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Volumn 27, Issue 24, 2008, Pages 6605-6613

Chiral dibenzazepine-based P-AIkene ligands and their rhodium complexes: Catalytic asymmetric 1,4 additions to enones

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINE COMPOUNDS; CRYSTAL ATOMIC STRUCTURE; OLEFINS; RHODIUM; RHODIUM COMPOUNDS; X RAY DIFFRACTION ANALYSIS;

EID: 61849119618     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om800793q     Document Type: Article
Times cited : (76)

References (43)
  • 8
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    • Deblon, S.; Grützmacher, H.; Maire, P.; Schonberg, H. WO 03/ 048175 Al, 2003.
    • (a) Deblon, S.; Grützmacher, H.; Maire, P.; Schonberg, H. WO 03/ 048175 Al, 2003.
  • 12
    • 47349105054 scopus 로고    scopus 로고
    • and references therein. For a recent application, see
    • (b) For a recent application, see: Sana, B.; Smith, C. R RajanBabu, T. V. J. Am. Chem. Soc. 2008, 130, 9000, and references therein.
    • (2008) J. Am. Chem. Soc , vol.130 , pp. 9000
    • Sana, B.1    Smith, C.R.2    RajanBabu, T.V.3
  • 31
    • 61849087344 scopus 로고    scopus 로고
    • This affirmation is based on an X-ray crystal structure analysis of complex [PdCl2(7)2, The other, minor isomer of 7 is thought to be the equatorial variant. Dorta. R, Briceño, A. Unpublished results
    • 2]. The other, minor isomer of 7 is thought to be the equatorial variant. Dorta. R.; Briceño, A. Unpublished results.
  • 33
    • 61849098308 scopus 로고    scopus 로고
    • 1H NMR revealed the same (S,S) configuration, thus minimizing the probability of an accidental mix- up. Dorta, R.; Briceño, A. Unpublished results.
    • 1H) NMR revealed the same (S,S) configuration, thus minimizing the probability of an accidental mix- up. Dorta, R.; Briceño, A. Unpublished results.
  • 35
    • 61849150489 scopus 로고    scopus 로고
    • RhP = 291 Hz), along with ca. 3.5 equiv of free COE in the proton spectrum. After washing in pentane, one single isomer was isolated in 95% yield.
    • RhP = 291 Hz), along with ca. 3.5 equiv of free COE in the proton spectrum. After washing in pentane, one single isomer was isolated in 95% yield.
  • 36
    • 61849161140 scopus 로고    scopus 로고
    • This compound was prepared and characterized separately, manuscript in preparation
    • This compound was prepared and characterized separately, manuscript in preparation.
  • 37
    • 61849132210 scopus 로고    scopus 로고
    • 1H) NMR spectrum.
    • 1H) NMR spectrum.
  • 40
    • 61849178054 scopus 로고    scopus 로고
    • The determination of the cis/trans isomerism in complexes 13,15, and 16 is the subject of ongoing efforts, and results will be published in due course.
    • The determination of the cis/trans isomerism in complexes 13,15, and 16 is the subject of ongoing efforts, and results will be published in due course.
  • 42
    • 61849105442 scopus 로고    scopus 로고
    • Software Users Guide
    • CRYSTALCLEAR, version 1.3.6;, Inc, The Woodlands, TX
    • CRYSTALCLEAR, Software Users Guide, version 1.3.6; Rigaku/ MSC, Inc.: The Woodlands, TX.2000.
    • (2000) Rigaku/ MSC
  • 43
    • 61849110357 scopus 로고    scopus 로고
    • SHELXTL-NT, Version 5.1; Broker AXS Inc, Madison, WI, 1998
    • SHELXTL-NT, Version 5.1; Broker AXS Inc.: Madison, WI, 1998.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.