 (1999) 10884; Q. Chen, C. Sioma, S.Z. Kan, B.S. Freiser, Int. J. Mass Spectrom. 180 (1998) 231; Q. Chen, B.S. Freiser, J. Phys. Chem. A 102 (1998) 3343.
11. Recent, representative work: I. Kretzschmar, D. Schröder, H. Schwarz, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 5046; M. Brönstrup, C. Trage, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 122 (2000) 699; M. Diefenbach, M. Brönstrup, M. Aschi, D. Schröder, H. Schwarz, ibid. 121 (1999) 10614; M. Brönstrup, D. Schröder, H. Schwarz, Organometallics 18 (1999) 1939; G. Hornung, S. Bärsch, D.Schröder, H. Schwarz, ibid. 17 (1998) 2271; M. Aschi, M. Brönstrup, M. Diefenbach, J.N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. Int. Ed. Engl. 37 (1998) 829; A. Andersen, F. Muntean, D. Walter, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 692; M.T. Rodgers, P.B. Armentrout, ibid. 103 (1999) 4955; M.R. Sievers, P.B. Armentrout, Inorg. Chem. 38 (1999) 397; P.A.M. van Koppen, M.T. Bowers, C.L. Haynes, P.B. Armentrout, J. Am. Chem. Soc. 120 (1998) 5704; D. Walter, P.B. Armentrout, ibid. 120 (1998) 3176; S.W. Lee, S.B. Chang, D. Kossakovski, H. Cox, J.L. Beauchamp, ibid. 121 (1999) 10152; K.C. Crellin, J.L. Beauchamp, W.A. Goddard, S. Geribaldi, M. Decouzon, Int. J. Mass Spectrom. 183 (1999) 121; K.C. Crellin, J.L. Beauchamp, S. Geribaldi, M. Decouzon, Organometallics 15 (1996) 5368; H.P. Chen, D.B. Jacobson, B.S. Freiser, J. Phys. Chem. A 103 (1999) 10884; Q. Chen, C. Sioma, S.Z. Kan, B.S. Freiser, Int. J. Mass Spectrom. 180 (1998) 231; Q. Chen, B.S. Freiser, J. Phys. Chem. A 102 (1998) 3343.
12. Recent, representative work: I. Kretzschmar, D. Schröder, H. Schwarz, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 5046; M. Brönstrup, C. Trage, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 122 (2000) 699; M. Diefenbach, M. Brönstrup, M. Aschi, D. Schröder, H. Schwarz, ibid. 121 (1999) 10614; M. Brönstrup, D. Schröder, H. Schwarz, Organometallics 18 (1999) 1939; G. Hornung, S. Bärsch, D.Schröder, H. Schwarz, ibid. 17 (1998) 2271; M. Aschi, M. Brönstrup, M. Diefenbach, J.N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. Int. Ed. Engl. 37 (1998) 829; A. Andersen, F. Muntean, D. Walter, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 692; M.T. Rodgers, P.B. Armentrout, ibid. 103 (1999) 4955; M.R. Sievers, P.B. Armentrout, Inorg. Chem. 38 (1999) 397; P.A.M. van Koppen, M.T. Bowers, C.L. Haynes, P.B. Armentrout, J. Am. Chem. Soc. 120 (1998) 5704; D. Walter, P.B. Armentrout, ibid. 120 (1998) 3176; S.W. Lee, S.B. Chang, D. Kossakovski, H. Cox, J.L. Beauchamp, ibid. 121 (1999) 10152; K.C. Crellin, J.L. Beauchamp, W.A. Goddard, S. Geribaldi, M. Decouzon, Int. J. Mass Spectrom. 183 (1999) 121; K.C. Crellin, J.L. Beauchamp, S. Geribaldi, M. Decouzon, Organometallics 15 (1996) 5368; H.P. Chen, D.B. Jacobson, B.S. Freiser, J. Phys. Chem. A 103 (1999) 10884; Q. Chen, C. Sioma, S.Z. Kan, B.S. Freiser, Int. J. Mass Spectrom. 180 (1998) 231; Q. Chen, B.S. Freiser, J. Phys. Chem. A 102 (1998) 3343.
13. Recent, representative work: I. Kretzschmar, D. Schröder, H. Schwarz, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 5046; M. Brönstrup, C. Trage, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 122 (2000) 699; M. Diefenbach, M. Brönstrup, M. Aschi, D. Schröder, H. Schwarz, ibid. 121 (1999) 10614; M. Brönstrup, D. Schröder, H. Schwarz, Organometallics 18 (1999) 1939; G. Hornung, S. Bärsch, D.Schröder, H. Schwarz, ibid. 17 (1998) 2271; M. Aschi, M. Brönstrup, M. Diefenbach, J.N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. Int. Ed. Engl. 37 (1998) 829; A. Andersen, F. Muntean, D. Walter, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 692; M.T. Rodgers, P.B. Armentrout, ibid. 103 (1999) 4955; M.R. Sievers, P.B. Armentrout, Inorg. Chem. 38 (1999) 397; P.A.M. van Koppen, M.T. Bowers, C.L. Haynes, P.B. Armentrout, J. Am. Chem. Soc. 120 (1998) 5704; D. Walter, P.B. Armentrout, ibid. 120 (1998) 3176; S.W. Lee, S.B. Chang, D. Kossakovski, H. Cox, J.L. Beauchamp, ibid. 121 (1999) 10152; K.C. Crellin, J.L. Beauchamp, W.A. Goddard, S. Geribaldi, M. Decouzon, Int. J. Mass Spectrom. 183 (1999) 121; K.C. Crellin, J.L. Beauchamp, S. Geribaldi, M. Decouzon, Organometallics 15 (1996) 5368; H.P. Chen, D.B. Jacobson, B.S. Freiser, J. Phys. Chem. A 103 (1999) 10884; Q. Chen, C. Sioma, S.Z. Kan, B.S. Freiser, Int. J. Mass Spectrom. 180 (1998) 231; Q. Chen, B.S. Freiser, J. Phys. Chem. A 102 (1998) 3343.
