Reactions of platinum-carbene clusters PtnCH2+ (n = 1-5) with O2, CH4, NH3, and H2O: Coupling processes versus carbide formation

Organometallics

Volumn 22, Issue 19, 2003, Pages 3809-3819

  Koszinowski, Konrad ^a   Schröder, Detlef ^a   Schwarz, Helmut ^a  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

GAS PHASE REACTIONS; METHANE FUNCTIONALIZATION; PLATINUM CARBENE CLUSTERS;

CATALYSIS; CATALYSTS; CHEMICAL BONDS; CRYSTAL LATTICES; DISSOCIATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; ISOTOPES; MASS SPECTROMETRY; PLATINUM COMPOUNDS; REACTION KINETICS; SUBSTRATES;

ORGANOMETALLICS;

EID: 0141842563     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om030272l     Document Type: Article

References (44)

1. Chem. Eng. News 1993 (May 31), 71, 27.
2. Muehlhofer, M.; Strassner, T.; Herrmann, W. A. Angew. Chem. 2002, 114, 1817
3. Muehlhofer, M.; Strassner, T.; Herrmann, W. A. Angew. Chem., Int. Ed. 2002, 41, 1745.
4. Fokin, A. A.; Schreiner, P. R. Chem. Rev. 2002, 102, 1551.
5. Litorja, M.; Ruscic, B. J. Chem. Phys. 1997, 107, 9852.
6. Labinger, J. A.; Bercaw, J. E. Nature 2002, 417, 507.
7. Schwarz, H.; Schröder, D. Pure Appl. Chem. 2000, 72, 2319.
8. Periana, R. A.; Taube, D. J.; Gamble, S.; Taube, H.; Satoh, T.; Fujii, H. Science 1998, 280, 560.
9. Hasenberg, D.; Schmidt, L. D. J. Catal. 1986, 97, 156.
10. Hasenberg, D.; Schmidt, L. D. J. Catal. 1987, 104, 441.
11. Waletzko, N.; Schmidt, L. D. AIChE J. 1988, 34, 1146.
12. Bockholt, A.; Harding, I. S.; Nix, R. M. J. Chem. Soc., Faraday Trans. 1997, 93, 3869.
13. Eller, K.; Schwarz, H. Chem. Rev. 1991, 91, 1121.
14. (a) Aschi, M.; Brönstrup, M.; Diefenbach, M.; Harvey, J. N.; Schröder, D.; Schwarz, H. Angew. Chem. 1998, 110, 858
15. Aschi, M.; Brönstrup, M.; Diefenbach, M.; Harvey, J. N.; Schröder, D.; Schwarz, H. Angew. Chem., Int. Ed. 1998, 37, 829.
16. -1, see: Liyanage, R.; Styles, M. L.; O'Hair, R. A. J.; Armentrout, P. B. Int. J. Mass Spectrom. 2003, 227, 47.
17. Diefenbach, M.; Brönstrup, M.; Aschi, M.; Schröder, D.; Schwarz, H. J. Am. Chem. Soc. 1999, 121, 10614.
18. Irikura, K. K.; Beauchamp, J. L. J. Phys. Chem. 1991, 95, 8344.
19. Brönstrup, M.; Schröder, D.; Schwarz, H. Organometallics 1999, 18, 1939.
20. Kaldor, A.; Cox, D. M. Pure Appl. Chem. 1990, 62, 79.
21. Achatz, U.; Berg, C.; Joos, S.; Fox, B. S.; Beyer, M. K.; Niedner-Schatteburg, G.; Bondybey, V. E. Chem. Phys. Lett. 2000, 320, 53.
22. Koszinowski, K.; Schröder, D.; Schwarz, H. J. Phys. Chem. A 2003, 107, 4999.
23. Koszinowski, K.; Schröder, D.; Schwarz, H. J. Am. Chem. Soc. 2003, 125, 3676.
24. http://webbook.nist.gov/chemistry/.
25. Taylor, S.; Lemire, G. W.; Hamrick, Y. M.; Fu, Z.; Morse, M. D. J. Chem. Phys. 1988, 89, 5517.
26. Wesendrup, R.; Schröder, D.; Schwarz, H. Angew. Chem. 1994, 106, 1232
27. Wesendrup, R.; Schröder, D.; Schwarz, H. Angew. Chem., Int. Ed. Engl. 1994, 33, 1174.
28. Pavlov, M.; Blomberg, M. R. A.; Siegbahn, P. E. M.; Wesendrup, R.; Heinemann, C.; Schwarz, H. J. Phys. Chem. A 1997, 101, 1567.
29. Zhang, X.-G.; Liyanage, R.; Armentrout, P. B. J. Am. Chem. Soc. 2001, 123, 5563.
30. Lias, S. G.; Bartmess, J. E.; Liebman, J. F.; Holmes, J. L.; Levin, R. D.; Mallard, W. G. J. Phys. Chem. Ref. Data Ser. 1988, 17, Suppl. 1.
31. Zhang, X.-G., Armentrout, P. B. Organometallics 2001, 20, 4266.
32. Forzatti, P.; Lietti, L. Catal. Today 1999, 52, 165.
33. Eller, K.; Schwarz, H. Int. J. Mass Spectrom. Ion Processes 1989, 93, 243.
34. Eller, K.; Zummack, W.; Zummack, W.; Schwarz, H. J. Am. Chem. Soc. 1990, 112, 621.
35. Engeser, M.; Weiske, T.; Schröder, D.; Schwarz, H. J. Phys. Chem. A 2003, 107, 2855.
36. Maruyama, S.; Anderson, L. R.; Smalley, R. E. Rev. Sci. Instrum. 1990, 61, 3686.
37. Berg, C.; Schindler, T.; Kantlehner, M.; Niedner-Schatteburg, G.; Bondybey, V. E. Chem. Phys. 2000, 262, 143.
38. 198Pt+.
39. Forbes, R. A.; Laukien, F. H.; Wronka, J. Int. J. Mass Spectrom. Ion Processes 1988, 83, 23.
40. 2 was prepared by dehydration of malonic acid; see: Beyer, H.; Walter, W. Lehrbuch der Organischen Chemie, 22th ed.; Hirzel: Stuttgart, Germany, 1991.
41. Schröder, D.; Schwarz, H.; Clemmer, D. E.; Chen, Y.-M.; Armentrout, P. B.; Baranov, V. I.; Böhme, D. K. Int. J. Mass Spectrom. Ion Processes 1997, 161, 175.
42. Mazurek, U.; Schwarz, H. ICR Kinetics, version 3.0.1, Technische Universität Berlin, 1998.
43. Mazurek, U. Dissertation, TU Berlin, D83, 2002.
44. Sievers, H. L.; Grützmacher, H.-F.; Caravatti, P. Int. J. Mass Spectrom. Ion Processes 1996, 157/158, 233.