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A molybdenum(VI) trioxide-based catalyst or a metallic silver catalyst is used. About 70% of newly installed production capacity uses the former. The heterogeneous catalysis is typically carried out at atmospheric pressure and 300-400°C with atmospheric dioxygen as the oxidant. High methanol conversion (>99%) and selectivity for formaldehyde (>95%) can be achieved. ibid.
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0242559509
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Alcohol acidities are from: http://webbook.nist.gov/chemistry/.
-
-
-
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72
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0242475748
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note
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Alcohol is present in the ion trap during all stages of a multistage experiment. If alcohol is used in initial reactions of the catalytic cycle (e.g., reaction 1) it remains present during later reactions.
-
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-
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76
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0242644170
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note
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A very small amount of alkene loss is also observed from dimolybdate centres with straight chain alkoxo ligands. This typically represents less than 2% of the amount of aldehyde loss.
-
-
-
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77
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0039479067
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We adopt the notation whereby the first carbon of the alkoxo ligand is denoted as the α-carbon
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Westheimer, F. H. Chem. Rev. 1949, 45, 419. We adopt the notation whereby the first carbon of the alkoxo ligand is denoted as the α-carbon.
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Westheimer, F.H.1
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78
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0242559508
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note
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-, suggesting a crude estimate for the KIE of this reaction of 6.
-
-
-
-
80
-
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0037080141
-
-
-. This ion could not be mass selected in the ion trap instrument, presumably due to its 'fragile' nature (consistent with the observation of 'peak fronting' for this species, see: McClellan, J. E.; Murphy, J. P., III.; Mulholland, J. J.; Yost, R. A. Anal. Chem. 2002, 74, 402).
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McClellan, J.E.1
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81
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0242475747
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note
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-1 s-1.
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82
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0242559506
-
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note
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- (Figure 6).
-
-
-
-
83
-
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0242644169
-
-
note
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- sample that is unreactive towards methanol and nitromethane represents a 'sink' in the catalytic cycles of Figure 1.
-
-
-
-
84
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0242475746
-
-
note
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- ions. To test this proposition, the rate of reaction was measured over a 10-fold range of methanol pressure, effectively varying the average number of collisions with helium before collision with methanol. Reaction rate was found to be independent of methanol pressure.
-
-
-
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85
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0242559507
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note
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- and the degree of collisional activation used, but no attempts have been made to quantify the influence of these factors.
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86
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0033199099
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2- anions (M = Cr, Mo, W): Amado, A. M.; Ribeiro-Claro, P. J. A. J. Mol. Struct. (THEOCHEM), 1999, 469, 191
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Amado, A.M.1
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88
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0242475745
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note
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-. Given that these species are generated via collisional activation, kinetic considerations are also likely to be important in determining the relative populations of these isomers.
-
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90
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0001066652
-
-
2OH (Damrauer, R.; Krempp, M.; Damrauer, N. H.; Schmidt, M. W.; Gordon, M. S. J. Am. Chem. Soc. 1993, 115, 5218).
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Damrauer, R.1
Krempp, M.2
Damrauer, N.H.3
Schmidt, M.W.4
Gordon, M.S.5
-
91
-
-
0242559505
-
-
note
-
- described earlier may in fact be an average isotope effect for these two processes.
-
-
-
-
93
-
-
37049083569
-
-
(b) Clegg, W.; Errington, R. J.; Fraser, K. A.; Richards, D. G. Chem. Commun. 1993, 1105.
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Chem. Commun.
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Clegg, W.1
Errington, R.J.2
Fraser, K.A.3
Richards, D.G.4
-
94
-
-
0242559504
-
-
note
-
Ditungstate species have been observed before using electrospray: see refs 6b,d.
-
-
-
-
95
-
-
0004219668
-
-
Huhey, J. E.; Keiter, E. A.; Keiter, R. L. Inorganic Chemistry, 4th ed.; Harper-Collins: New York, 1993; pp 188-190.
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(1993)
Inorganic Chemistry, 4th Ed.
, pp. 188-190
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-
Huhey, J.E.1
Keiter, E.A.2
Keiter, R.L.3
-
96
-
-
37049108701
-
-
(a) Brownstein, S.; Heath, G. A.; Sengupta, A.; Sharp, D. W. A. Chem. Commun. 1983, 669
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(1983)
Chem. Commun.
, vol.669
-
-
Brownstein, S.1
Heath, G.A.2
Sengupta, A.3
Sharp, D.W.A.4
-
97
-
-
37049105490
-
-
(b) Heath, G. A.; Moock, K. A.; Sharp, D. W. A.; Yellowlees, L. J. Chem. Commun. 1985, 1503.
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(1985)
Chem. Commun.
, vol.1503
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-
Heath, G.A.1
Moock, K.A.2
Sharp, D.W.A.3
Yellowlees, L.J.4
-
98
-
-
0242559502
-
-
note
-
3l.
-
-
-
-
99
-
-
0242644167
-
-
note
-
- were also observed (M = Mo, W).
-
-
-
-
101
-
-
0022162442
-
-
Harrison, W. T. A.; Chowdhry, U.; Machiels, C. J.; Sleight, A. W.; Cheetham, A. K. J. Solid State. Chem. 1985, 60, 101.
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J. Solid State. Chem.
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, pp. 101
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-
Harrison, W.T.A.1
Chowdhry, U.2
Machiels, C.J.3
Sleight, A.W.4
Cheetham, A.K.5
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102
-
-
0346709734
-
-
Lee, K. Y.; Arai, T.; Nakata, S.; Asaoka, S.; Okuhara, T.; Misono, M. J. Am. Chem. Soc. 1992, 114, 2836.
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J. Am. Chem. Soc.
, vol.114
, pp. 2836
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-
Lee, K.Y.1
Arai, T.2
Nakata, S.3
Asaoka, S.4
Okuhara, T.5
Misono, M.6
-
103
-
-
0003595639
-
-
and references therein
-
Iwasawa, Y. In Tailored Metal Catalysts; Iwasawa, Y. Eds.; D. Reidel Publishing Company: Holland, 1986, p 54-60 and references therein.
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(1986)
Tailored Metal Catalysts
, pp. 54-60
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-
Iwasawa, Y.1
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