14. Recent, representative work: I. Kretzschmar, D. Schröder, H. Schwarz, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 5046; M. Brönstrup, C. Trage, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 122 (2000) 699; M. Diefenbach, M. Brönstrup, M. Aschi, D. Schröder, H. Schwarz, ibid. 121 (1999) 10614; M. Brönstrup, D. Schröder, H. Schwarz, Organometallics 18 (1999) 1939; G. Hornung, S. Bärsch, D.Schröder, H. Schwarz, ibid. 17 (1998) 2271; M. Aschi, M. Brönstrup, M. Diefenbach, J.N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. Int. Ed. Engl. 37 (1998) 829; A. Andersen, F. Muntean, D. Walter, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 692; M.T. Rodgers, P.B. Armentrout, ibid. 103 (1999) 4955; M.R. Sievers, P.B. Armentrout, Inorg. Chem. 38 (1999) 397; P.A.M. van Koppen, M.T. Bowers, C.L. Haynes, P.B. Armentrout, J. Am. Chem. Soc. 120 (1998) 5704; D. Walter, P.B. Armentrout, ibid. 120 (1998) 3176; S.W. Lee, S.B. Chang, D. Kossakovski, H. Cox, J.L. Beauchamp, ibid. 121 (1999) 10152; K.C. Crellin, J.L. Beauchamp, W.A. Goddard, S. Geribaldi, M. Decouzon, Int. J. Mass Spectrom. 183 (1999) 121; K.C. Crellin, J.L. Beauchamp, S. Geribaldi, M. Decouzon, Organometallics 15 (1996) 5368; H.P. Chen, D.B. Jacobson, B.S. Freiser, J. Phys. Chem. A 103 (1999) 10884; Q. Chen, C. Sioma, S.Z. Kan, B.S. Freiser, Int. J. Mass Spectrom. 180 (1998) 231; Q. Chen, B.S. Freiser, J. Phys. Chem. A 102 (1998) 3343.
15. Recent, representative work: I. Kretzschmar, D. Schröder, H. Schwarz, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 5046; M. Brönstrup, C. Trage, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 122 (2000) 699; M. Diefenbach, M. Brönstrup, M. Aschi, D. Schröder, H. Schwarz, ibid. 121 (1999) 10614; M. Brönstrup, D. Schröder, H. Schwarz, Organometallics 18 (1999) 1939; G. Hornung, S. Bärsch, D.Schröder, H. Schwarz, ibid. 17 (1998) 2271; M. Aschi, M. Brönstrup, M. Diefenbach, J.N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. Int. Ed. Engl. 37 (1998) 829; A. Andersen, F. Muntean, D. Walter, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 692; M.T. Rodgers, P.B. Armentrout, ibid. 103 (1999) 4955; M.R. Sievers, P.B. Armentrout, Inorg. Chem. 38 (1999) 397; P.A.M. van Koppen, M.T. Bowers, C.L. Haynes, P.B. Armentrout, J. Am. Chem. Soc. 120 (1998) 5704; D. Walter, P.B. Armentrout, ibid. 120 (1998) 3176; S.W. Lee, S.B. Chang, D. Kossakovski, H. Cox, J.L. Beauchamp, ibid. 121 (1999) 10152; K.C. Crellin, J.L. Beauchamp, W.A. Goddard, S. Geribaldi, M. Decouzon, Int. J. Mass Spectrom. 183 (1999) 121; K.C. Crellin, J.L. Beauchamp, S. Geribaldi, M. Decouzon, Organometallics 15 (1996) 5368; H.P. Chen, D.B. Jacobson, B.S. Freiser, J. Phys. Chem. A 103 (1999) 10884; Q. Chen, C. Sioma, S.Z. Kan, B.S. Freiser, Int. J. Mass Spectrom. 180 (1998) 231; Q. Chen, B.S. Freiser, J. Phys. Chem. A 102 (1998) 3343.
16. Recent, representative work: I. Kretzschmar, D. Schröder, H. Schwarz, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 5046; M. Brönstrup, C. Trage, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 122 (2000) 699; M. Diefenbach, M. Brönstrup, M. Aschi, D. Schröder, H. Schwarz, ibid. 121 (1999) 10614; M. Brönstrup, D. Schröder, H. Schwarz, Organometallics 18 (1999) 1939; G. Hornung, S. Bärsch, D.Schröder, H. Schwarz, ibid. 17 (1998) 2271; M. Aschi, M. Brönstrup, M. Diefenbach, J.N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. Int. Ed. Engl. 37 (1998) 829; A. Andersen, F. Muntean, D. Walter, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 692; M.T. Rodgers, P.B. Armentrout, ibid. 103 (1999) 4955; M.R. Sievers, P.B. Armentrout, Inorg. Chem. 38 (1999) 397; P.A.M. van Koppen, M.T. Bowers, C.L. Haynes, P.B. Armentrout, J. Am. Chem. Soc. 120 (1998) 5704; D. Walter, P.B. Armentrout, ibid. 120 (1998) 3176; S.W. Lee, S.B. Chang, D. Kossakovski, H. Cox, J.L. Beauchamp, ibid. 121 (1999) 10152; K.C. Crellin, J.L. Beauchamp, W.A. Goddard, S. Geribaldi, M. Decouzon, Int. J. Mass Spectrom. 183 (1999) 121; K.C. Crellin, J.L. Beauchamp, S. Geribaldi, M. Decouzon, Organometallics 15 (1996) 5368; H.P. Chen, D.B. Jacobson, B.S. Freiser, J. Phys. Chem. A 103 (1999) 10884; Q. Chen, C. Sioma, S.Z. Kan, B.S. Freiser, Int. J. Mass Spectrom. 180 (1998) 231; Q. Chen, B.S. Freiser, J. Phys. Chem. A 102 (1998) 3343.
17. Recent, representative work: I. Kretzschmar, D. Schröder, H. Schwarz, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 5046; M. Brönstrup, C. Trage, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 122 (2000) 699; M. Diefenbach, M. Brönstrup, M. Aschi, D. Schröder, H. Schwarz, ibid. 121 (1999) 10614; M. Brönstrup, D. Schröder, H. Schwarz, Organometallics 18 (1999) 1939; G. Hornung, S. Bärsch, D.Schröder, H. Schwarz, ibid. 17 (1998) 2271; M. Aschi, M. Brönstrup, M. Diefenbach, J.N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. Int. Ed. Engl. 37 (1998) 829; A. Andersen, F. Muntean, D. Walter, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 692; M.T. Rodgers, P.B. Armentrout, ibid. 103 (1999) 4955; M.R. Sievers, P.B. Armentrout, Inorg. Chem. 38 (1999) 397; P.A.M. van Koppen, M.T. Bowers, C.L. Haynes, P.B. Armentrout, J. Am. Chem. Soc. 120 (1998) 5704; D. Walter, P.B. Armentrout, ibid. 120 (1998) 3176; S.W. Lee, S.B. Chang, D. Kossakovski, H. Cox, J.L. Beauchamp, ibid. 121 (1999) 10152; K.C. Crellin, J.L. Beauchamp, W.A. Goddard, S. Geribaldi, M. Decouzon, Int. J. Mass Spectrom. 183 (1999) 121; K.C. Crellin, J.L. Beauchamp, S. Geribaldi, M. Decouzon, Organometallics 15 (1996) 5368; H.P. Chen, D.B. Jacobson, B.S. Freiser, J. Phys. Chem. A 103 (1999) 10884; Q. Chen, C. Sioma, S.Z. Kan, B.S. Freiser, Int. J. Mass Spectrom. 180 (1998) 231; Q. Chen, B.S. Freiser, J. Phys. Chem. A 102 (1998) 3343.
18. Recent, representative work: I. Kretzschmar, D. Schröder, H. Schwarz, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 5046; M. Brönstrup, C. Trage, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 122 (2000) 699; M. Diefenbach, M. Brönstrup, M. Aschi, D. Schröder, H. Schwarz, ibid. 121 (1999) 10614; M. Brönstrup, D. Schröder, H. Schwarz, Organometallics 18 (1999) 1939; G. Hornung, S. Bärsch, D.Schröder, H. Schwarz, ibid. 17 (1998) 2271; M. Aschi, M. Brönstrup, M. Diefenbach, J.N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. Int. Ed. Engl. 37 (1998) 829; A. Andersen, F. Muntean, D. Walter, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 692; M.T. Rodgers, P.B. Armentrout, ibid. 103 (1999) 4955; M.R. Sievers, P.B. Armentrout, Inorg. Chem. 38 (1999) 397; P.A.M. van Koppen, M.T. Bowers, C.L. Haynes, P.B. Armentrout, J. Am. Chem. Soc. 120 (1998) 5704; D. Walter, P.B. Armentrout, ibid. 120 (1998) 3176; S.W. Lee, S.B. Chang, D. Kossakovski, H. Cox, J.L. Beauchamp, ibid. 121 (1999) 10152; K.C. Crellin, J.L. Beauchamp, W.A. Goddard, S. Geribaldi, M. Decouzon, Int. J. Mass Spectrom. 183 (1999) 121; K.C. Crellin, J.L. Beauchamp, S. Geribaldi, M. Decouzon, Organometallics 15 (1996) 5368; H.P. Chen, D.B. Jacobson, B.S. Freiser, J. Phys. Chem. A 103 (1999) 10884; Q. Chen, C. Sioma, S.Z. Kan, B.S. Freiser, Int. J. Mass Spectrom. 180 (1998) 231; Q. Chen, B.S. Freiser, J. Phys. Chem. A 102 (1998) 3343.
19. Recent, representative work: I. Kretzschmar, D. Schröder, H. Schwarz, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 5046; M. Brönstrup, C. Trage, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 122 (2000) 699; M. Diefenbach, M. Brönstrup, M. Aschi, D. Schröder, H. Schwarz, ibid. 121 (1999) 10614; M. Brönstrup, D. Schröder, H. Schwarz, Organometallics 18 (1999) 1939; G. Hornung, S. Bärsch, D.Schröder, H. Schwarz, ibid. 17 (1998) 2271; M. Aschi, M. Brönstrup, M. Diefenbach, J.N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. Int. Ed. Engl. 37 (1998) 829; A. Andersen, F. Muntean, D. Walter, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 692; M.T. Rodgers, P.B. Armentrout, ibid. 103 (1999) 4955; M.R. Sievers, P.B. Armentrout, Inorg. Chem. 38 (1999) 397; P.A.M. van Koppen, M.T. Bowers, C.L. Haynes, P.B. Armentrout, J. Am. Chem. Soc. 120 (1998) 5704; D. Walter, P.B. Armentrout, ibid. 120 (1998) 3176; S.W. Lee, S.B. Chang, D. Kossakovski, H. Cox, J.L. Beauchamp, ibid. 121 (1999) 10152; K.C. Crellin, J.L. Beauchamp, W.A. Goddard, S. Geribaldi, M. Decouzon, Int. J. Mass Spectrom. 183 (1999) 121; K.C. Crellin, J.L. Beauchamp, S. Geribaldi, M. Decouzon, Organometallics 15 (1996) 5368; H.P. Chen, D.B. Jacobson, B.S. Freiser, J. Phys. Chem. A 103 (1999) 10884; Q. Chen, C. Sioma, S.Z. Kan, B.S. Freiser, Int. J. Mass Spectrom. 180 (1998) 231; Q. Chen, B.S. Freiser, J. Phys. Chem. A 102 (1998) 3343.
20. Recent, representative work: I. Kretzschmar, D. Schröder, H. Schwarz, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 5046; M. Brönstrup, C. Trage, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 122 (2000) 699; M. Diefenbach, M. Brönstrup, M. Aschi, D. Schröder, H. Schwarz, ibid. 121 (1999) 10614; M. Brönstrup, D. Schröder, H. Schwarz, Organometallics 18 (1999) 1939; G. Hornung, S. Bärsch, D.Schröder, H. Schwarz, ibid. 17 (1998) 2271; M. Aschi, M. Brönstrup, M. Diefenbach, J.N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. Int. Ed. Engl. 37 (1998) 829; A. Andersen, F. Muntean, D. Walter, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 692; M.T. Rodgers, P.B. Armentrout, ibid. 103 (1999) 4955; M.R. Sievers, P.B. Armentrout, Inorg. Chem. 38 (1999) 397; P.A.M. van Koppen, M.T. Bowers, C.L. Haynes, P.B. Armentrout, J. Am. Chem. Soc. 120 (1998) 5704; D. Walter, P.B. Armentrout, ibid. 120 (1998) 3176; S.W. Lee, S.B. Chang, D. Kossakovski, H. Cox, J.L. Beauchamp, ibid. 121 (1999) 10152; K.C. Crellin, J.L. Beauchamp, W.A. Goddard, S. Geribaldi, M. Decouzon, Int. J. Mass Spectrom. 183 (1999) 121; K.C. Crellin, J.L. Beauchamp, S. Geribaldi, M. Decouzon, Organometallics 15 (1996) 5368; H.P. Chen, D.B. Jacobson, B.S. Freiser, J. Phys. Chem. A 103 (1999) 10884; Q. Chen, C. Sioma, S.Z. Kan, B.S. Freiser, Int. J. Mass Spectrom. 180 (1998) 231; Q. Chen, B.S. Freiser, J. Phys. Chem. A 102 (1998) 3343.
21. Recent, representative work: I. Kretzschmar, D. Schröder, H. Schwarz, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 5046; M. Brönstrup, C. Trage, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 122 (2000) 699; M. Diefenbach, M. Brönstrup, M. Aschi, D. Schröder, H. Schwarz, ibid. 121 (1999) 10614; M. Brönstrup, D. Schröder, H. Schwarz, Organometallics 18 (1999) 1939; G. Hornung, S. Bärsch, D.Schröder, H. Schwarz, ibid. 17 (1998) 2271; M. Aschi, M. Brönstrup, M. Diefenbach, J.N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. Int. Ed. Engl. 37 (1998) 829; A. Andersen, F. Muntean, D. Walter, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 692; M.T. Rodgers, P.B. Armentrout, ibid. 103 (1999) 4955; M.R. Sievers, P.B. Armentrout, Inorg. Chem. 38 (1999) 397; P.A.M. van Koppen, M.T. Bowers, C.L. Haynes, P.B. Armentrout, J. Am. Chem. Soc. 120 (1998) 5704; D. Walter, P.B. Armentrout, ibid. 120 (1998) 3176; S.W. Lee, S.B. Chang, D. Kossakovski, H. Cox, J.L. Beauchamp, ibid. 121 (1999) 10152; K.C. Crellin, J.L. Beauchamp, W.A. Goddard, S. Geribaldi, M. Decouzon, Int. J. Mass Spectrom. 183 (1999) 121; K.C. Crellin, J.L. Beauchamp, S. Geribaldi, M. Decouzon, Organometallics 15 (1996) 5368; H.P. Chen, D.B. Jacobson, B.S. Freiser, J. Phys. Chem. A 103 (1999) 10884; Q. Chen, C. Sioma, S.Z. Kan, B.S. Freiser, Int. J. Mass Spectrom. 180 (1998) 231; Q. Chen, B.S. Freiser, J. Phys. Chem. A 102 (1998) 3343.
22. Recent, representative work: I. Kretzschmar, D. Schröder, H. Schwarz, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 5046; M. Brönstrup, C. Trage, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 122 (2000) 699; M. Diefenbach, M. Brönstrup, M. Aschi, D. Schröder, H. Schwarz, ibid. 121 (1999) 10614; M. Brönstrup, D. Schröder, H. Schwarz, Organometallics 18 (1999) 1939; G. Hornung, S. Bärsch, D.Schröder, H. Schwarz, ibid. 17 (1998) 2271; M. Aschi, M. Brönstrup, M. Diefenbach, J.N. Harvey, D. Schröder, H. Schwarz, Angew. Chem. Int. Ed. Engl. 37 (1998) 829; A. Andersen, F. Muntean, D. Walter, C. Rue, P.B. Armentrout, J. Phys. Chem. A 104 (2000) 692; M.T. Rodgers, P.B. Armentrout, ibid. 103 (1999) 4955; M.R. Sievers, P.B. Armentrout, Inorg. Chem. 38 (1999) 397; P.A.M. van Koppen, M.T. Bowers, C.L. Haynes, P.B. Armentrout, J. Am. Chem. Soc. 120 (1998) 5704; D. Walter, P.B. Armentrout, ibid. 120 (1998) 3176; S.W. Lee, S.B. Chang, D. Kossakovski, H. Cox, J.L. Beauchamp, ibid. 121 (1999) 10152; K.C. Crellin, J.L. Beauchamp, W.A. Goddard, S. Geribaldi, M. Decouzon, Int. J. Mass Spectrom. 183 (1999) 121; K.C. Crellin, J.L. Beauchamp, S. Geribaldi, M. Decouzon, Organometallics 15 (1996) 5368; H.P. Chen, D.B. Jacobson, B.S. Freiser, J. Phys. Chem. A 103 (1999) 10884; Q. Chen, C. Sioma, S.Z. Kan, B.S. Freiser, Int. J. Mass Spectrom. 180 (1998) 231; Q. Chen, B.S. Freiser, J. Phys. Chem. A 102 (1998) 3343.
23. Cole R.B. Electrospray Ionization Mass Spectrometry. 1997;Wiley, New York.
24. Biochemical and Biotechnological Applications of Electrospray Ionization Mass Spectrometry, A.P. Snyder (Ed.), ACS. Symp. Ser. 619 (1995).
25. A good overview of applications of ESMS to the analysis of biomacromolecules can be found in: M. Przybylski, M.O. Glocker, Angew. Chem. Int. Ed. Engl. 35 (1996) 806.
26. Bailey A.G. Electrostatic Spraying of Liquids. 1988;Research Studies Press, Taunton, Somerset, UK.
27. In contrast to Dole's "charge residual model" (CRM), a different mechanism for the last stage of free ion formation in the electrospray process, the so-called "ion evaporation model" (IEM), was proposed in J.V. Iribarne, B.A. Thomson, J. Chem. Phys. 64 (1976) 2287; B.A. Thomson, J.V. Iribarne, ibid. 71 (1979) 4451. For a discussion of the current view on the mechanism of ion formation in electrospray, see: J.B. Fenn, J. Rosell, T. Nohmi, S. Shen, F.J. Banks Jr., Electrospray Ion Formation: Desorption Versus Desertion, in [8], p.60; P. Kebarle, Y. Ho, On the Mechanism of Electrospray Mass Spectrometry, in [7], p.3.
28. In contrast to Dole's "charge residual model" (CRM), a different mechanism for the last stage of free ion formation in the electrospray process, the so-called "ion evaporation model" (IEM), was proposed in J.V. Iribarne, B.A. Thomson, J. Chem. Phys. 64 (1976) 2287; B.A. Thomson, J.V. Iribarne, ibid. 71 (1979) 4451. For a discussion of the current view on the mechanism of ion formation in electrospray, see: J.B. Fenn, J. Rosell, T. Nohmi, S. Shen, F.J. Banks Jr., Electrospray Ion Formation: Desorption Versus Desertion, in [8], p.60; P. Kebarle, Y. Ho, On the Mechanism of Electrospray Mass Spectrometry, in [7], p.3.
29. In contrast to Dole's "charge residual model" (CRM), a different mechanism for the last stage of free ion formation in the electrospray process, the so-called "ion evaporation model" (IEM), was proposed in J.V. Iribarne, B.A. Thomson, J. Chem. Phys. 64 (1976) 2287; B.A. Thomson, J.V. Iribarne, ibid. 71 (1979) 4451. For a discussion of the current view on the mechanism of ion formation in electrospray, see: J.B. Fenn, J. Rosell, T. Nohmi, S. Shen, F.J. Banks Jr., Electrospray Ion Formation: Desorption Versus Desertion, in [8], p.60; P. Kebarle, Y. Ho, On the Mechanism of Electrospray Mass Spectrometry, in [7], p.3.
30. In contrast to Dole's "charge residual model" (CRM), a different mechanism for the last stage of free ion formation in the electrospray process, the so-called "ion evaporation model" (IEM), was proposed in J.V. Iribarne, B.A. Thomson, J. Chem. Phys. 64 (1976) 2287; B.A. Thomson, J.V. Iribarne, ibid. 71 (1979) 4451. For a discussion of the current view on the mechanism of ion formation in electrospray, see: J.B. Fenn, J. Rosell, T. Nohmi, S. Shen, F.J. Banks Jr., Electrospray Ion Formation: Desorption Versus Desertion, in [8], p.60; P. Kebarle, Y. Ho, On the Mechanism of Electrospray Mass Spectrometry, in [7], p.3.
31. Dole M., Hines R.L., Mack L.L., Mobley R.C., Ferguson L.D., Alice M.B. Macromolecules. 1:1968;96.
32. Dole M., Mack L.L., Hines R.L., Mobley R.C., Ferguson L.D., Alice M.B. J. Chem. Phys. 49:1968;2240.
33. Mack L.L., Kralik P., Rheude A., Dole M. J. Chem. Phys. 52:1970;4977.
34. Clegg G.A., Dole M. Biopolymers. 10:1971;821.
35. A very personal account of the route to electrospray mass spectrometry was published by J. B. Fenn as a foreword to a recent monograph, see [7].
36. Yamashita M., Fenn J.B. J. Phys. Chem. 88:1984;4451.
37. Yamashita M., Fenn J.B. J. Phys. Chem. 88:1984;4671.
38. Whitehouse C.M., Dreyer R.N., Yamashita M., Fenn J.B. Anal. Chem. 57:1985;675.
39. Fenn J.B., Mann M., Meng C.K., Wong S.F., Whitehouse C.M. Science. 246:1989;64.
40. Katta V., Chowdhury S.K., Chait B.T. J. Am. Chem. Soc. 112:1990;5348.
41. R. Colton, A. D'Agostino, J.C. Traeger, Mass Spectrom. Rev. 14 (1995) 79, and references cited therein.
42. Henderson W., Nicholson B.K., McCaffrey L.J. Polyhedron. 17:1998;4291.
43. (a) T.G. Spence, T.D. Burns, L.A. Posey, J. Phys. Chem. A 101 (1997) 139
44. (b) T.G. Spence, T.D. Burns, G.B. Guckenberger, L.A. Posey, ibid. 101 (1997) 1081;
45. (c) T.G. Spence, B.T. Trotter, T.D. Burns, L.A. Posey, ibid. 102 (1998) 6101.
46. Arndtsen B.A., Bergman R.G., Mobley T.A., Petersen T.H. Acc. Chem. Res. 28:1995;154.
47. A.H. Janowicz, R.G. Bergman, J. Am. Chem. Soc. 104 (1982) 352; W.D. Jones, F.J. Feher, ibid. 106 (1984) 1650; J.K. Hoyano, A.D. McMaster, W.A.G. Graham, ibid. 105 (1983) 7190.
48. A.H. Janowicz, R.G. Bergman, J. Am. Chem. Soc. 104 (1982) 352; W.D. Jones, F.J. Feher, ibid. 106 (1984) 1650; J.K. Hoyano, A.D. McMaster, W.A.G. Graham, ibid. 105 (1983) 7190.
49. A.H. Janowicz, R.G. Bergman, J. Am. Chem. Soc. 104 (1982) 352; W.D. Jones, F.J. Feher, ibid. 106 (1984) 1650; J.K. Hoyano, A.D. McMaster, W.A.G. Graham, ibid. 105 (1983) 7190.
50. P. Burger, R.G. Bergman, J. Am. Chem. Soc. 115 (1993) 10462; B.A. Arndtsen, R.G. Bergman, Science 270 (1995) 1970; J.E. Veltheer, P. Burger, R.G. Bergman, J. Am. Chem. Soc. 117 (1995) 12478.
51. P. Burger, R.G. Bergman, J. Am. Chem. Soc. 115 (1993) 10462; B.A. Arndtsen, R.G. Bergman, Science 270 (1995) 1970; J.E. Veltheer, P. Burger, R.G. Bergman, J. Am. Chem. Soc. 117 (1995) 12478.
52. P. Burger, R.G. Bergman, J. Am. Chem. Soc. 115 (1993) 10462; B.A. Arndtsen, R.G. Bergman, Science 270 (1995) 1970; J.E. Veltheer, P. Burger, R.G. Bergman, J. Am. Chem. Soc. 117 (1995) 12478.
53. Strout D.L., Zaric S., Niu S., Hall M.B. J. Am. Chem. Soc. 118:1996;6068.
54. Hinderling C., Plattner D.A., Chen P. Angew. Chem. Int. Ed. Engl. 36:1997;243.
55. Hinderling C., Feichtinger D., Plattner D.A., Chen P. J. Am. Chem. Soc. 119:1997;10793.
56. Luecke H.F., Bergman R.G. J. Am. Chem. Soc. 119:1997;11538.
57. (a) T.L. Siddall, N. Miyaura, J.C. Huffman, J.K. Kochi, J. Chem. Soc., Chem. Commun. (1983) 1185;
58. (b) E.G. Samsel, K. Srinivasan, J.K. Kochi, J. Am. Chem. Soc. 107 (1985) 7606;
59. (c) K. Srinivasan, J.K. Kochi, Inorg. Chem. 24 (1985) 4671;
60. (d) K. Srinivasan, P. Michaud, J.K. Kochi, J. Am. Chem. Soc. 108 (1986) 2309;
61. (e) K. Srinivasan, S. Perrier, J.K. Kochi, J. Mol. Cat. 36 (1986) 297.
62. Groves J.T., Kruper W.J. J. Am. Chem. Soc. 101:1979;7613.
63. Zhang W., Loebach J.L., Wilson S.R., Jacobsen E.N. J. Am. Chem. Soc. 112:1990;2801.
64. Irie R., Noda K., Ito Y., Matsumoto N., Katsuki T. Tetrahedron Lett. 31:1990;7345.
65. Feichtinger D., Plattner D.A. Angew. Chem. Int. Ed. Engl. 36:1997;1718.
66. Feichtinger D., Plattner D.A. J. Chem. Soc.,Perkin Trans. 2:2000;1023.
67. Plattner D.A., Feichtinger D., El-Bahraoui J., Wiest O. Int. J. Mass Spectrom. 195/196:2000;351.
68. Feichtinger D., Plattner D.A. Chem. Eur. J. 7:2001;591.
69. A similar method that translates kinetic branching ratios into thermochemical data in cases where the difference of entropy change between two different fragmentation pathways can be neglected was introduced by Cooks. The assumptions inherent in the "Cooks' kinetic method" are essentially the same as those required for linear free energy relationships, i.e. Hammett σρ correlations. The kinetic method has been widely used for the determination of proton affinities and gas-phase basicities of many organic compounds, yielding values in excellent agreement with independent methods: R.G. Cooks, J.S. Patrick, T. Kotiaho, S.A. McLuckey, Mass Spectrom. Rev. 13 (1994) 287; R.G. Cooks, P.S.H. Wong, Acc. Chem. Res. 31 (1998) 379, and references cited therein.
70. A similar method that translates kinetic branching ratios into thermochemical data in cases where the difference of entropy change between two different fragmentation pathways can be neglected was introduced by Cooks. The assumptions inherent in the "Cooks' kinetic method" are essentially the same as those required for linear free energy relationships, i.e. Hammett σρ correlations. The kinetic method has been widely used for the determination of proton affinities and gas-phase basicities of many organic compounds, yielding values in excellent agreement with independent methods: R.G. Cooks, J.S. Patrick, T. Kotiaho, S.A. McLuckey, Mass Spectrom. Rev. 13 (1994) 287; R.G. Cooks, P.S.H. Wong, Acc. Chem. Res. 31 (1998) 379, and references cited therein.
71. Brown H.C., Okamoto Y. J. Am. Chem. Soc. 80:1958;4979.
72. Fink G., Mülhaupt R., Brintzinger H.H. Ziegler Catalysts. 1995;Springer, New York.
73. R.F. Jordan, W.E. Dasher, S.F. Echols, J. Am. Chem. Soc. 108 (1986) 1718; R.F. Jordan, C.S. Bajgur, R. Willett, B. Scott, ibid. 108 (1986) 7410.
74. R.F. Jordan, W.E. Dasher, S.F. Echols, J. Am. Chem. Soc. 108 (1986) 1718; R.F. Jordan, C.S. Bajgur, R. Willett, B. Scott, ibid. 108 (1986) 7410.
75. Brintzinger H.H., Fischer D., Mülhaupt R., Rieger B., Waymouth R. Angew. Chem. Int. Ed. Engl. 34:1995;1143.
76. C.S. Christ, J.R. Eyler, D.E. Richardson, J. Am. Chem. Soc. 110 (1988) 4038; 112 (1990) 596; D.E. Richardson, N.G. Alameddin, M.F. Ryan, T. Hayes, J.R. Eyler, A.R. Siedle, ibid. 118 (1996) 11244.
77. C.S. Christ, J.R. Eyler, D.E. Richardson, J. Am. Chem. Soc. 110 (1988) 4038; 112 (1990) 596; D.E. Richardson, N.G. Alameddin, M.F. Ryan, T. Hayes, J.R. Eyler, A.R. Siedle, ibid. 118 (1996) 11244.
78. C.S. Christ, J.R. Eyler, D.E. Richardson, J. Am. Chem. Soc. 110 (1988) 4038; 112 (1990) 596; D.E. Richardson, N.G. Alameddin, M.F. Ryan, T. Hayes, J.R. Eyler, A.R. Siedle, ibid. 118 (1996) 11244.
79. Feichtinger D., Plattner D.A., Chen P. J. Am. Chem. Soc. 120:1998;7125.
80. Chien J.C.W., Wang B.P. J. Polym. Sci. 28:(Part A):1990;15.
81. Martinho Simões J.A., Beauchamp J.L. Chem. Rev. 90:1990;629.
82. P.B Armentrout, Thermochemical Measurements by Guided Ion Beam Mass Spectrometry, in N. Adams, L.M. Babcock (Eds.), Advances in Gas Phase Ion Chemistry, JAI Press, Greenwich, CT, 1992, Vol. 1, p 83, and references cited therein.
83. K.M. Ervin, P.B. Armentrout, J. Chem. Phys. 83 (1985) 166; S.K. Loh, D.A. Hales, L. Lian, P.B. Armentrout, ibid. 90 (1989) 5466; R.H. Schultz, P.B. Armentrout, Int. J. Mass Spectrom. Ion Processes 107 (1991) 29; N.F. Dalleska, K. Honma, L.S. Sunderlin, P.B. Armentrout, J. Am. Chem. Soc. 116 (1994) 3519; M.T. Rodgers, K.M. Ervin, P.B. Armentrout, J. Chem. Phys. 106 (1997) 4499.
84. K.M. Ervin, P.B. Armentrout, J. Chem. Phys. 83 (1985) 166; S.K. Loh, D.A. Hales, L. Lian, P.B. Armentrout, ibid. 90 (1989) 5466; R.H. Schultz, P.B. Armentrout, Int. J. Mass Spectrom. Ion Processes 107 (1991) 29; N.F. Dalleska, K. Honma, L.S. Sunderlin, P.B. Armentrout, J. Am. Chem. Soc. 116 (1994) 3519; M.T. Rodgers, K.M. Ervin, P.B. Armentrout, J. Chem. Phys. 106 (1997) 4499.
85. K.M. Ervin, P.B. Armentrout, J. Chem. Phys. 83 (1985) 166; S.K. Loh, D.A. Hales, L. Lian, P.B. Armentrout, ibid. 90 (1989) 5466; R.H. Schultz, P.B. Armentrout, Int. J. Mass Spectrom. Ion Processes 107 (1991) 29; N.F. Dalleska, K. Honma, L.S. Sunderlin, P.B. Armentrout, J. Am. Chem. Soc. 116 (1994) 3519; M.T. Rodgers, K.M. Ervin, P.B. Armentrout, J. Chem. Phys. 106 (1997) 4499.
86. K.M. Ervin, P.B. Armentrout, J. Chem. Phys. 83 (1985) 166; S.K. Loh, D.A. Hales, L. Lian, P.B. Armentrout, ibid. 90 (1989) 5466; R.H. Schultz, P.B. Armentrout, Int. J. Mass Spectrom. Ion Processes 107 (1991) 29; N.F. Dalleska, K. Honma, L.S. Sunderlin, P.B. Armentrout, J. Am. Chem. Soc. 116 (1994) 3519; M.T. Rodgers, K.M. Ervin, P.B. Armentrout, J. Chem. Phys. 106 (1997) 4499.
87. K.M. Ervin, P.B. Armentrout, J. Chem. Phys. 83 (1985) 166; S.K. Loh, D.A. Hales, L. Lian, P.B. Armentrout, ibid. 90 (1989) 5466; R.H. Schultz, P.B. Armentrout, Int. J. Mass Spectrom. Ion Processes 107 (1991) 29; N.F. Dalleska, K. Honma, L.S. Sunderlin, P.B. Armentrout, J. Am. Chem. Soc. 116 (1994) 3519; M.T. Rodgers, K.M. Ervin, P.B. Armentrout, J. Chem. Phys. 106 (1997) 4499.
88. Dalleska N.F., Honma K., Armentrout P.B. J. Am. Chem. Soc. 115:1993;12125.
89. P. Armentrout, pivate communication.
90. Anderson S.G., Blades A.T., Klassen J., Kebarle P. Int. J. Mass Spectrom. Ion Processes. 141:1995;217.
91. C. Hinderling, D.A. Plattner, unpublished results.
92. Holbrook K.A., Pilling M.J., Robertson S.H. Unimolecular Reactions. 1996;Wiley, Chichester.
93. R.H. Schultz, K.C. Crellin, P.B. Armentrout, J. Am. Chem. Soc. 113 (1991) 8590; F.A. Khan, D.E. Clemmer, R.H. Schultz, P.B. Armentrout, J. Phys. Chem. 97 (1993) 7978.
94. R.H. Schultz, K.C. Crellin, P.B. Armentrout, J. Am. Chem. Soc. 113 (1991) 8590; F.A. Khan, D.E. Clemmer, R.H. Schultz, P.B. Armentrout, J. Phys. Chem. 97 (1993) 7978.
95. Sunderlin L.S., Wang D., Squires R.R. J. Am. Chem. Soc. 115:1993;12060.
96. Kim Y.-M., Chen P. Int. J. Mass Spectrom. 202:2000;1.
97. Klassen J.S., Anderson S.G., Blades A.T., Kebarle P. J. Phys. Chem. 100:1996;14218.